Physical Chemistry
Physical Chemistry
2nd Edition
ISBN: 9781133958437
Author: Ball, David W. (david Warren), BAER, Tomas
Publisher: Wadsworth Cengage Learning,
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Chapter 9, Problem 9.30E
Interpretation Introduction

(a)

Interpretation:

The value and units of the slope of the energy versus wavelength for given Planck’s law equation at given temperatures and wavelengths is to be calculated.

Concept introduction:

Planck’s equation can also be represented in the form of energy density distribution of a black body radiation at a given temperature and wavelength. This equation is known as Planck’s radiation distribution law.

Expert Solution
Check Mark

Answer to Problem 9.30E

The value and units of the slope of the energy versus wavelength at given temperature and wavelength is 4.9×105 and Jm4 respectively.

Explanation of Solution

It is given that temperature and wavelength is 1000K and 500nm respectively.

To calculate slope of the energy versus wavelength, the Planck’s law equation used is,

dρdλ=8πhcλ5(1ehc/λkT1)

Where,

ρ is the energy density.

λ is the wavelength.

h is the Planck’s constant.

k is the Boltzmann constant.

c is the speed of light.

Substitute the values of constants, temperature and wavelength in the given equation.

dρdλ=8(3.14)(6.626×1034Js)(3×108ms1)(500×109m)5(1e6.626×1034Js×3×108ms1500×109m×1.38×1023JK1×1000K1)=4.9×105Jm4

Thus, the slope of the energy versus wavelength is 4.9×105Jm4.

Conclusion

The value and units of the slope of the energy versus wavelength at given temperature and wavelength is 4.9×105 and Jm4 respectively.

Interpretation Introduction

(b)

Interpretation:

The value and units of the slope of the energy versus wavelength for given Planck’s law equation at given temperatures and wavelengths is to be calculated.

Concept introduction:

Planck’s equation can also be represented in the form of energy density distribution of a black body radiation at a given temperature and wavelength. This equation is known as Planck’s radiation distribution law.

Expert Solution
Check Mark

Answer to Problem 9.30E

The value and units of the slope of the energy versus wavelength at given temperature and wavelength is 89.3 and Jm4 respectively.

Explanation of Solution

It is given that temperature and wavelength is 2000K and 500nm.

To calculate slope of the energy versus wavelength, the Planck’s law equation used is,

dρdλ=8πhcλ5(1ehc/λkT1)

Where,

ρ is the energy density.

λ is the wavelength.

h is the Planck’s constant.

k is the Boltzmann constant.

c is the speed of light.

Substitute the values of constants, temperature and wavelength in the given equation.

dρdλ=8(3.14)(6.626×1034Js)(3×108ms1)(500×109m)5(1e6.626×1034Js×3×108ms1500×109m×1.38×1023JK1×2000K1)=89.3Jm4

Thus, the slope of the energy versus wavelength is 89.3Jm4.

Conclusion

The value and units of the slope of the energy versus wavelength at given temperature and wavelength is 89.3 and Jm4 respectively.

Interpretation Introduction

(c)

Interpretation:

The value and units of the slope of the energy versus wavelength for given Planck’s law equation at given temperatures and wavelengths is to be calculated.

Concept introduction:

Planck’s equation can also be represented in the form of energy density distribution of a black body radiation at a given temperature and wavelength. This equation is known as Planck’s radiation distribution law.

Expert Solution
Check Mark

Answer to Problem 9.30E

The value and units of the slope of the energy versus wavelength at given temperature and wavelength is 496.1 and Jm4 respectively.

Explanation of Solution

It is given that temperature and wavelength is 2000K and 5000nm.

To calculate slope of the energy versus wavelength, the Planck’s law equation used is,

dρdλ=8πhcλ5(1ehc/λkT1)

Where,

ρ is the energy density.

λ is the wavelength.

h is the Planck’s constant.

k is the Boltzmann constant.

c is the speed of light.

Substitute the values of constants, temperature and wavelength in the given equation.

dρdλ=8(3.14)(6.626×1034Js)(3×108ms1)(5000×109m)5(1e6.626×1034Js×3×108ms15000×109m×1.38×1023JK1×2000K1)=496.1Jm4

Thus, the slope of the energy versus wavelength is 496.1Jm4.

Conclusion

The value and units of the slope of the energy versus wavelength at given temperature and wavelength is 496.1 and Jm4 respectively.

Interpretation Introduction

(d)

Interpretation:

The value and units of the slope of the energy versus wavelength for given Planck’s law equation at given temperatures and wavelengths is to be calculated.

Concept introduction:

Planck’s equation can also be represented in the form of energy density distribution of a black body radiation at a given temperature and wavelength. This equation is known as Planck’s radiation distribution law.

Expert Solution
Check Mark

Answer to Problem 9.30E

The value and units of the slope of the energy versus wavelength at given temperature and wavelength is 47.4 and Jm4 respectively.

Explanation of Solution

It is given that temperature and wavelength is 2000K and 10000nm.

To calculate slope of the energy versus wavelength, the Planck’s law equation used is,

dρdλ=8πhcλ5(1ehc/λkT1)

Where,

ρ is the energy density.

λ is the wavelength.

h is the Planck’s constant.

k is the Boltzmann constant.

c is the speed of light.

Substitute the values of constants, temperature and wavelength in the given equation.

dρdλ=8(3.14)(6.626×1034Js)(3×108ms1)(10000×109m)5(1e6.626×1034Js×3×108ms110000×109m×1.38×1023JK-1×2000K1)=47.4Jm4

Thus, the slope of the energy versus wavelength is 47.4Jm4.

Conclusion

The value and units of the slope of the energy versus wavelength at given temperature and wavelength is 47.4 and Jm4 respectively.

Interpretation Introduction

(e)

Interpretation:

The results are to be compared with those of exercise 9.25.

Concept introduction:

Planck’s equation can also be represented in the form of energy density distribution of a black body radiation at a given temperature and wavelength. This equation is known as Planck’s radiation distribution law.

The slope of the plot of energy versus wavelength for the Rayleigh-Jeans law is given by a rearrangement of equation 9.20 which is given below.

dρdλ=8πkTλ4

Expert Solution
Check Mark

Answer to Problem 9.30E

The values of slope of the plot of energy versus wavelength from Rayleigh-Jeans law is similar to that of Planck’s radiation distribution law at temperature and wavelength 2000K and 10000nm respectively and most dissimilar at temperature and wavelength 1000K and 500nm respectively.

Explanation of Solution

On comparing the results from exercise 9.25, it is found that the values of slope of the plot of energy versus wavelength from Rayleigh-Jeans law is similar to that of Planck’s radiation distribution law at temperature and wavelength 2000K and 10000nm respectively and most dissimilar at temperature and wavelength 1000K and 500nm respectively.

Conclusion

The values of slope of the plot of energy versus wavelength from Rayleigh-Jeans law is similar to that of Planck’s radiation distribution law at temperature and wavelength 2000K and 10000nm respectively and most dissimilar at temperature and wavelength 1000K and 500nm respectively.

Interpretation Introduction

(f)

Interpretation:

The temperatures and spectral regions at which the Rayleigh-Jeans law is close to Planck’s law are to be identified.

Concept introduction:

Planck’s equation can also be represented in the form of energy density distribution of a black body radiation at a given temperature and wavelength. This equation is known as Planck’s radiation distribution law.

The slope of the plot of energy versus wavelength for the Rayleigh-Jeans law is given by,

dρdλ=8πkTλ4

Expert Solution
Check Mark

Answer to Problem 9.30E

At higher temperatures and longer wavelengths, the Rayleigh-Jeans law is close to Planck’s law.

Explanation of Solution

On comparing the results from exercise 9.25, it is found that the values of slope of the plot of energy versus wavelength from Rayleigh-Jeans law is similar to that of Planck’s radiation distribution law at temperature and wavelength 2000K and 10000nm respectively and most dissimilar at temperature and wavelength 1000K and 500nm respectively. Thus, at higher temperatures and longer wavelengths the Rayleigh-Jeans law is close to Planck’s law.

Conclusion

At higher temperatures and longer wavelengths the Rayleigh-Jeans law is close to Planck’s law.

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Chapter 9 Solutions

Physical Chemistry

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