(a)
Interpretation:
For each given reaction, the structure of each product is to be drawn.
Concept introduction:
If the reactant molecule has two different functional groups attached to different places on the same molecule, then intramolecular reaction is possible. Whenever an intramolecular reaction can take place, an intermolecular reaction is also possible. When a five or six-membered ring can be formed, the intramolecular cyclization reactions are favored over their corresponding intermolecular reactions.
(b)
Interpretation:
For the given reaction, the mechanism that accounts for the formation of each of those products is to be drawn.
Concept introduction:
If the reactant molecule has two different functional groups attached to different places on the same molecule, then the intramolecular reaction is possible. Whenever an intramolecular reaction can take place, an intermolecular reaction is also possible. When a five or six-membered ring can be formed, the intramolecular cyclization reactions are favored over their corresponding intermolecular reactions.
(c)
Interpretation:
How the isomeric reactants lead to different products is to be explained.
Concept introduction:
If the reactant molecule has two different functional groups attached to different places on the same molecule, then the intramolecular reaction is possible. Whenever an intramolecular reaction can take place, an intermolecular reaction is also possible. When a five or six-membered ring can be formed, the intramolecular cyclization reactions are favored over their corresponding intermolecular reactions.
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Organic Chemistry: Principles and Mechanisms (Second Edition)
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