A student completed Test Solution 1: 2.5 mL of 2.00×10−32.00×10−3 M Fe(NO3)3Fe(NO3)3 mixed with 0.5 mL of 2.00×10−32.00×10−3 M NaSCNNaSCN and topped with 2.0 mL of 0.1 M HNO3HNO3 to make a total of 5.0 mL solution. The absorbance of the solution was measured, and the calibration curve was used to calculate [FeSCN2+][FeSCN2+] at equilibrium. Concentration of [FeSCN2+][FeSCN2+] at equilibrium was 7.5×10−57.5×10−5 M. Complete the given chart and the calculation that follows.   initial [Fe3+], M2=   initial SCN[Fe3+], M2=   M Fe3+Fe3+ + SCN−SCN− ↽−−⇀↽−−⇀ FeSCN2+FeSCN2+ Initial       Change       Equilibrium             Calculate the equilibrium Kc for this reaction (to two significant figures

Principles of Instrumental Analysis
7th Edition
ISBN:9781305577213
Author:Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Publisher:Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Chapter9: Atomic Absorption And Atomic Fluorescence Spectrometry
Section: Chapter Questions
Problem 9.21QAP
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A student completed Test Solution 1: 2.5 mL of 2.00×10−32.00×10−3 M Fe(NO3)3Fe(NO3)3 mixed with 0.5 mL of 2.00×10−32.00×10−3 M NaSCNNaSCN and topped with 2.0 mL of 0.1 M HNO3HNO3 to make a total of 5.0 mL solution. The absorbance of the solution was measured, and the calibration curve was used to calculate [FeSCN2+][FeSCN2+] at equilibrium. Concentration of [FeSCN2+][FeSCN2+] at equilibrium was 7.5×10−57.5×10−5 M. Complete the given chart and the calculation that follows.

 

initial [Fe3+], M2=
 
initial SCN[Fe3+], M2=
 
M
Fe3+Fe3+ + SCN−SCN− ↽−−⇀↽−−⇀ FeSCN2+FeSCN2+
Initial      
Change      
Equilibrium      
 
 
 
Calculate the equilibrium Kc for this reaction (to two significant figures
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