Organic Chemistry
Organic Chemistry
7th Edition
ISBN: 9780321826596
Author: Bruice, Paula Yurkanis/
Publisher: Pearson College Div
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Chapter 9.2, Problem 11P

(a)

Interpretation Introduction

Interpretation:

From the given species better nucleophile in the given solvent has to be identified.

Concept Introduction:

  • Aprotic solvent are polar solvent molecules which do not have hydrogen bonded to oxygen to nitrogen.
  • Protic solvent are polar solvent molecules which do have hydrogen bonded to oxygen to nitrogen.
  • The stronger base is always a better nucleophile in an aprotic solvent.

(b)

Interpretation Introduction

Interpretation:

From the given species better nucleophile in the given solvent has to be identified.

Concept Introduction:

  • Aprotic solvent are polar solvent molecules which do not have hydrogen bonded to oxygen to nitrogen.
  • Protic solvent are polar solvent molecules which do have hydrogen bonded to oxygen to nitrogen.
  • The stronger base is always a better nucleophile in an aprotic solvent.

(c)

Interpretation Introduction

Interpretation:

From the given species better nucleophile in the given solvent has to be identified.

Concept Introduction:

  • Aprotic solvent are polar solvent molecules which do not have hydrogen bonded to oxygen to nitrogen.
  • Protic solvent are polar solvent molecules which do have hydrogen bonded to oxygen to nitrogen
  • The stronger base is always a better nucleophile in an aprotic solvent.

(d)

Interpretation Introduction

Interpretation:

From the given species better nucleophile in the given solvent has to be identified.

Concept Introduction:

  • Aprotic solvent are polar solvent molecules which do not have hydrogen bonded to oxygen to nitrogen.
  • Protic solvent are polar solvent molecules which do have hydrogen bonded to oxygen to nitrogen
  • The stronger base is always a better nucleophile in an aprotic solvent.

(e)

Interpretation Introduction

Interpretation:

From the given species better nucleophile in the given solvent has to be identified.

Concept Introduction:

  • Aprotic solvent are polar solvent molecules which do not have hydrogen bonded to oxygen to nitrogen.
  • Protic solvent are polar solvent molecules which do have hydrogen bonded to oxygen to nitrogen
  • The stronger base is always a better nucleophile in an aprotic solvent.

(f)

Interpretation Introduction

Interpretation:

From the given species better nucleophile in the given solvent has to be identified.

Concept Introduction:

  • Aprotic solvent are polar solvent molecules which do not have hydrogen bonded to oxygen to nitrogen.
  • Protic solvent are polar solvent molecules which do have hydrogen bonded to oxygen to nitrogen
  • The stronger base is always a better nucleophile in an aprotic solvent.

(g)

Interpretation Introduction

Interpretation:

From the given species better nucleophile in the given solvent has to be identified.

Concept Introduction:

  • Aprotic solvent are polar solvent molecules which do not have hydrogen bonded to oxygen to nitrogen.
  • Protic solvent are polar solvent molecules which do have hydrogen bonded to oxygen to nitrogen
  • The stronger base is always a better nucleophile in an aprotic solvent.

(h)

Interpretation Introduction

Interpretation:

From the given species better nucleophile in the given solvent has to be identified.

Concept Introduction:

  • Aprotic solvent are polar solvent molecules which do not have hydrogen bonded to oxygen to nitrogen.
  • Protic solvent are polar solvent molecules which do have hydrogen bonded to oxygen to nitrogen
  • The stronger base is always a better nucleophile in an aprotic solvent.

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Students have asked these similar questions
Would you say its sn1 ir sn2, I said it was sn1,because the nucleophile is weak, but my teachers said it was sn2
Retrosynthesis: When No2 bond breaks, which one would be the next better leaving group, SO3H or cyclopentane?    Why is SO3H a better leaving group than cyclopentane?   Why NO2 is the first one that leave in Retrosynthesis, what make NO2 a better leaving group over SO3H or cyclopentane?
Which nucleophile(s) is also a strong base? a) CH3MgBr b) LiAlH4 c) CHCH2OH d) Both CH3MgBr and LiAlH4

Chapter 9 Solutions

Organic Chemistry

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