3 Draw the phase diagram for metals (A, B) with melting points (1180°C, 1455°C respectively). They are completely soluble in each other in solid stale. Follow un the cooling of allov with 60% B:
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- a concentrated H2SO4 has the following composition specific gravity 1.84 and purity of H2SO4 is 97 percent by weight. express in mole/LDetermine the percentage Fe in a sample of limonite from the following data:Sample : 0.5000g ; KMnO4 used = 50.00 ml ; 1.000ml of KMnO4 is equivalent 0.005317 g Fe,FeSO4 used = 6.00 ml; 1.000ml FeSO4 is equivalent 0.009200 g FeO ( ans 44.59 %)BINARY PHASE DIAGRAMS Please answer ALL parts with as much explanation as possible, showing full working out.a)(i) What is the melting point of pure Mg?(ii) What is the maximum solubility of Mg in Pb and at what temperaturedoes this occur? (b) A 50 wt.% Pb-50wt% Mg alloy is slowly cooled from 700 °C to 400 °C.(i) At what temperature does the first solid phase form?(ii) What is the composition of this solid phase?(iii) At what temperature does all the liquid solidify?(iv) What is the composition of the last remaining liquid phase?(v) What is the freezing range? (c) What is the mass fraction of solid and liquid of a 60 wt.% Mg alloy at atemperature of 500 °C.(d) Draw and label the microstructure of an 80 wt.% Mg alloy at 600 °C.(e) A Mg-Pb alloy of mass 5.5 kg has a composition just slightly below thesolubility limit of 200 °C.(i) What mass of lead is in the alloy?(ii) If the alloy is heated to 350 °C how much more lead can be dissolvedin the α phase without exceeding the solubility…
- The %purity of a powdered crude sample of Na2CO3 containing only inert impurities is to be determined by reacting 225.0 mg of the crude sample to 10.0 mL of 3.00 M HCl solution, and bubbling the resulting CO2(g) product in water that is at exactly 29 °C. After the reaction has completed, the level of the liquid inside the eudiometer rests 4.30 cm above the water level in the beaker. The graduation on the eudiometer indicates that the trapped gas is 44.37 mL. The experiment was done under a barometric pressure of 755.2 torr. a. How many moles of CO2 were collected? b. What is the percent purity of the sample? Round off to the nearest whole numberThe %purity of a powdered crude sample of Na2CO3 containing only inert impurities is to be determined by reacting 225.0 mg of the crude sample to 10.0 mL of 3.00 M HCl solution, and bubbling the resulting CO2(g) product in water that is at exactly 29 °C. After the reaction has completed, the level of the liquid inside the eudiometer rests 4.30 cm above the water level in the beaker. The graduation on the eudiometer indicates that the trapped gas is 44.37 mL. The experiment was done under a barometric pressure of 755.2 torr. What CASE does this experiment satisfy?Given the solubility of ferrihydrite (Fe(OH)3) and goethite (FeOOH), with dissolution reactions shown below: [1] Fe(OH)3 3 H+ à Fe3+ + 3 H2O Ksp = 8.4 x 10^4 ∆ Gr0 = -28 KJ/mol Solubility of Fe(OH3) = 7.468 [2] FeOOH + 3 H+ à Fe3+ + 2 H2O Ksp = 8.8 x 10^-2 ∆ Gr0 = 6 KJ/mol Solubility of FeOOH = 0.353 QUESTION: [A] How much Fe3+ from ferrihydrite would dissolve at pH 2 ? [B] How much Fe3+ from ferrihydrite would dissolve at pH 7 ? [C] How much Fe3+ from goethite would dissolve at pH 2 ? [D] How much Fe3+ from goethite would dissolve at pH 7 ?
- Suppose you have a soil that is made up of 10% organic matter with CEC = 200 cmol/kg, 40% kaolinitewith CEC = 10 cmol/kg, and 50% vermiculite with CEC = 100 cmol/kg.1- Calculate the overall CEC of the soil by taking a weighted average of the three soil components.2- What percentage of the overall CEC is contributed by the organic matter? How does that numbercompare to the 10% of the soil itself that is organic?In a solution containing 25ml (NH4)2S2O8 with a total volume = 100 ml =0.1 liters , the solution composition are shown below.Note; the solution require 25ml of 0.2M S2O8^-2.SOLUTION Kl KNO3 EDTA Na2S2O3 STARCH50ml 23ml 1 drop 1 ml 10 dropsExperiment; initial (S2O8-2) =0.05M ; INITIAL (l-)=0.10 Mml of S2O3^-2 added Time in minutes and seconds for color change Cumulative time in seconds Total moles of S2O8^-2 consumed1 1:43 2.0 x 10^-42 1:20 4.0 x 10^-43 1:13 6.0 x 10 ^-44 1.17 8.0 x 10 ^-45 1.24 10 x 10 ^-41a) Find the cumulative time in secondsb) for the runs ,plot mole of S2O8^2- REACTION vs. time in seconds2) Draw a straight line through ( origin ) the points and calculate the slope3) divide the value of the slope by the total volume of ( 0.1 L) to get the rate in units of M/s4) find the rate5 )calculate x and y and kgiven that 7.0g of Pb and 3.0g of Sn is mixed identify the following: a.) mass in Pb-rich phase and Sn rich phase at 100 degC b.) mass in melt phase and Pb-rich phase at 200degC
- TRUE OR FALSE __________ 11. The minimum number of centrifuge tubes in a centrifuge machine during its operation is one. __________ 12. Never place reagents directly onto the weighing pan of a balance, always use weighing paper, a beaker, or some other container. __________ 13. To transfer a solution, the stirring rod touches the delivery point of the reagent vessel and the wall of the receiving vessel. __________ 14. An open flame is the heat source for heating or evaporating flammable liquids. __________ 15. Most chemicals used in experiments can be discarded into the sink.The % purity of a powdered crude sample of Na^2CO^3 containing only inert impurities is to be determined by reacting 225.0 mg of the crude sample to 10.0 mL of 3.00 M HCl solution, and bubbling the resulting CO2(g) product in water that is at exactly 29 °C. After the reaction has completed, the level of the liquid inside the eudiometer rests 4.30 cm above the water level in the beaker. The graduation on the eudiometer indicates that the trapped gas is 44.37 mL. The experiment was done under a barometric pressure of 755.2 torr. Write the balanced chemical equation of the reaction in your solutions sheet. What is the sum of all the coefficients of the balanced chemical equation? Determine the pressure of the trapped gas inside the eudiometer in mmHg. Determine the partial pressure of the collected CO^2 in mm Hg. How many millimoles of CO^2 was collected? What is the % purity of the sample to the nearest whole number?The % purity of a powdered crude sample of Na^2CO^3 containing only inert impurities is to be determined by reacting 225.0 mg of the crude sample to 10.0 mL of 3.00 M HCl solution, and bubbling the resulting CO2(g) product in water that is at exactly 29 °C. After the reaction has completed, the level of the liquid inside the eudiometer rests 4.30 cm above the water level in the beaker. The graduation on the eudiometer indicates that the trapped gas is 44.37 mL. The experiment was done under a barometric pressure of 755.2 torr. What is the % purity of the sample to the nearest whole number?