Concept explainers
Interpretation:
The IUPAC name of
Concept introduction:
The IUPAC name of a compound is made up of three parts: prefix, root, and suffix. If the compound contains different functional groups, the highest priority group is determined. This determines the suffix. The longest continuous chain of carbons that contains the highest priority group forms the root. The final ‘e’ in the name of the corresponding
If any chiral carbons are present, their absolute configurations are determined on the basis of Cahn-Ingold-Prelog rules and listed at the start along with the carbon number.
Answer to Problem F.1P
The IUPAC name of
Explanation of Solution
The structure of
The highest priority function group in
There are two other functional groups,
The root carbons are numbered from the carboxylic acid carbon as shown below.
This puts the amino group on C2 and the carbamoyl on C3. The carbon to which the amine group is attached is a chiral carbon. Based on the Cahn-Ingold-Prelog rules, the absolute configuration at this carbon is S.
Apparently, the three highest priority groups are arranged clockwise, but with the lowest priority hydrogen pointing toward the observer. Therefore, the actual configuration is S.
Therefore, the complete IUPAC name of
The highest priority functional group is considered as suffix, and the other remaining groups are considered as substituents for writing IUPAC name of the molecule.
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Chapter F Solutions
ORG. CHEM. LL W/SSM+SG+ACCESS
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- Chemistry for Today: General, Organic, and Bioche...ChemistryISBN:9781305960060Author:Spencer L. Seager, Michael R. Slabaugh, Maren S. HansenPublisher:Cengage Learning