University Physics Volume 3
17th Edition
ISBN: 9781938168185
Author: William Moebs, Jeff Sanny
Publisher: OpenStax
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Textbook Question
Chapter 9, Problem 92AP
Show that the moment of inertia of a diatomic molecule is
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Show that the moment of inertia of a diatomic molecule composed of atoms of masses mA and mB and bond length R is equal to meffR2, where meff = mAmB/(mA+mB).
Show that the moment of inertia of a diatomic molecule composed of atoms of masses mA and mB and bond length R is equal to meffR2, where meff = mAmB/(mA + mB).
For a certain diatomic molecule, the lowest-energy photon in the vibrational spectrum is 0.17 eV.What is the energy of a photon emitted in a transition from the 5th exited vibrational energy level to the 2nd exited vibrational energy level, assuming no change in the rotational energy?
Chapter 9 Solutions
University Physics Volume 3
Ch. 9 - Check Your Understanding Why is the potential...Ch. 9 - Check Your Understanding What does the energy...Ch. 9 - Check Your Understanding If the dissociation...Ch. 9 - Check Your Understanding What happens to the...Ch. 9 - Check Your Understanding How does the magnitude of...Ch. 9 - Check Your Understanding What conditions are...Ch. 9 - What is the main difference between an ionic bond,...Ch. 9 - For the following cases, what type of bonding...Ch. 9 - Describe three steps to ionic bonding.Ch. 9 - What prevents a positive and negative ion from...
Ch. 9 - For the H2 molecule, why must the spins the...Ch. 9 - Does the absorption spectrum of the diatomic...Ch. 9 - Rank the energy spacing (E) of the following...Ch. 9 - Explain key features of a vibrational-rotation...Ch. 9 - Why is tbe equilibrium separation distance between...Ch. 9 - Describe the difference between a face-centered...Ch. 9 - In sodium chloride, how many Clatoms are “nearest...Ch. 9 - In cesium iodide, how many Clatoms are "nearest...Ch. 9 - The NaCl crystal structure is FCC. The equilibrium...Ch. 9 - Why does the Fermi energy (EF) increase with the...Ch. 9 - If the election number density (N/V) of a metal...Ch. 9 - Why does the horizontal Line in the graph in...Ch. 9 - Why does the graph in Figure 9.12 increase...Ch. 9 - Why are the sharp transitions at the Fermi energy...Ch. 9 - What are the two main approaches used to determine...Ch. 9 - Describe two features of energy levels for an...Ch. 9 - How does the number of energy levels in a band...Ch. 9 - Why are some materials very good conductors and...Ch. 9 - Why are some materials semiconductors?Ch. 9 - Why does the resistance of a semiconductor...Ch. 9 - What kind of semiconductor is produced if...Ch. 9 - What kind of semiconductor is produced if silicon...Ch. 9 - What is the Hall effect and what is it used for?Ch. 9 - For an n-type semiconductor, how do impurity atoms...Ch. 9 - For a p-type semiconductor, how do impurity atoms...Ch. 9 - When p- and n-type materials are joined, why is a...Ch. 9 - When p- and n-type materials are joined, why does...Ch. 9 - How do you know if a diode is in the forward...Ch. 9 - Why does the reverse bias configuration lead to a...Ch. 9 - What happens in the extreme case that where the n-...Ch. 9 - Explain how an audio amplifier works, using the...Ch. 9 - Describe two main features of a superconductor.Ch. 9 - How does BCS theory explain superconductivity?Ch. 9 - What is the Meissner effect?Ch. 9 - What impact does an increasing magnetic field have...Ch. 9 - The electron configuration of carbon is 1s22s22p2....Ch. 9 - Potassium chloride (KCl) is a molecule formed by...Ch. 9 - The electron affinity of Cl is 3.89 eV and the...Ch. 9 - The measured energy dissociated energy of KC1 is...Ch. 9 - In a physics lab, you measure the vibrational-...Ch. 9 - For the preceding problem, find the equilibrium...Ch. 9 - The separation between oxygen atoms in an O2...Ch. 9 - The characteristic energy of the N2 molecule is...Ch. 9 - The characteristic energy for KCl is 1.4105eV ....Ch. 9 - A diatomic F2 molecule is in the l = 1 state, (a)...Ch. 9 - In a physics lab, you measure the vibrational-...Ch. 9 - The Csl crystal structure is BCC. The equilibrium...Ch. 9 - The potential energy of a crystal is - 8.10 eV/ion...Ch. 9 - The measured density of a NaF crystal is 2.558...Ch. 9 - What value of the repulsion constant, n, gives the...Ch. 9 - Determine the dissociation energy of 12 moles of...Ch. 9 - The measured density of a KCl crystal is 1.984...Ch. 9 - What value of the repulsion constant, n, gives the...Ch. 9 - The measured density of a CsCl crystal is 3.988...Ch. 9 - What is the difference in energy between the...Ch. 9 - An electron is confined to a metal cube of I = 0.8...Ch. 9 - What value of energy corresponds to a density of...Ch. 9 - Compare the density of states at 2.5 eV and 0.25...Ch. 9 - Consider a cube of copper with edges 1.50 mm long....Ch. 9 - If there is one free electron per atom of copper,...Ch. 9 - Determine the Fermi energy and temperature for...Ch. 9 - For a one-dimensional crystal, write the lattice...Ch. 9 - What is the main difference between an insulator...Ch. 9 - What is the longest wavelength for a photon that...Ch. 9 - A valence electron in a crystal absorbs a photon...Ch. 9 - An experiment is performed to demonstrate the Hall...Ch. 9 - Suppose that the cross-sectional area of the strip...Ch. 9 - A current-carrying copper wire with cross-section...Ch. 9 - The Hall effect is demonstrated in the laboratory....Ch. 9 - Show that for V less than zero, InetI0.Ch. 9 - A p-n diode has a reverse saturation current...Ch. 9 - The collector current of a transistor is 3.4 A for...Ch. 9 - Applying the positive end of a battery to the...Ch. 9 - The base current of a transistor is 4.4 A, and its...Ch. 9 - At what temperature, in terms of Tc, is the...Ch. 9 - What is the critical magnetic field for lead at T...Ch. 9 - A Pb wire wound in a tight solenoid of diameter of...Ch. 9 - A tightly wound solenoid at 4.0 K is 50 cm long...Ch. 9 - Potassium fluoride (KF) is a molecule formed by...Ch. 9 - For the preceding problem, sketch the potential...Ch. 9 - The separation between hydrogen atoms in a H2...Ch. 9 - The characteristic energy of the Cl2 molecule is...Ch. 9 - Determine the lowest three rotational energy...Ch. 9 - A carbon atom can hybridize in the...Ch. 9 - List five main characteristics of ionic crystals...Ch. 9 - Why is bonding in favorable? Express your answer...Ch. 9 - Astronomers claim to find evidence of He2 from...Ch. 9 - Show that the moment of inertia of a diatomic...Ch. 9 - Show that the average energy of an electron in a...Ch. 9 - Measurements of a superconductor's critical...Ch. 9 - Estimate the fraction of Si atoms that must be...Ch. 9 - Transition in the rotation spectrum are observed...Ch. 9 - Determine the Fermi energies for (a) Mg, (b) Na,...Ch. 9 - Find the average energy of an electron in a Zn...Ch. 9 - What value of the repulsion constant, n, gives the...Ch. 9 - A physical model of a diamond suggests packing...Ch. 9 - For an electron in a three-dimensional metal, show...
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- Consider the HCl molecule, which consists of a hydrogen atom of mass 1 u bound to a chlorine atom of mass 35 u. The equilibrium separation between the atoms is 0.128 nm, and it requires 0.15 eV of work to increase or decrease this separation by 0.01 nm. (a) Calculate the four lowest rotational energies (in eV) that are possible, assuming the molecule rotates rigidly. (b) Find the molecules spring constant and its classical frequency of vibration. (Hint: Recall that U=12Kx2.) (c) Find the two lowest vibrational energies and the classical amplitude of oscillation corresponding to each of these energies. (d) Determine the longest wavelength radiation that the molecule can emit in a pure rotational transition and in a pure vibrational transition.arrow_forwardThe v = 0 to v = 1 vibrational transition of the HI molecule occurs at a frequency of 6.69 × 1013 Hz. The same transition for the NO molecule occurs at a frequency of 5.63 × 1013 Hz. Calculate (a) the effective force constant and (b) the amplitude of vibration for each molecule. (c) Explain why the force constant of the NO molecule is so much larger than that of the HI molecule.arrow_forwardLet's consider the three atoms composing the molecule now have different masses and coordinate, while the axis of rotation is still z axis that is perpendicular to the xy plane. The first atom has a mass of 142.54 kg, with x coordinate at 3 m and y coordinate at 6 m. The second atom has a mass of 82.55 kg, with x coordinate at 1 m and y coordinate at 6 m. The third atom has a mass of 8 kg, with x coordinate at 5 m and y coordinate at 9 m. What is the moment of inertia in unit of kg m2 with respect to the x axis?arrow_forward
- 2(6) Calculate the fundamental vibrational wavenumber (in cm-1) for HI molecule, if its angular vibrational frequency is 4.394×1014 s-1. Calculate the vibrational energy of the molecule in the ground state and the force constant. Assume the mass is the mass of a proton.arrow_forwardWhat is the minimum energy required to go from one vibrational state to the next higher vibrational state for a molecule whose vibrations are modeled by a harmonic oscillator?arrow_forwardWhen are the rotational degrees of freedom of a diatomic molecule expected to contribute R to the molar constant volume heat capacity? When will a vibrational degree of freedom contribute R to the molar heat capacity?arrow_forward
- Find the number of vibrational degrees of freedom of a CO2 molecule,if the average kinetic energy of it is 4 kT.arrow_forwardAlthough an ordinary H2 molecule consists of two identical atoms, this is not the case for the molecule HD, with one atom of deuterium (Le., heavy hydrogen, 2H). Because of its small moment of inertia, the HD molecule has a relatively large value of E: 0.0057 eV. At approximately what temperature would you expect the rotational heat capacity of a gas of HD molecules to "freeze out," that is, to fall significantly below the constant value predicted by the equipartition theorem?arrow_forwardConsider a CO molecule that is initially in the ground state of n = 0, l = 0. If the energy of a vibrational transition from the n = 0 state to the n = 1 state in CO could instead be absorbed in a rotational transition, what would be the value of l for the final state?arrow_forward
- The intensities of spectroscopic transitions between the vibrational states of a molecule are proportional to the square of the integral ∫ψv′xψvdx over all space. Use the relations between Hermite polynomials given in Table 7E.1 to show that the only permitted transitions are those for which v′ = v ± 1 and evaluate the integral in these cases.arrow_forwardConsider the NaCl molecule, for which the rotational inertia is 1.30x 10-45 kg*m2. If infrared radiation with wavelength 30 μ m is Raman-scattered from a free NaCl molecule, what are the allowed wavelengths of the scattered radiation?arrow_forwardA gas phase H19F molecule has a bond length of 91.68 pm and a vibrational force constant,k = 966 N/m. For the v = 0, J = 10 and v = 1, J = 10 rovibrational levels, calculate the period of rotation andvibration. How many times does the molecule rotate during one vibrational period?arrow_forward
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