580340 Determination of Water Hardness by Titration Q
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Dec 6, 2023
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Determination of Water Hardness by Titration
Jerret Jarvis
November 2, 2023
1
Data
Activity 1
Data Table 1: Complexometric Titration of Hard Water
Hard Water
Trial 1
Hard Water Trial 2
Hard Water
Trial 3
Initial
Syringe
Reading (mL)
1.0 mL
1.0 mL
1.0 mL
Final Syringe
Reading (mL)
0.6 mL
0.5 mL
0.2 mL
Volume of
EDTA
Consumed
(mL)
0.4 mL
0.5 mL
0.8 mL
Water
Hardness
ppm CaCO
3
(mg/L)
400.4 ppm
500.5 ppm
800.9 ppm
Average ppm CaCO
3
(mg/L):
567.23 ppm
© 2016 Carolina Biological Supply Company
2
Data Table 2: Complexometric Titration of Tap Water
Hard Water
Trial 1
Hard Water Trial 2
Hard Water
Trial 3
Initial
Syringe
Reading
(mL)
1.0 mL
1.0 mL
1.0 mL
Final
Syringe
Reading
(mL)
0.3 mL
0.5 mL
0.3 mL
Volume of
EDTA
Consumed
(mL)
0.7 mL
0.5 mL
0.7 mL
Water
Hardness
ppm CaCO
3
(mg/L)
700.7 ppm
500.5 ppm
700.7 ppm
Average ppm CaCO
3
(mg/L): 633.97 ppm
© 2016 Carolina Biological Supply Company
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Related Questions
Data for titration of 15.00 mL of vinegar with approximately 1.0 M NaOH. Note you must use the exact
concentration of the standard NaOH solution to calculate the moles of NaOH.
Quantity
Еxample
Trial 1
Trial 2
Trial 3
M NaOH (exact
concentration)
0.992 M
0.953 M
0.953 M
0.953 M
V initial buret
reading = V,
0.20 mL
1.20 mL
0.52 mL
0.15 mL
V final buret
reading = V,
12.90 mL
14.22 mL
13.71 mL
13.31 mL
%3D
Vep = VNAOH
added = V; - V,
12.70 mL
13.02 mL
13.19 mL
13.16 mL
Vep = VNAOH in L
0.01270 L
0.01302 L
0.01319 L
0.01316 L
moles NaOH =
0.0126 mol
0.0124 mol
0.0126 mol
0.0125 mol
MNAOH X VNAOH
moles AA =
0.0126 mol
0.0124 mol
0.0126 mol
0.0125 mol
moles NaOH
V sample = V
acid
0.0150 L
0.0150 L
0.0150 L
0.0150 L
(15.00 mL)
(15.00 mL)
(15.00 mL)
Actual molarity
0.840 M
0.827 M
0.840 M
0.833 M
of AA
Average molarity for 3 trials =>
of AA
0.833 M
1. Report the acetic acid (AA) concentration of vinegar in units of molarity (M).
2. Use your average AA concentration to calculate the mass…
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Data Table 3: Complexometric Titration of Soft Water
5 ml of water
1ml of buffer
Hard Water Trial 1
Hard Water Trial 2
Hard Water Trial 3
Initial Syringe Reading (mL)
1ml
1ml
1ml
Final Syringe Reading (mL)
77ml
79ml
75ml
Volume of EDTA Consumed (mL)
.23ml
.21ml
.25ml
Water Hardness
ppm CaCO3 (mg/L)
Average ppm CaCO3 (mg/L):
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Calculate the total volume of HCl titrant delivered to the equivalence point for each trial
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How much calcium would you ingest by drinking one 8 oz glass of your tap water? Show all calculations.
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Concentration sodium thiosulfate solution used:
0.056 mol L-1
ACCURATE TITRATION VOLUME OF SODIUM THIOSULFATE SOLUTION USED
Volume titration 1, (ml)
Volume titration 2, (mL)
Your Group
15.80
15.75
Group 1
16.05
15.70
Group 2
16.30
16.25
ANALYSIS
Average volume used, (mL)
Standard deviation
Unrounded value
Rounded value
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Preparation and Standardization of KMnO4 solution
Experimental data
Complete the table below.
Trial 1
0.2001 g
Trial 2
0.2065 g
Trial 3
Weight of sodium oxalate
(Na2C2O4, MM= 134 g/mol)
Titration data
0.2050 g
Final reading
Initial reading
29.86 mL
0.00 mL
30.66 mL
30.52 mL
0.00 mL
0.00 mL
Total vol. of KMNO4 used
Computed Molarity of KMNO4
solution
Mean Molarity
Computed Normality of KMNO4
Mean Normality of KMNO4
solution
Reaction Involved:
Calculations:
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Table 2. Titration data
Trial 1
Trial 2
Trial 3
Initial burette reading (mL)
1.19
2.26
2.39
Molarity of NaOH (M)
0.100
0.100
0.100
Volume of vinegar sample (mL)
5.00
5.00
5.00
Final burette reading (mL)
48.55
49.43
49.99
Expected color at end point
Volume of NaOH used (mL)
Average Volume of NaOH used in liters
Average moles of NaOH used (mol)
Average moles of acetic acid (mol)
Average molarity of acetic acid (M)
Average mass of acetic acid (g)
Average mass of vinegar (g) (assume the density of vinegar is 1.00 g/mL)
Average mass % of acetic acid in vinegar
Known mass % of acetic acid in vinegar is 5.45%
Percent Error
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Determine the concentration of acetic acid and vinegar
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Titration Titrant Reductant/ Oxidant Analyte Standardizing Indicator Reagent COD BOD INDIRECT TITRATIONKindly identify the blank sections appropriately.
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Procedure
Preparation of Dilute Solution of Vinegar
• Using a 10 mL pipette, transfer 10mL of vinegar into 100 mL volumetric flask.
• Dilute to mark of the volumetric flask using distilled water.
B. Titration of Diluted Solution of Vinegar
• Transfer 25 mL of diluted solution to 250 mL Erlenmeyer flask.
• Add 0.5 mL phenolphthalein indicator. Set aside.
• Transfer 50mL of 0.110 M NaOH into a 50 mL burette.
• Titrate the diluted solution until the phenolphthalein endpoint (very faint pink).
• Record volume of NaOH used.
Answer the question:
What is the experimentally determined concentration of acetic acid in your vinegar solution: (Please give your answer to three significant figures.)
______ M Acetic Acid
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Answer if true or false , if false, put the correct answer
1. Molarity of titrant = number of moles analyte / volume of analyte
2. Two general types of titration curves are sigmoidal and linear segment
3. Tritration must occur slowly
4. Primary standard has high purity and is stable
5. Using phenlphthalein indicator, acidic to basic endpoint is usually colorless
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Identify which of the graphs represent the given titration experiments best.
Graph A
Graph B
12
12
11-
11-
10-
10-
9-
9-
8-
8-
7-
7-
6-
6-
5-
5-
4-
3-
3-
2-
2
1
10 15 20 25 30 35 40 45 50
10 15 20 25 30 35 40 45
50
Titrant.volume Cml).
Titrant.volume (mL).
Answer Bank
This graph does not represent a titration.
a basic solution titrated with an acid
an acidic solution titrated with a base
Hd
Hd
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Sample #
1
2
0.2425
0.2160
0.2274
Weighed mass of ascorbic acid (g)
volume of KIO3 (mL)
18.86
17.91
17.37
0.02459
0.02462
0.02432
[KIO3] (mol L-1)
Mean [KIO3] (based on titration)
0.02451
mol L-1
Standard deviation in the mean [KIO3]
mol L-1
Confidence limit for the [KI03]
mol L-1
Relative confidence limit for the [KIO3]
ppt
=
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Part A: Standardization of a Sodium Hydroxide Solution
Titration 1
Titration 2
Titration 3
Mass of 125 mL flask
45.849g
46.715g
44.953g
Mass of flask and KHP
46.849g
47.745g
46.003g
Initial buret reading (mL)
0.5 ml
0.5 ml
0.5 ml
Final buret reading (mL)
27.8 ml
26.5 ml
26.7 ml
Volume of NaOH used (mL)
45.11 ml
45.06 ml
45.14 ml
Calculations
Titration 1
Titration 2
Titration 3
Moles of KHP
Moles of NaOH
Molarity of NaOH
Average Molarity of NaOH: _______________
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20 mL of 0.1M titrand titrated with 0.1M titrant. Data points at 1 mL increments.
14.0
12.0
10.0
HO
8.0
6.0
4.0
2.0
0.0
0.0
10.0
20.0
30.0
Volume of titrant (mL)
40.0
444444
50.0
(a) Is the species being titrated an acid or a base?
(b) Is the species being titrated strong or weak?
(c) What is the value of Ka (if a weak acid) or K (if a weak base) for the species being titrated?
If the species is strong (100% dissociated), enter 999.
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Hi, I just need to know the correct answer for these. Thank you
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Data:
Table 1: Titration of 1.00 mL H2O2 with KMNO4
0.1134M
Concentration of KMNO4
Trial #
Initial KMNO4 Volume (mL)
Final KMNO4 Volume (mL)
Volume KMnO4 Used (mL)
1
10
2
10
19.7
19.7
29.6
Pre-lab:
1.
What is a titrant? What is the titrant in this lab?
2. What is an analyte? What is the analyte in this lab?
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A drug is ordered to be administered IV at the initial rate of 4 mU/min, and may increase by 2 mu/min q 15 min to a max of 10 mU/min. The IV strength is 5 mU/mL.
Construct the first two lines of the titration table for this order.
O A. Dose Rate (mU/min) IV rate (mL/h)
4 mU/min (initial)
8 mU/min
36 mL/h
48 mL/h
O B. Dose Rate (mU/min)
4 mU/min (initial)
6 mU/min
Oc. Dose Rate (mU/min)
4 mU/min (initial)
6 mU/min
O D. Dose Rate (mu/min)
4 mU/min (initial)
6 mu/min
IV rate (mL/h)
24 mL/h
48 mL/h
IV rate (mL/h)
48 mL/h
72 mL/h
IV rate (mL/h)
36 mL/h
36 mL/h
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Understanding of food analysis methods. Principles of method described compared to other techniques.
1 The MOHR Titration, AOAC Method? What is it and how does it work? How can it be used to quantify salt in a sample.
2 Are there any advantages and/or disadvantages of this method?3 Are there any alternate methods better than the Mohr Titration toquantitatively determine salt in a sample?
4. Diseases with recent statistics? Refer to World Health Organisation?
5. Why analayse salt?
6. Consumption?
7. Main aims of study?
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Titration Experiment 1: Acid-Base Titration: Unknown HCl
Write chemical equation
*+ HClcags N s
→ Naclceg) + H,O
Write NIE
OH c) + HEogs → H2OC)
Enter the data into the table and choose three titrations to find the molarity of the unknown HCI.
Unknown # HCI
Titration 1 Titration 2 Titration 3 Titration 4 Titration 5
Volume NaOH used to titrate
unknown HCI solution
17.43ml 16.5O ml662 mll16.57ml16.6dmL
Molarity of NaOH used for
each titration
0.2564
0.1787/01692/0.1704/oiado1703
Molarity of HCI
Average M HCI (avg ±
standard deviation)
10.1717
1.63
% Precision
Calculations
1. Provide one representative calculation that you used to determine the molarity of HCI. Be
sure to show all units and use proper sig figs!
V HCI-25mL
MHCI =?
VN2OH = 16.6lmL
MNAOH=0.2564
MHCI VHCI=MNAOH VAa OH
MHCI 25=O. 1564 16.61
MHCI= 0.2564.16.61
25
MHCI=0.1703
2. Average molarity of three titrations.
6.1787+0.1692+0.1704+0.1619+ O.1703
MACI= 0.117
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30
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Calculate the average concentration of Vitamin C in each sample
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Acid-Base titration:
Standardization of 0.1 M NAOH
Trial 1
Mass KHP used, g
0.297 g
Final reading
Volume NaOH, mL
15.59 mL
Initial reading
Volume NaOH, mL
0.23 mL
Volume NaOH
consumed, mL
15.36 mL
Moles KHP used
Moles NaOH used
Molarity of NaOH
solution
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In the six runs indicated below 1.2 x 105 M stock solution of the crystal
violet used.
RUN
CV +
10.00 mL
6.00 mL
4.00 mL
10.00 mL
6.00 mL
B. Only III and IV are correct
OC. Only II and III are correct
BEAKER 1
D. All of the four statements are correct
O E. Only I, II, and III are correct
H ₂0
BEAKER 2
1
2
3
4
5
4.00 mL
6
4.00 mL
6.00 mL
Which of the following statements is or are correct:
I. The initial concentration of NaOH solution in the mixture of runs 1 is
0.025 M, and in runs 4 is 0.015 M
II. The initial concentration of crystal violet solution in the mixture of
runs 1 is 1.2 x 10-6 M and in runs 3 is 6.0 x 10-6 M
III. The used time range of data collection per each run is 5 min.
During this period; the temperature is assumed to remain constant.
IV. The addition of water will dilute CV +-solution, this dilution will
make runs 1 to 3 of different slopes of the inear plots of In A vs. t.
OA. Only I and III are correct
4.00 mL
6.00 mL
0.05 M NaOH
10.00 mL
10.00 mL
10.00 mL
6.00 mL…
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Data Table 2: Complexometric Titration of Tap Water
photo shows equation to find water hardness
6 ml of water used (5 ml of tap water 1ml of buffer)
Hard Water Trial 1
Hard Water Trial 2
Hard Water Trial 3
Initial Syringe Reading (mL)
2ml
2ml
2ml
Final Syringe Reading (mL)
.61ml
.69ml
.58ml
Volume of EDTA Consumed (mL)
139ml
131ml
142ml
Water Hardness
ppm CaCO3 (mg/L)
Average ppm CaCO3 (mg/L):
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Experiment :CONDUCTOMETRIC TITRATION OF A MIXTURE OF ACIDS WITH A STRONG BASE
I want the calculations for this Experiment with the graph
note: M:0.01M
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5. A 300.0 mg sample containing Na,CO3, NaHCO, and NaOH and inert material either alone or in
some combination was dissolved and titrated with 0.1000 M HCI the titration required 24.41 ml
to reach the phenolphthalein endpoint. And an additional 8.67 mL to reach the methyl red endpoint.
Determine the composition of the sample and calculate the percent of each titrated component.
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With the attached data, how do I calculate the mass percent of vinegar?
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Question 24
This problem requires a numerical answer. Type your answer into the box provided. Do not include any
units. Report the answer to two decimal places. If Canvas rounds to fewer that is ok, but you should not
do so independently.
5.00 mL of 0.100o M ammonia (NH3, K, = 1.8x10 5) is titráted with 0.100 M HNO3. Calculate the
%3D
pH after 1.00 mL of HNO3 is added.
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Related Questions
- Data for titration of 15.00 mL of vinegar with approximately 1.0 M NaOH. Note you must use the exact concentration of the standard NaOH solution to calculate the moles of NaOH. Quantity Еxample Trial 1 Trial 2 Trial 3 M NaOH (exact concentration) 0.992 M 0.953 M 0.953 M 0.953 M V initial buret reading = V, 0.20 mL 1.20 mL 0.52 mL 0.15 mL V final buret reading = V, 12.90 mL 14.22 mL 13.71 mL 13.31 mL %3D Vep = VNAOH added = V; - V, 12.70 mL 13.02 mL 13.19 mL 13.16 mL Vep = VNAOH in L 0.01270 L 0.01302 L 0.01319 L 0.01316 L moles NaOH = 0.0126 mol 0.0124 mol 0.0126 mol 0.0125 mol MNAOH X VNAOH moles AA = 0.0126 mol 0.0124 mol 0.0126 mol 0.0125 mol moles NaOH V sample = V acid 0.0150 L 0.0150 L 0.0150 L 0.0150 L (15.00 mL) (15.00 mL) (15.00 mL) Actual molarity 0.840 M 0.827 M 0.840 M 0.833 M of AA Average molarity for 3 trials => of AA 0.833 M 1. Report the acetic acid (AA) concentration of vinegar in units of molarity (M). 2. Use your average AA concentration to calculate the mass…arrow_forwardData Table 3: Complexometric Titration of Soft Water 5 ml of water 1ml of buffer Hard Water Trial 1 Hard Water Trial 2 Hard Water Trial 3 Initial Syringe Reading (mL) 1ml 1ml 1ml Final Syringe Reading (mL) 77ml 79ml 75ml Volume of EDTA Consumed (mL) .23ml .21ml .25ml Water Hardness ppm CaCO3 (mg/L) Average ppm CaCO3 (mg/L):arrow_forwardCalculate the total volume of HCl titrant delivered to the equivalence point for each trialarrow_forward
- How much calcium would you ingest by drinking one 8 oz glass of your tap water? Show all calculations.arrow_forwardConcentration sodium thiosulfate solution used: 0.056 mol L-1 ACCURATE TITRATION VOLUME OF SODIUM THIOSULFATE SOLUTION USED Volume titration 1, (ml) Volume titration 2, (mL) Your Group 15.80 15.75 Group 1 16.05 15.70 Group 2 16.30 16.25 ANALYSIS Average volume used, (mL) Standard deviation Unrounded value Rounded valuearrow_forwardPreparation and Standardization of KMnO4 solution Experimental data Complete the table below. Trial 1 0.2001 g Trial 2 0.2065 g Trial 3 Weight of sodium oxalate (Na2C2O4, MM= 134 g/mol) Titration data 0.2050 g Final reading Initial reading 29.86 mL 0.00 mL 30.66 mL 30.52 mL 0.00 mL 0.00 mL Total vol. of KMNO4 used Computed Molarity of KMNO4 solution Mean Molarity Computed Normality of KMNO4 Mean Normality of KMNO4 solution Reaction Involved: Calculations:arrow_forward
- Table 2. Titration data Trial 1 Trial 2 Trial 3 Initial burette reading (mL) 1.19 2.26 2.39 Molarity of NaOH (M) 0.100 0.100 0.100 Volume of vinegar sample (mL) 5.00 5.00 5.00 Final burette reading (mL) 48.55 49.43 49.99 Expected color at end point Volume of NaOH used (mL) Average Volume of NaOH used in liters Average moles of NaOH used (mol) Average moles of acetic acid (mol) Average molarity of acetic acid (M) Average mass of acetic acid (g) Average mass of vinegar (g) (assume the density of vinegar is 1.00 g/mL) Average mass % of acetic acid in vinegar Known mass % of acetic acid in vinegar is 5.45% Percent Errorarrow_forwardDetermine the concentration of acetic acid and vinegararrow_forwardTitration Titrant Reductant/ Oxidant Analyte Standardizing Indicator Reagent COD BOD INDIRECT TITRATIONKindly identify the blank sections appropriately.arrow_forward
- Procedure Preparation of Dilute Solution of Vinegar • Using a 10 mL pipette, transfer 10mL of vinegar into 100 mL volumetric flask. • Dilute to mark of the volumetric flask using distilled water. B. Titration of Diluted Solution of Vinegar • Transfer 25 mL of diluted solution to 250 mL Erlenmeyer flask. • Add 0.5 mL phenolphthalein indicator. Set aside. • Transfer 50mL of 0.110 M NaOH into a 50 mL burette. • Titrate the diluted solution until the phenolphthalein endpoint (very faint pink). • Record volume of NaOH used. Answer the question: What is the experimentally determined concentration of acetic acid in your vinegar solution: (Please give your answer to three significant figures.) ______ M Acetic Acidarrow_forwardAnswer if true or false , if false, put the correct answer 1. Molarity of titrant = number of moles analyte / volume of analyte 2. Two general types of titration curves are sigmoidal and linear segment 3. Tritration must occur slowly 4. Primary standard has high purity and is stable 5. Using phenlphthalein indicator, acidic to basic endpoint is usually colorlessarrow_forwardIdentify which of the graphs represent the given titration experiments best. Graph A Graph B 12 12 11- 11- 10- 10- 9- 9- 8- 8- 7- 7- 6- 6- 5- 5- 4- 3- 3- 2- 2 1 10 15 20 25 30 35 40 45 50 10 15 20 25 30 35 40 45 50 Titrant.volume Cml). Titrant.volume (mL). Answer Bank This graph does not represent a titration. a basic solution titrated with an acid an acidic solution titrated with a base Hd Hdarrow_forward
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Recommended textbooks for you
- Chemistry & Chemical ReactivityChemistryISBN:9781337399074Author:John C. Kotz, Paul M. Treichel, John Townsend, David TreichelPublisher:Cengage Learning
Chemistry & Chemical Reactivity
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ISBN:9781337399074
Author:John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
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