(a)
Interpretation:
The stronger nucleophile has to be selected from the given set of nucleophiles.
Concept Introduction:
Nucleophile:
The species, that make a covalent bond by donates a pair of electrons is known as nucleophile.
Stronger nucleophiles are negative charge or ready to donate a pair of electrons.
Weak nucleophiles are neutral molecules with lone pair of electrons.
(b)
Interpretation:
The stronger nucleophile has to be selected from the given set of nucleophiles.
Concept Introduction:
Nucleophile:
The species, that make a covalent bond by donates a pair of electrons is known as nucleophile.
Stronger nucleophiles are negative charge or ready to donate a pair of electrons.
Weak nucleophiles are neutral molecules with lone pair of electrons.
(c)
Interpretation:
The stronger nucleophile has to be selected from the given set of nucleophiles.
Concept Introduction:
Nucleophile:
The species, that make a covalent bond by donates a pair of electrons is known as nucleophile.
Stronger nucleophiles are negative charge or ready to donate a pair of electrons.
Weak nucleophiles are neutral molecules with lone pair of electrons.
(d)
Interpretation:
The stronger nucleophile has to be selected from the given set of nucleophiles.
Concept Introduction:
Nucleophile:
The species, that make a covalent bond by donates a pair of electrons is known as nucleophile.
Stronger nucleophiles are negative charge or ready to donate a pair of electrons.
Weak nucleophiles are neutral molecules with lone pair of electrons.
(e)
Interpretation:
The stronger nucleophile has to be selected from the given set of nucleophiles.
Concept Introduction:
Nucleophile:
The species, that make a covalent bond by donates a pair of electrons is known as nucleophile.
Stronger nucleophiles are negative charge or ready to donate a pair of electrons.
Weak nucleophiles are neutral molecules with lone pair of electrons.
(f)
Interpretation:
The stronger nucleophile has to be selected from the given set of nucleophiles.
Concept Introduction:
Nucleophile:
The species, that make a covalent bond by donates a pair of electrons is known as nucleophile.
Stronger nucleophiles are negative charge or ready to donate a pair of electrons.
Weak nucleophiles are neutral molecules with lone pair of electrons.
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Chapter 9 Solutions
Organic Chemistry
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- Draw the mechanism and predict the major product for each of the following reactions. (a) (b) O (c) NABH4 NABH4. 1. LIAIH4, Et,O ? CH;OH ? 2. H2SO4, H2O mOCH3 CH;OHarrow_forwardFor each pair of aromatic compounds, determine which will undergo electrophilic aromatic substitution faster. (a) (b) (c) (d) LOH ОН CF3 NO, (e) CI CI (f) SO3H SCH3 (g) (h) OH LOHarrow_forwardHow will you synthesize cyclohexanecarboxaldehyde (cyclohexylmethanal) from the following reagents? (There are no restrictions on the reagents or the number of steps). (a) Cyclohexanone (b) Ethynylcyclohexane (c) Methyl cyclohexylformate (Remember: Formic acid is the IUPAC recognized name for Methanoic acid) (d) Cyclohexanecarboxylic acid (Cyclohexylmethanoic acid) (e) Vinylcyclohexanearrow_forward
- 3) Please draw the structures that correspond to omitted structure for each of the following synthetic sequences. HO Cro3 Cro3 (a) Product `OH Product H,0 HO PCC Cl РСС (b) Product (e) Product OH HO РСС NABHA (f) Starting Material (c) Product OH ELOHarrow_forwardWhen treated with NaOH, the bromide below gives an alkene by the E2 mechanism, by eliminationof the circled atoms: (a) Draw the Newman projection from which elimination takes place. (b) Draw the mechanism. (c) Draw the product with the proper stereochemistry. (d) Assign the proper stereochemical descriptor to the product. (Z, E? Trans,CiS?) (e)What would happen to the stereochemistry of the product if the enantiomer of the starting material were used inthe reaction?arrow_forwardFor each pair of compounds determine which will undergo electrophilic substitution faster. (a) (b) (c) (d) CF3 HO Он NO2 () (g) SCH, (e) SO,H OH (h) CI CI HOarrow_forward
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