CH3CH2OH + D½O → CH3CH2OD + HOD What is the best way of showing that this reaction has occurred? A. By testing the product with phosphorus pentachloride and not getting steamy fumes. B. By determining the mass spectrum of the mixture and showing peaks at m/z values of 20 and 46. C. By fractionally distilling the mixture and determining the amount of CH3CH2OD using a Geiger counter. D. By determining the mass spectrum of the mixture and showing peaks at m/z values by 19 and 47.

Organic Chemistry: A Guided Inquiry
2nd Edition
ISBN:9780618974122
Author:Andrei Straumanis
Publisher:Andrei Straumanis
Chapter17: Conjugation And Molecular Orbital (mo) Theory
Section: Chapter Questions
Problem 12E
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40. Deuterium oxide, D20, is water that contains the stable hydrogen isotope 2H,
usually shown as D. When dissolved in deuterium oxide, ethanol undergoes the
following reaction: *
CH3CH2OH + D½0 →
CH;CH2OD + HOD
What is the best way of showing that this reaction has occurred?
A. By testing the product with phosphorus pentachloride and not getting steamy fumes.
B. By determining the mass spectrum of the mixture and showing peaks at m/z values of 20
and 46.
C. By fractionally distilling the mixture and determining the amount of CH3CH2OD using a
Geiger counter.
D. By determining the mass spectrum of the mixture and showing peaks at m/z values by 19
and 47.
A
В
O D
Transcribed Image Text:40. Deuterium oxide, D20, is water that contains the stable hydrogen isotope 2H, usually shown as D. When dissolved in deuterium oxide, ethanol undergoes the following reaction: * CH3CH2OH + D½0 → CH;CH2OD + HOD What is the best way of showing that this reaction has occurred? A. By testing the product with phosphorus pentachloride and not getting steamy fumes. B. By determining the mass spectrum of the mixture and showing peaks at m/z values of 20 and 46. C. By fractionally distilling the mixture and determining the amount of CH3CH2OD using a Geiger counter. D. By determining the mass spectrum of the mixture and showing peaks at m/z values by 19 and 47. A В O D
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