Gas Laws - Group Report Template

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University of New Hampshire *

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Chemistry

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Apr 3, 2024

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Molar Volume of an Ideal Gas Group Report Include your name and your lab partner’s name and submit the same file to both partners’ Canvas accounts if and only if both of you collaborated on this report. Grace Foster and Devyn Bernhard Do not modify or remove the question text. Do not use bold font in your answers. Do not use red text in your answers. 1. Submit a typed copy of your completed Table 1. Trial 1 Trial 2 Available Volume in Flask 137.714 mL 137.714 mL Mass of Mg .015g .011g Initial Pressure 1.0211 atm 1.0220 atm Maximum Pressure 1.1439 amt 1.1221 atm Pressure Change .1228 atm .1001 atm Temperature 294.1 K 294.8 K 2. Give the balanced chemical equation for the reaction performed in the flask. Be sure to indicate phases. ࠵?࠵?(࠵?) + 2࠵?࠵?࠵?(࠵?࠵?) → ࠵?࠵?࠵?࠵? ! (࠵?࠵?) + ࠵? ! (࠵?) 3. Show your calculations for the number of moles of gas evolved in your reaction for each trial performed (Data analysis step 1). Trial 1: 0.015࠵? ࠵?࠵? × !"#$ &’ ().+!’ &’ × !"#$ , ! !"#$ &’ = 6.17 × 10 -) ࠵?࠵?࠵? ࠵? ( Trial 2: 0.011࠵? ࠵?࠵? × !"#$ &’ ().+!’ &’ × !"#$ , ! !"#$ &’ = 4.52 × 10 -) ࠵?࠵?࠵? ࠵? ( 4. Show your calculations for the molar volume under the experimental conditions for each trial performed using the calculated number of moles of gas evolved in your reaction (Data analysis step 2) ࠵? .$/01 ࠵?࠵?࠵? ࠵? ( Trial 1: 2.!+33!) 4 5.!3×!2 "# "#$ , ! = 223 4 "#$ Trial 2: 2.!+33!) 4 ).7(×!2 "# "#$ , ! = 305 4 "#$ 5. Show your calculations for the standard molar volume resulting from each trial performed using the combined gas law. Trial 1 Trial 2
(.1228)(223.199) 294.1 ࠵? 1 ࠵?࠵?࠵? ∗ ࠵? 2 273.15 ࠵? = 25.4࠵?࠵?࠵?/࠵? (.1001)(305) 294.8 ࠵? 1 ࠵?࠵?࠵? ∗ ࠵? 2 273.15 = 28.2884 ࠵?࠵?࠵?/࠵? 6. The actual standard molar volume of an ideal gas is about 22.41 L/mol. Show how this number can be calculated from the ideal gas law ( PV = nRT ) and the value of the gas constant, ࠵? = ࠵?. ࠵?࠵?࠵?࠵?࠵? L∙atm mol∙K . ( Hint: remember that the molar volume (V m ) is equal to ࠵? ࠵? , and remember what “standard” tells you about the other variables in the equation ) ࠵? = ࠵?࠵?࠵? ࠵? ࠵? = (1࠵?࠵?࠵?)(0.08206 ࠵? ∙ ࠵?࠵?࠵? ࠵?࠵?࠵? ∙ ࠵? )(273.15࠵?) (1࠵?࠵?࠵?) = 22.41 ࠵? ࠵?࠵?࠵? 7. Find the percent error in the measured standard molar volume for each of your two trials. Review Appendix A if needed for how to calculate percent error. % ࠵?࠵?࠵?࠵?࠵? = |࠵?࠵?࠵?࠵?࠵?| ࠵?࠵?࠵?࠵?࠵?࠵? × 100 Trial 1: |(7.)-((.)!| ((.)! × 100 = 13.3% Trial 2: |(C.+-((.)!| ((.)! × 100 = 26.3% 8. The most common zinc ore in nature is sphalerite, a mineral with the chemical formula ZnS. One method of processing zinc metal from its ore involves first reacting the sphalerite with O 2 gas to form zinc oxide, ZnO, and sulfur dioxide. a. Write the balanced chemical equation. 2࠵?࠵?࠵? + 3࠵? ! → 2࠵?࠵?࠵? + ࠵?࠵? ! b. If 657 kg of sphalerite is reacted, what standard volume of oxygen is needed to carry out this reaction? Show your work. ࠵?࠵?࠵?࠵?࠵? ࠵?࠵?࠵?࠵? ࠵?࠵? ࠵?࠵?࠵? = 97.474 ࠵?/࠵?࠵?࠵? 657,000࠵? 97.474࠵?/࠵?࠵?࠵? = 6,740.26 ࠵?࠵?࠵?࠵?࠵? ࠵?࠵? ࠵?࠵?࠵? ࠵?࠵?࠵?࠵?࠵? ࠵?࠵? ࠵? ! ࠵?࠵?࠵?࠵?࠵?࠵?࠵?࠵? = 6,740.26 ࠵?࠵?࠵?࠵?࠵? ࠵?࠵? ࠵?࠵?࠵? ∗ # %&’() * ! ! %&’() +,- = 10110.39 moles of ࠵? 2 10110.39 ࠵?࠵?࠵? ࠵? ! + 22.4 ࠵?/࠵?࠵?࠵? = 2.26* 10 5 ࠵?࠵?࠵?࠵?࠵?࠵? ࠵?࠵? ࠵? 2
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