General Chemistry
General Chemistry
4th Edition
ISBN: 9781891389603
Author: Donald A. McQuarrie, Peter A. Rock, Ethan B. Gallogly
Publisher: University Science Books
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Chapter 1, Problem 1.38P

(a)

Interpretation Introduction

Interpretation:

SI unit conversion has to be performed for 325feet to meters and expressed in correct number of significant figures.

Concept Introduction:

Conversion factors:

Conversion of one unit into another unit is done by the use of unit conversion factor.  This involves multiplying or dividing by the power of 10.  For example, if centimeter has to be converted into meter, then the given value in centimeter has to be multiplied by the conversion factor as shown below.

    1=1m100cm

Significant figures:

Precision of the quantities that are measured use the significant figures to express the result.  There are six rules for determining the number of significant figures.  They are given as follows.

  • Nonzero digits and the zeros that are present between nonzero digits are significant.
  • Zeros that are used merely to position the decimal are not significant.
  • If zeros are present in the right end of the decimal point, then the zeros are significant.
  • If zeros are present in the result are not in right of the decimal point, then the zeros may or may not be significant.
  • If the zeros disappear when scientific notation is used means then those zeros are not significant.
  • Exact numbers have no limit to their precision and they do not obey the rules given for significant figures.

Answer for a calculation should be always expressed in least significant figures in case of multiplication and division.

In case of addition and subtraction, the answer should have least significant figures after the decimal point.

(a)

Expert Solution
Check Mark

Explanation of Solution

Given value is 325feet.  This has to be converted into meters using the conversion factor.  Conversion factor for feet and meters conversion is given below.

    1m3.28084ftor3.28084ft1m

As the given value is in feet, the first conversion factor is considered.  The SI unit conversion is performed as shown below.

    325ft×1m3.28084ft=99.0599968300801m

Number 325 has three significant figures and 3.28084 has six significant figures.  Therefore, the answer should contain only three significant figures.

Therefore,

  99.0599968300801m99.1 m

(b)

Interpretation Introduction

Interpretation:

SI unit conversion has to be performed for 1.54angstroms to picometers and to nanometers, and expressed in correct number of significant figures.

Concept Introduction:

Refer part (a).

(b)

Expert Solution
Check Mark

Explanation of Solution

Given value is 1.54angstroms.  This has to be converted into picometers and nanometers using the conversion factor.  Conversion factors to be used for the conversion are given below.

    1angstrom1010mor1010m1angstromand1pm1012mor1012m1pmand1nm109mor109m1nm

The SI unit conversion is performed as shown below.

    1.54angstroms×1010m1angstrom×1pm1012m=154pm

    1.54angstroms×1010m1angstrom×1nm109m=0.154nm

Number 1.54 has three significant figures.  Therefore, the answer should contain only three significant figures.

Therefore, the converted units are 154pm and 0.154nm.

(c)

Interpretation Introduction

Interpretation:

SI unit conversion has to be performed for 175pounds to kilograms and expressed in correct number of significant figures.

Concept Introduction:

Refer part (a).

(c)

Expert Solution
Check Mark

Explanation of Solution

Given value is 175pounds.  Conversion factor for the given conversion is shown below.

    1kg2.20462poundor2.20462pound1kg

As the given value is in pounds, the first conversion factor is considered.  The SI unit conversion is performed as shown below.

    175pounds×1kg2.20462pound=79.37875915123695kg

Number 175 has three significant figures and 2.20462 has six significant figures.  Therefore, the answer should contain only three significant figures.

Therefore,

  79.37875915123695kg79.4kg

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Chapter 1 Solutions

General Chemistry

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