Treatment of c i s -4-bromocyclohexanol with HO − affords compound A and cyclohex-3-en-1-ol . Treatment of t r a n s -4-bromocyclohexanol under the same conditions forms compound B and cyclohex-3-en-1-ol . A and B contain different functional groups and are not isomers of each other. Propose structures for A and B and offer an explanation for their formation.
Treatment of c i s -4-bromocyclohexanol with HO − affords compound A and cyclohex-3-en-1-ol . Treatment of t r a n s -4-bromocyclohexanol under the same conditions forms compound B and cyclohex-3-en-1-ol . A and B contain different functional groups and are not isomers of each other. Propose structures for A and B and offer an explanation for their formation.
Solution Summary: The author explains that the structures for A and B are drawn from the substitution reaction of cis and trans isomers of 4-bromocyclohexanol.
Treatment of
c
i
s
-4-bromocyclohexanol
with
HO
−
affords compound A and
cyclohex-3-en-1-ol
. Treatment of
t
r
a
n
s
-4-bromocyclohexanol
under the same conditions forms compound B and
cyclohex-3-en-1-ol
. A and B contain different functional groups and are not isomers of each other. Propose structures for A and B and offer an explanation for their formation.
Definition Definition Group of atoms that shape the chemical characteristics of a molecule. The behavior of a functional group is uniform in undergoing comparable chemical reactions, regardless of the other constituents of the molecule. Functional groups aid in the classification and anticipation of reactivity of organic molecules.
Which of the following reactions give isopropyl alcohol as the major product?
v. propene + aqueous nitric acid;
w. propene + aqueous sodium hydroxide;
x. propene + BH3 followed by H2O2 in water;
y. isopropyl amine + aqueous sodium hydroxide;
z. isopropyl iodide + water.
show every reaction and their steps
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