The rate law for the reaction 2NO (g) + Cl2 (g) → 2NOCI (g) rate = k[NO][Clz] a) Given the information above, explain why this reaction must occur in more than one step.

Biochemistry
6th Edition
ISBN:9781305577206
Author:Reginald H. Garrett, Charles M. Grisham
Publisher:Reginald H. Garrett, Charles M. Grisham
Chapter19: The Tricarboxylic Acid Cycle
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4.
The rate law for the reaction n od or sieb intooniei (mog
vEw fnot
2NO (g) + Cl2 (g) → 2NOC1 (g)
(3)
is
rate = k[NO][C2]
a) Given the information above, explain why this reaction must occur in more than
one step.
A proposed mechanism for this reaction is:
i.
NO (g) + Cl2 (g) → NOC2 (g)
ii.
NOCI2 (g) + NO (g) → 2NOCI (g)
b) Which of the two steps must be the slow step? Explain your answer.
olo rbo ad i teW (s
c) Identify any intermediates in this proposed mechanism.
d) What is the molecularity of each step in the mechanism?
Transcribed Image Text:4. The rate law for the reaction n od or sieb intooniei (mog vEw fnot 2NO (g) + Cl2 (g) → 2NOC1 (g) (3) is rate = k[NO][C2] a) Given the information above, explain why this reaction must occur in more than one step. A proposed mechanism for this reaction is: i. NO (g) + Cl2 (g) → NOC2 (g) ii. NOCI2 (g) + NO (g) → 2NOCI (g) b) Which of the two steps must be the slow step? Explain your answer. olo rbo ad i teW (s c) Identify any intermediates in this proposed mechanism. d) What is the molecularity of each step in the mechanism?
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