Extension Questions 1. A sample with an unknown concentration of Cr(NO3)3 has an absorbance of 0.68 at A of 426 nm. A calibration curve was produced for Cr(NO3)s and is shown below in Figure 1. Absorbance 0.5 4.63E-03*x + 4.4E-03 0.4 0.3 0.2 0.1 0 25 50 75 100 Concentration (mM) Figure 1. Calibration curve for Cr(NO) collected at 426 nm a. Determine the molar absorptivity (E) ifa 1.5 cm path length cuvette was used to collect data. Utilize the slope of the calibration curve above to determine the molar absorptivity value. b. Determine the concentration (mM) of Cr(NO3) in the unknown solution. n 9 c. A different lab group used a 1.0 cm path length cuvette in the preparation of a calibration curve using the same concentrations of Cr(NO3)3 space below, quantitatively draw out what the new calibration curve would look like. as in Figure 1. In the Include the axes labels and numerical values. Absorbance

Appl Of Ms Excel In Analytical Chemistry
2nd Edition
ISBN:9781285686691
Author:Crouch
Publisher:Crouch
Chapter4: Least-squares And Calibration Methods
Section: Chapter Questions
Problem 11P
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Please answer all the parts of the question that correspond to number 1 (a, b and c). Please show all work and explain all the steps.

 

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Extension Questions
1. A sample with an unknown concentration of Cr(NO3)3 has an absorbance of 0.68 at A
of 426 nm. A calibration curve was produced for Cr(NO3)s and is shown below in
Figure 1.
Absorbance
0.5
4.63E-03*x + 4.4E-03
0.4
0.3
0.2
0.1
0
25
50
75
100
Concentration (mM)
Figure 1. Calibration curve for Cr(NO) collected at 426 nm
a. Determine the molar absorptivity (E) ifa 1.5 cm path length cuvette was used to
collect data. Utilize the slope of the calibration curve above to determine the molar
absorptivity value.
b. Determine the concentration (mM) of Cr(NO3) in the unknown solution.
n
9
c. A different lab group used a 1.0 cm path length cuvette in the preparation of a
calibration curve using the same concentrations of Cr(NO3)3
space below, quantitatively draw out what the new calibration curve would look like.
as in Figure 1. In the
Include the axes labels and numerical values.
Absorbance
Transcribed Image Text:Extension Questions 1. A sample with an unknown concentration of Cr(NO3)3 has an absorbance of 0.68 at A of 426 nm. A calibration curve was produced for Cr(NO3)s and is shown below in Figure 1. Absorbance 0.5 4.63E-03*x + 4.4E-03 0.4 0.3 0.2 0.1 0 25 50 75 100 Concentration (mM) Figure 1. Calibration curve for Cr(NO) collected at 426 nm a. Determine the molar absorptivity (E) ifa 1.5 cm path length cuvette was used to collect data. Utilize the slope of the calibration curve above to determine the molar absorptivity value. b. Determine the concentration (mM) of Cr(NO3) in the unknown solution. n 9 c. A different lab group used a 1.0 cm path length cuvette in the preparation of a calibration curve using the same concentrations of Cr(NO3)3 space below, quantitatively draw out what the new calibration curve would look like. as in Figure 1. In the Include the axes labels and numerical values. Absorbance
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