PAL Practice Exam 3

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Apr 3, 2024

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November 5, 2023 Dante Henneberg dchenn01@louisville.edu Chem 202-01 Dr. Craig Grapperhaus University of Louisville Practice Exam 3 (Chapters 14 & 15) 1. (14.1) The compound H 3 C 6 H 5 O 7 is citric acid. Which of the following is true about citric acid? K a1 = 7.4 x 10 -4 , K a2 = 1.7 x 10 -5 , K a3 = 4.0 x 10 -7 . a. H 2 C 6 H 5 O 7 - is a stronger base than HC 6 H 5 O 7 2- b. Three amphoteric species are in citric acid’s equilibrium series. c. The K b of C 6 H 5 O 7 3- is equal to 1/K a3 . d. HC 6 H 5 O 7 2- acid dissociation is favored over base dissociation. 2. (14.1) From the following reaction identify the conjugate acid. CH 3 OOH + HONH 2 CH 3 OO - + HONH 3 + a. CH 3 OOH b. HONH 2 c. CH 3 OO - d. HONH 3 +
3. (14.2) An aqueous solution that has a H 3 O + concentration of 4.6 x 10 -6 . Select the answer that best describes the solution. a. The solution is basic because the pOH is high. b. The solution is acidic because the pOH is high. c. The solution is basic because the pOH is low. d. The solution is acidic because the pOH is low. 4. (14.4) KHCO 3 is added to a neutral solution. The K a1 of H 2 CO 3 is 4.3 x 10 -7 and the K a2 is 4.7 x 10 -11 . Determine the net pH effect of salt when it is added to pure water. a. Potassium is neutral and bicarbonate is acidic, pH will decrease. b. Potassium is neutral and bicarbonate is basic, pH will increase. c. Potassium is acidic and bicarbonate is basic, no net pH effect. d. Potassium is basic and bicarbonate is acidic, no net pH effect. 5. (14.3) 0.05M of oxalic acid (H 2 C 2 O 4 ) solution reacts with water in an acid- base dissociation. Once the reaction reaches equilibrium, the concentration of the conjugate base is 0.0375M. What is the percent ionization of the conjugate acid? a. 25% b. 50% c. 75% d. 100%
6. (14.6) A buffer is made with 0.018M of SH 2 and 0.018M of SH - and the pH is 7. What amount of base must be added in order for the new pH of the buffer to be 100 times more acidic? K a = 9.6 x 10 -8 a. 1.8M b. 0.18M c. 0.0018M d. 0.00018M 7. (15.1) What is the solubility product of 0.45M of lead (II) iodide in water if the equilibrium amounts of the ions are both 0.008M. a. 5.12 x 10 -7 b. 1.14 x 10 -6 c. 6.40 x 10 -5 d. 1.42 x 10 -4 8. (15.1) The addition of which molecule would have no effect on the solubility of a saturated solution of MgCO 3 ? a. MgCl 2 b. MgCO 3 c. K 2 CO 3 d. Na 2 CO 3
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9. (15.1) At what concentration of Sr 2+ will the precipitate Sr(OH) 2 form in a solution with a pOH of 7.8. K sp = 6.7 x 10 -17 ? a. 4.0 x 10 -9 M b. 0.26 M c. 3.7 M d. 2.4 x 10 8 M 10. (15.3) A beaker contains the slightly soluble salt, BaF 2 , in water. HF is added to the beaker. What effect would the increase in acidity have on the solubility of BaF 2 ? K sp = 1.5 x 10 -6 , K a = 1.8 x 10 -4 . a. The solubility would increase because the new K is larger. b. The solubility would decrease because the new K is larger. c. The solubility would increase because the new K is smaller. d. The solubility would decrease because the new K is smaller.
11. (15.1) 0.34M AgCl of and 1.3 x 10 -3 of BaCl 2 are added to a solution. If Na 2 CrO 4 is added slowly to the solution will Ag 2 CrO 4 or BaCrO 4 form first? BaCrO 4 K sp = 2.1 x 10 -10 Ag 2 CrO 4 K sp = 2.6 x 10 -12 12. (14.5) H 2 SeO 3 is a weak diprotic acid that undergoes successive protonation. The K a1 is 2.4 x 10 -3 and K a2 is 4.8 x 10 -9 . Find the pH after the second dissociation if the reaction originally begins with 3 mols of H 2 SeO 3 in 1.0L of solution.
13. Ag 2 S is a slightly soluble salt with a K sp of 8.0 x 10 -15 . a. What is the molar solubility of Ag 2 S? b. The following equilibrium reaction proceeds in the same vessel as the dissolution of Ag 2 S. Does this reaction increase, decrease, or have no effect on the solubility of Ag 2 S? SH - (aq) ⇌ S 2- (aq) +H + (aq) c. If the K a of the above reaction is 9.5 x 10 -8 , what is the new K sp of Ag 2 S?
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