Answered: P17E.6 The oxidation of NO to NO2,… | bartleby

Fundamentals Of Analytical Chemistry

Fundamentals Of Analytical Chemistry

9th Edition

ISBN:9781285640686

Author:Skoog

Publisher:Skoog

Chapter30: Kinetic Methods Of Analysis

Section: Chapter Questions

Problem 30.9QAP

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P17E.6 The oxidation of NO to NO2, 2NO(g) +O,(g)-> 2NO 2 (g), proceeds by
the following mechanism:
NO +NO- N,O2
kg
KA
N2O2
NO + NO
a
N,O2+O2-> NO2+ NO2
kg
Verify that application of the steady-state approximation to the intermediate
N2O2 results in the rate law
2k k,[NOPIO,]
d[NO21
K+k,[O2]
dt

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