Data Report Sheet: Spectrophotometric Determination of an Equilibrium Constant. Part A: Determination ofa Calibration Curve: I puIS (OH) Std. 2 Stnd. 3 Stnd. 5 Stnd. 6 + puis 0600000 0.000106 0.000127 0.000189 0.000204 |Fe(SCN)"] Column A 0.432 0.480 0.633 0.831 0.887 Absorbance Column E y= 4339.8x + 0.0258 Equation of Calibration Line: Correlation Coefficient: 4339.8 Slope (br): Part B: Determination ofK Expt. 1 Expt. 2 Expt. 3 Expt. 4 Expt. 5 0.00165 0.00165 0.00165 0.00165 0.00165 (Table 1) 0.00033 0.00132 0.00165 990000 66000'0 (Table 1) [Fe(SCN) laqui 0.290 0.524 0.803 1.024 66 Column F |Fe"lqt 190000 ISCNle 148.6799 135.1678 142.2659 141.8466 134.2843 Average K:140 448

Fundamentals Of Analytical Chemistry
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Chapter7: Statistical Data Treatment And Evaluation
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Problem 7.10QAP
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Complete chart for Part B: Determination  of  K

Data Report Sheet: Spectrophotometric Determination of an Equilibrium
Constant.
Part A: Determination of a Calibration Curve:
I puIS
(H)
0.000090 0.000106 0.000127
Std. 2
Stnd. 3
Stnd. 5
Stnd. 6
t puis
0.000189 0.000204
|Fe(SCN)"]
Column A
0.432
0.480
0.633
0.831
0.887
Absorbance
Column E
y= 4339.8x + 0.0258
Equation of Calibration Line:
Correlation Coefficient:
4339.8
Slope (bɛ):
Part B: Determination of K
Expt. 1
Expt. 2
Expt. 3
Expt. 4
Expt. 5
0.00165
0.00165
0.00165
0.00165
0.00165
(Table I)
0.00033
0.00132 0.00165
9900000
66000'0
(Table 1)
|Fe(SCN)*"laqui.
0.290
0.524
0.803
1.024
Column F
mba
|Fe lequt
1900000
|SCN'legu
148.6799
135.1678 142.2659 141.8466
134.2843
Average K:140 448
6.
Transcribed Image Text:Data Report Sheet: Spectrophotometric Determination of an Equilibrium Constant. Part A: Determination of a Calibration Curve: I puIS (H) 0.000090 0.000106 0.000127 Std. 2 Stnd. 3 Stnd. 5 Stnd. 6 t puis 0.000189 0.000204 |Fe(SCN)"] Column A 0.432 0.480 0.633 0.831 0.887 Absorbance Column E y= 4339.8x + 0.0258 Equation of Calibration Line: Correlation Coefficient: 4339.8 Slope (bɛ): Part B: Determination of K Expt. 1 Expt. 2 Expt. 3 Expt. 4 Expt. 5 0.00165 0.00165 0.00165 0.00165 0.00165 (Table I) 0.00033 0.00132 0.00165 9900000 66000'0 (Table 1) |Fe(SCN)*"laqui. 0.290 0.524 0.803 1.024 Column F mba |Fe lequt 1900000 |SCN'legu 148.6799 135.1678 142.2659 141.8466 134.2843 Average K:140 448 6.
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