(a) For use in an iodine titration, you prepare a solution from 0.222 2 (+0.000 2) g of KIO3 [FM 214.001 0 (+0.000 9)] in 50.00 (+0.05) mL. Find the molarity and its uncertainty with an appropriate number of significant figures. (b) Would your answer be affected significantly if the reagent were only 99.9% pure?

(a) For use in an iodine titration, you prepare a solution from 0.222 2 (+0.000 2) g of KIO3 [FM 214.001 0 (+0.000 9)] in 50.00 (+0.05) mL. Find the molarity and its uncertainty with an appropriate number of significant figures. (b) Would your answer be affected significantly if the reagent were only 99.9% pure?

Fundamentals Of Analytical Chemistry

9th Edition

ISBN:9781285640686

Author:Skoog

Publisher:Skoog

Chapter16: Applications Of Neutralization Titrations

Section: Chapter Questions

Problem 16.18QAP

See similar textbooks

Similar questions

A stock solution of 0.225 +/- 0.003 M NaNO2 was transferred to a 100 mL volumetric flask (class A) and diluted to the mark. If 7 mL of the stock solution was transferred using one 5-mL and two 1-mL volumetric pipettes, what is the new concentration of the solution and the uncertainty? Please show how to calculate the uncertainty, that is the one part I don't understand how to do
Analytical chemistry is a particular field within the broader spectrum of the chemical sciences, in which many times the focus of analytical experiments is to develop new methods to analyze compounds, either structurally or by determining concentrations of compounds. One of the processes analytical chemists use to determine the exact concentration of a working solution is called standardization. In your own words, describe the differences between a primary, secondary, and tertiary standard, and describe the underlying concept behind the standardization process. Why is it done?
After creating her standard curve for absorption versus the concentration (M) of FD&C Red 40 and processing her data, Sally found that her drinking strength Kool-Aid sample had a concentration of 4.692 x 10–5 M. If 0.132 grams of Kool-Aid powder was used to prepare an 8-fl oz cup of her assigned flavor, what is the percent by mass of FD&C Red 40 in her Kool-aid powder? Report your answer as a percentage with two places after the decimal. Do not include the percentage sign in your answer. Pay attention to units. You are trying to find the mass percentage of red dye, so you need to know each variable in the equation in Appendix B. Note that the percent by mass equation should be multiplied by 100. There may be some useful conversion factors in the experimental procedure.
1. A student performed this experiment and obtained the following concentration values: 0.02813 M, 0.02802, and 0.02788 M a. what is the mean concentration? b. what is the standard deviation of these results? 3. how would the following errors affect the concentration of Cl- obtained in question 2b? give your reasoning in each case. a. the student read the molarity of AgNo3 as 0.02104M instead of 0.02014M b. the student was past the endpoint of titration when he took the final buret reading.
A stock solution of 0.225 +/- 0.003 M NaNO2 was transferred to a 100 mL volumetric flask (class A) and diluted to the mark. If 7 mL of the stock solution was transferred using one 5-mL and two 1-mL volumetric pipettes, what is the new concentration of the solution and the uncertainty?
A volumetric calcium analysis on triplicate samples of the blood serum of a patient believed to be suffering from a hyperparathyroid condition produced the following data: mmol Ca/L = 3.15, 3.25, 3.26. What is the 95% confidence interval for the mean of the data, assuming no prior information about the precision of the analysis?
4.Discussed the Purposed of the Golden rules in the practice of Forensic Chrmistry.
What are the differences between systematic and random errors and how do they effect accuracy and precision? In what circumstances would you use standard addition (versus a normal calibration curve) to determine the amount of an analyte in a sample? A urine sample, containing analyte Z is analysed by the standard addition method where 5 mL of the original sample was mixed with increasing amounts of a Z standard and each solution diluted to a volume of 50 mL prior to analysis. A plot of the final concentration of the standard in each of the 50 mL samples (x axis) versus The measured signal from the analysis of each 50 mL sample (on y axis) produced a straight line with the general equation: y = 44.72x + 4.06 what was the final concentration of Z in the 50 mL standard addition sample? what was the initial concentration of Z in the original urine sample?
An excess of 0.34 mg Pb is obtained from an assay test determined in an analysis. What is the percent relative error in ppt if the mass of the sample is 550 g?
A method for the detection of morphine is used to generate a calibration curve in which the assay response (y) is plotted versus morphine concentration (x, in mg/L). This gives a straight line with a slope (m) of 0.241 and a y-intercept (b) of 0.011, where y = mx + b. The slope of this line has a standard deviation of ±0.007, and the standard deviation of the intercept is ±0.006. If the sample from an athlete gives a response of 0.506 ± 0.013 in this method, what is the concentration of morphine in the sample and estimated precision of this concentration?
Consider the titration illustrated in Figure 8.] Anhydrous sodium carbonate (Na₂CO₃) is a primary standard. When 0.364 grams of the substance is placed in a conical flask, then 20.00 cm³ of sulphuric acid (H₂SO₄) solution is required to reach the end point of the titration. What is the concentration in mol·dm⁻³ of the sulphuric acid solution? [Give the answer to 3 decimal places. Do not type in the unit. Use a decimal point.] *
After creating her standard curve for absorption versus the concentration (M) of FD&C Red 40 and processing her data, Sally found that her drinking strength Kool-Aid sample had an FD&C Red 40 concentration of 1.086 x 10–5 M. If 0.133 grams of Kool-Aid powder was used to prepare an 8-fl oz cup of her assigned flavor, what is the percent by mass of FD&C Red 40 in her Kool-aid powder?