The reduction potentials of iron in each of the cytochromes in the electron transport complexesvary from 0.The reduction potentials of iron in each of the cytochromes in the electron transport complexes vary from 0.1 V to 0.39 V. Explain why these different values are necessary for the operation of this process
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The reduction potentials of iron in each of the cytochromes in the electron transport complexes
vary from 0.The reduction potentials of iron in each of the cytochromes in the electron transport complexes
vary from 0.1 V to 0.39 V. Explain why these different values are necessary for the operation of
this process
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- The Overall Free Energy Change for Photosynthetic NADP+ Reduction What is the overall free energy change (G) for noncyclic photosynthetic electron transport? 4 (700-nm photons) + 4 (680-nm photons) + 2 H2O + 2 NADP+O2 + 2 NADPH + 2H+Under standard conditions, NADH reoxidation by the electron-transport chain has a free-energy change equal to –220 kJ/mol. With 100% efficiency, how many ATP could be synthesized under standard conditions? What is the "actual" efficiency given these numbers?It is estimated that each electron pair donated by NADH leads to the synthesis of approximately three ATP molecules, whereas each electron pair donated by FADH2 leads to the synthesis of approximately two ATP molecules. What is the underlying reason for the difference in yield for electrons donated by FADH2 versus NADH?
- For the Complex III in the electron transport chain: Complex III step 1: UQH2 is oxidized in a 2 electron process. Cytochrome c is reduced and UQ is reduced to UQH in two 1 electron processes. Complex III step 2: UQH2 is oxidized in a 2 electron process. Cytochrome c is reduced and UQH is reduced to UQH2 in two 1 electron processes. The necessary standard reduction potentials are: UQ + 2H+ + 2e- UQH2 E° = 0.06 V cyt c (Fe3+) + e- cyt c (Fe2+) E° = 0.254 V UQ + H+ + e- UQH. E° = 0.03 V UQH. + H+ + e- UQH2 E° = 0.19 V Calculate the total redox potential of the complex. Now calculate how many moles of protons can be translocated across the inner mitochondrial membrane if translocation of 1 mole requires 23 kJ. Calculate the free energy available for proton translocation assuming a 2electron process for each complex.A new ATP-producing protein is discovered that couples ATP production to the oxidation of NADPH by oxidative phosphorylation. Assume that the value of ΔGo for ATP synthesis is 30 kJ•mol−1. If this protein only produces 1 molecule of ATP per reaction that consumes one NADPH: a. How much free energy is wasted, under standard conditions?b. How many more ATP molecules could be created by a perfectly efficient electron transport chain from one NADPH?A newly identified bacterium is unable to synthesize ubiquinone. A mobile electron carrier called CXC3 is used as a substitute. From the information provided in the table, calculate the delta G knot prime and the Keq value at 298 K for the redox reaction that occurs in this bacterium’s electron transport chain. Explain the impact that using CXC 3 instead of ubiquinol will have on ATP production in the cell. How might this cell adapt to this situation?
- Which of the following statements concerning the complete oxidation of FADH2 in the electron transport chain is NOT true? a. In the final step, electrons from cytochrome c to O2 reducing it to H2O in complex IV, and four protons are transported from the intermembrane space to the matrix. b. In the first step, electrons from FADH2 are transferred in complex II to ubiquinone, which does not transport any proton across the inner mitochondrion membrane. c. In the second step, complex III transfers the electrons from ubiquinone to cytochrome c, and four protons are transported from the matrix to the intermembrane space. d. The complete oxidation of FADH2 causes transfer of 6 protons and yields two ATP.a newly identified bacterium called Nomore biochem is unable to synthesize ubiquinone. A mobile electron carrier called CXC3 is used as a substitute. From the information provided in the table, calculate delta G' and Keq value at 298K for the redox reaction that occurs in the Nomore Biochem electron transport chain. (constants: R=8.3 J/degree x mol, F= 96.1 kJ/v x mol Half Reactions E' (V) ubiquinone + 2e- + 2H+--> Ubiquinol + H2 0.045 NAD+ + 2e- + 2H+ --> NADH + H+ -0.320 CXC3 + 2e- + 2H+ --> CXC3H2 -0.450 explain the impact that using CXC3 instead of ubiquinone will have on ATP production in the cell. How might the cell adapt to this situation?What is the oxidative phosphorylation coefficient? indicate the oxidative phosphorylation coefficient of the primary electron donors in krebs cycle
- In chloroplasts, a greater pH gradient across the thylakoid membrane is required to power the synthesis of ATP than is required across the mitochondrial inner membrane. Explain this difference.Some anaerobic prokaryotes use nitrate (NO3- ) as the terminal electronacceptor for energy metabolism. Assuming 100% effi ciency, how much ATP could be synthesized by the oxidation of NADH by nitrate?The inhibitor X prevents coenzyme Q (Q) from participating in electron transfer in the electrontransport chain.(a) Will the presence of X prevent electrons from N ADH from passing through the electron trans-port chain? Explain why or why not.(b) Compound Y is a non-physiological reducing agent capable of directly reducing cytochromec1 in Complex III. Would oxygen consumption resume upon the addition of compound Y tomitochondria inhibited by inhibitor X? Be sure to explain your answer.