Why must x be small to use the Henderson-Hasselbalch equation

Physical Chemistry
2nd Edition
ISBN:9781133958437
Author:Ball, David W. (david Warren), BAER, Tomas
Publisher:Ball, David W. (david Warren), BAER, Tomas
Chapter20: Kinetics
Section: Chapter Questions
Problem 20.82E: Show that another form of the Michaelis-Menten equation is rate=V[S]K+[S]
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Why must x be small to use the Henderson-Hasselbalch equation

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