Consider the following reactions:CO (g) + H2O (g) <-> CO2 (g) + H2 (g) | Kp(1) = 0.694 at 1200.KC3H8 (g) + 3 H2O (g) <-> 3 CO (g) + 7 H2(g) | Kp(2) = 8.175 x 1015 at 1200.KUsing the overall reaction from above and Le Chatelier’s principle, predict which direction the reaction will shift to reestablish equilibrium for each of the following changes:Carbon dioxide is increased. Propane is decreased.The reaction is placed in a dehydration chamber (which siphons off water). If the pressure in the reaction container is doubled.Calculate the enthalpy of reaction for this reaction using the standard thermodynamics values for the reactants and products. Is the reaction endothermic or exothermic?Now, use Le Chatelier’s principle again to determine the direction the equilibrium will shift if heat is added to the reaction. If 35 kPa of propane is mixed with 35 kPa of steam in a 1.5 L container at 1200. K, what is the theoretical yield of carbon dioxide?

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Answered: Consider the following reactions: CO…

Chemistry: The Molecular Science

5th Edition

ISBN:9781285199047

Author:John W. Moore, Conrad L. Stanitski

Publisher:John W. Moore, Conrad L. Stanitski

Chapter9: Liquids, Solids, And Materials

Section: Chapter Questions

Problem 45QRT: At the critical point for carbon dioxide, the substance is very far from being an ideal gas. Prove...

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Consider the following reactions:

CO (g) + H₂O (g) <-> CO₂ (g) + H₂ (g) | K_p(1) = 0.694 at 1200.K

C₃H₈ (g) + 3 H₂O (g) <-> 3 CO (g) + 7 H₂(g) | K_p(2) = 8.175 x 10¹⁵ at 1200.K

Using the overall reaction from above and Le Chatelier’s principle, predict which direction the reaction will shift to reestablish equilibrium for each of the following changes:

Carbon dioxide is increased.
Propane is decreased.
The reaction is placed in a dehydration chamber (which siphons off water).
If the pressure in the reaction container is doubled.
Calculate the enthalpy of reaction for this reaction using the standard thermodynamics values for the reactants and products. Is the reaction endothermic or exothermic?
Now, use Le Chatelier’s principle again to determine the direction the equilibrium will shift if heat is added to the reaction.
If 35 kPa of propane is mixed with 35 kPa of steam in a 1.5 L container at 1200. K, what is the theoretical yield of carbon dioxide?

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