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Concept explainers
Interpretation:
The organic product of each of the given reactions is to be predicted.
Concept introduction:
舧 Electrophiles are electron-deficient species, which has positive or partially positive charge. Lewis acids are electrophiles, which accept electron pair.
舧 Nucleophiles are electron-rich species, which has negative or partially negative charge. Lewis bases are nucleophiles, which donate electron pair.
舧 Substitution reaction: A reaction in which one of the hydrogen atoms of a hydrocarbon or a
舧 Elimination reaction: A reaction in which two substituent groups are detached and a double bond is formed is called elimination reaction.
舧 Addition reaction: It is the reaction in which unsaturated bonds are converted to saturated molecules by the addition of molecules.
舧 Reaction sequences involve conversion of one functional group to other, which may also require addition of carbon or loss of carbon from the reactant.
舧 These sequences involve a number of steps carried on by different reagents. Sometimes, different reagents give same products.
舧 The compound methyl magnesium bromide reacts with acetophenone and on subsequent acid treatment gives the product 2-phenylpropan-2-ol.
舧 The alkyl lithium reagents react with
舧 The excess methyl magnesium bromide reacts with methyl benzoate and on subsequent acid treatment gives the product 2-phenylpropan-2-ol.
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Chapter FRP Solutions
ORGANIC CHEM. VOL.1+2-W/WILEYPLUS
- Explain the following statements. You must use chemical equations to justify your explanation. (ii) (I) Phenol is more acidic than cyclohexanol.arrow_forwardWhich of the following is true for the reactions of alkyl halides? (a) The characteristic reactions of alkyl halides are oxidation and reduction.(b) The characteristic reactions of alkyl halides are elimination and substitutionc. The characteristic reactions of alkyl halides are addition and substitutiond. Characteristic reactions of alkyl halides are addition and elimination.arrow_forward(a) When bromine is added to two beakers, one containing phenyl iso propyl ether and the other containing cyclohexene, the bromine color in both beakers disappears. What observation could you make while performing this test that would allow you to distinguish the alkene from the aryl ether? (b) Write any three methods in detail for the preparation of aldehyde from primary alcohol. (c) State the clemmenson reduction.arrow_forward
- Write the structure of the major organic product formed in the reaction of each of the following with hydrogen bromide in the absence of peroxides and in their presence. (a) 1-Pentene (b) 2-Methyl-2-butene (c) 1-Methylcyclohexenearrow_forwardWhat will be the color of the flame and the amount of soot if the following are ignited:(a) Hexane (b)Heptane(c) Cyclohexane (d) Cyclohexene (e) Benzene (f) Toluenearrow_forwardExplain the structural formula for (C) (B) (A) in the following reaction:arrow_forward
- Answer ALL parts of this question. (a) Compound Z is a tertiary aromatic amine with the formula, C8H11N. Provide a chemical structure for compound Z. (b) Provide a reaction scheme for the preparation of nitrous acid. (c) Draw the structure of the product formed exclusively when nitrous acid reacts with Z. (d) Give a curly arrow mechanism for the preparation of the yellow azo-dye from the reaction of Z with benzenediazonium chloride.arrow_forwardAnswer ALL parts of this question. (a) Using resonance structures, discuss the following statement; phenols are much stronger acids than aliphatic alcohols. (b) Give the structure of a stronger organic acid than phenol. (c) Rationalise the acidity of the latter organic acid by drawing two resonance structures of the conjugate base. (d) Eugenol is a natural product derived from the dried flower buds of the evergreen tree, Eugenia aromatica. Briefly describe a procedure with reagents required to extract eugenol as a single component from the mixture of compounds present in these flower buds. OH LOCH 3 eugenolarrow_forwardDraw the structures of the following compounds. (a) isobutyl bromidearrow_forward
- 1. (a) Describe aromaticity, Kekule structure and resonance structure for benzene. (b) Why is benzene more stable than aliphatic alkenes?arrow_forward6. Describe concisely a chemical test to distinguish between the following pairs of compounds. (a) n-pentanol and 3-methylpentan-3-ol (b) Ethanal dan pentanal (c) Phenol and benzoic acidarrow_forwardGiven each of the structures provided, write the corresponding IUPAC name. (a) (b) (c) (d) (e)arrow_forward
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