Compounds from the 1 H NMR data and the given molecular formula has to be identified. Concept introduction: The 1 H NMR spectrum of a compound provides some vital information that is required to predict the structure of the compound. The chemical shift values can predict the groups that are present in the molecule. The splitting of signals predicts the number of hydrogens or protons attached to the adjacent carbon in a carbon chain of a compound. The single signal is split into multiple peaks called the multiplicity of the signal. Splitting of signals is done according to the ( N + 1 ) rule. N is the number of adjacent non-equivalent protons. According to the ( N + 1 ) rule, for a proton-coupled with N adjacent non-equivalent protons, the signal split into ( N + 1 ) peak. The splitting is mutual. With this information, the structure of the compound can be predicted.

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Answer 1

Question

Chapter 10, Problem 69P

(a)

Interpretation Introduction

Interpretation:

Compounds from the 1H NMR data and the given molecular formula has to be identified.

Concept introduction:

The 1H NMR spectrum of a compound provides some vital information that is required to predict the structure of the compound. The chemical shift values can predict the groups that are present in the molecule.

The splitting of signals predicts the number of hydrogens or protons attached to the adjacent carbon in a carbon chain of a compound. The single signal is split into multiple peaks called the multiplicity of the signal. Splitting of signals is done according to the (N+1) rule. N is the number of adjacent non-equivalent protons.

According to the (N+1) rule, for a proton-coupled with N adjacent non-equivalent protons, the signal split into (N+1) peak. The splitting is mutual. With this information, the structure of the compound can be predicted.

(b)

Interpretation Introduction

Interpretation:

Compounds from the 1H NMR data and the given molecular formula has to be identified.

Concept introduction:

The 1H NMR spectrum of a compound provides some vital information that is required to predict the structure of the compound. The chemical shift values can predict the groups that are present in the molecule.

The splitting of signals predicts the number of hydrogens or protons attached to the adjacent carbon in a carbon chain of a compound. The single signal is split into multiple peaks called the multiplicity of the signal. Splitting of signals is done according to the (N+1) rule. N is the number of adjacent non-equivalent protons.

According to the (N+1) rule, for a proton-coupled with N adjacent non-equivalent protons, the signal split into (N+1) peak. The splitting is mutual. With this information, the structure of the compound can be predicted.

(c)

Interpretation Introduction

Interpretation:

Compounds from the 1H NMR data and the given molecular formula has to be identified.

Concept introduction:

The 1H NMR spectrum of a compound provides some vital information that is required to predict the structure of the compound. The chemical shift values can predict the groups that are present in the molecule.

The splitting of signals predicts the number of hydrogens or protons attached to the adjacent carbon in a carbon chain of a compound. The single signal is split into multiple peaks called the multiplicity of the signal. Splitting of signals is done according to the (N+1) rule. N is the number of adjacent non-equivalent protons.

According to the (N+1) rule, for a proton-coupled with N adjacent non-equivalent protons, the signal split into (N+1) peak. The splitting is mutual. With this information, the structure of the compound can be predicted.

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For each compound, give the number of 1H NMR signals and then determine how many peaks are present for each NMR signal.

1. Identify the solvent peak in the spectrum and list its chemical shift. 2. Other than the solvent peak, how many signals are present in the 13C NMR and how does this correlate to the number of chemically distinct carbons? 3. Based on the chemical shifts, what functional groups are present in your compound? For each, correlate the functional group with the chemical shift of the identifying peak.

Draw a structure that is consistent with the 1H NMR data shown. The location of peak 'd' is dependent upon concentration, i.e., is exchangeable. Make peak assignments on your structure using the labels a-e (shown underneath the spectrum).

Answer 2

Question

Chapter 10, Problem 69P

(a)

Interpretation Introduction

Interpretation:

Compounds from the 1H NMR data and the given molecular formula has to be identified.

Concept introduction:

The 1H NMR spectrum of a compound provides some vital information that is required to predict the structure of the compound. The chemical shift values can predict the groups that are present in the molecule.

The splitting of signals predicts the number of hydrogens or protons attached to the adjacent carbon in a carbon chain of a compound. The single signal is split into multiple peaks called the multiplicity of the signal. Splitting of signals is done according to the (N+1) rule. N is the number of adjacent non-equivalent protons.

According to the (N+1) rule, for a proton-coupled with N adjacent non-equivalent protons, the signal split into (N+1) peak. The splitting is mutual. With this information, the structure of the compound can be predicted.

(b)

Interpretation Introduction

Interpretation:

Compounds from the 1H NMR data and the given molecular formula has to be identified.

Concept introduction:

The 1H NMR spectrum of a compound provides some vital information that is required to predict the structure of the compound. The chemical shift values can predict the groups that are present in the molecule.

The splitting of signals predicts the number of hydrogens or protons attached to the adjacent carbon in a carbon chain of a compound. The single signal is split into multiple peaks called the multiplicity of the signal. Splitting of signals is done according to the (N+1) rule. N is the number of adjacent non-equivalent protons.

According to the (N+1) rule, for a proton-coupled with N adjacent non-equivalent protons, the signal split into (N+1) peak. The splitting is mutual. With this information, the structure of the compound can be predicted.

(c)

Interpretation Introduction

Interpretation:

Compounds from the 1H NMR data and the given molecular formula has to be identified.

Concept introduction:

The 1H NMR spectrum of a compound provides some vital information that is required to predict the structure of the compound. The chemical shift values can predict the groups that are present in the molecule.

The splitting of signals predicts the number of hydrogens or protons attached to the adjacent carbon in a carbon chain of a compound. The single signal is split into multiple peaks called the multiplicity of the signal. Splitting of signals is done according to the (N+1) rule. N is the number of adjacent non-equivalent protons.

According to the (N+1) rule, for a proton-coupled with N adjacent non-equivalent protons, the signal split into (N+1) peak. The splitting is mutual. With this information, the structure of the compound can be predicted.

Expert Solution & Answer

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Answer 3

Question

Chapter 10, Problem 69P

(a)

Interpretation Introduction

Interpretation:

Compounds from the 1H NMR data and the given molecular formula has to be identified.

Concept introduction:

The 1H NMR spectrum of a compound provides some vital information that is required to predict the structure of the compound. The chemical shift values can predict the groups that are present in the molecule.

The splitting of signals predicts the number of hydrogens or protons attached to the adjacent carbon in a carbon chain of a compound. The single signal is split into multiple peaks called the multiplicity of the signal. Splitting of signals is done according to the (N+1) rule. N is the number of adjacent non-equivalent protons.

According to the (N+1) rule, for a proton-coupled with N adjacent non-equivalent protons, the signal split into (N+1) peak. The splitting is mutual. With this information, the structure of the compound can be predicted.

(b)

Interpretation Introduction

Interpretation:

Compounds from the 1H NMR data and the given molecular formula has to be identified.

Concept introduction:

The 1H NMR spectrum of a compound provides some vital information that is required to predict the structure of the compound. The chemical shift values can predict the groups that are present in the molecule.

The splitting of signals predicts the number of hydrogens or protons attached to the adjacent carbon in a carbon chain of a compound. The single signal is split into multiple peaks called the multiplicity of the signal. Splitting of signals is done according to the (N+1) rule. N is the number of adjacent non-equivalent protons.

According to the (N+1) rule, for a proton-coupled with N adjacent non-equivalent protons, the signal split into (N+1) peak. The splitting is mutual. With this information, the structure of the compound can be predicted.

(c)

Interpretation Introduction

Interpretation:

Compounds from the 1H NMR data and the given molecular formula has to be identified.

Concept introduction:

The 1H NMR spectrum of a compound provides some vital information that is required to predict the structure of the compound. The chemical shift values can predict the groups that are present in the molecule.

The splitting of signals predicts the number of hydrogens or protons attached to the adjacent carbon in a carbon chain of a compound. The single signal is split into multiple peaks called the multiplicity of the signal. Splitting of signals is done according to the (N+1) rule. N is the number of adjacent non-equivalent protons.

According to the (N+1) rule, for a proton-coupled with N adjacent non-equivalent protons, the signal split into (N+1) peak. The splitting is mutual. With this information, the structure of the compound can be predicted.

Expert Solution & Answer

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Answer 4

Question

Chapter 10, Problem 69P

(a)

Interpretation Introduction

Interpretation:

Compounds from the 1H NMR data and the given molecular formula has to be identified.

Concept introduction:

The 1H NMR spectrum of a compound provides some vital information that is required to predict the structure of the compound. The chemical shift values can predict the groups that are present in the molecule.

The splitting of signals predicts the number of hydrogens or protons attached to the adjacent carbon in a carbon chain of a compound. The single signal is split into multiple peaks called the multiplicity of the signal. Splitting of signals is done according to the (N+1) rule. N is the number of adjacent non-equivalent protons.

According to the (N+1) rule, for a proton-coupled with N adjacent non-equivalent protons, the signal split into (N+1) peak. The splitting is mutual. With this information, the structure of the compound can be predicted.

(b)

Interpretation Introduction

Interpretation:

Compounds from the 1H NMR data and the given molecular formula has to be identified.

Concept introduction:

The 1H NMR spectrum of a compound provides some vital information that is required to predict the structure of the compound. The chemical shift values can predict the groups that are present in the molecule.

The splitting of signals predicts the number of hydrogens or protons attached to the adjacent carbon in a carbon chain of a compound. The single signal is split into multiple peaks called the multiplicity of the signal. Splitting of signals is done according to the (N+1) rule. N is the number of adjacent non-equivalent protons.

According to the (N+1) rule, for a proton-coupled with N adjacent non-equivalent protons, the signal split into (N+1) peak. The splitting is mutual. With this information, the structure of the compound can be predicted.

(c)

Interpretation Introduction

Interpretation:

Compounds from the 1H NMR data and the given molecular formula has to be identified.

Concept introduction:

The 1H NMR spectrum of a compound provides some vital information that is required to predict the structure of the compound. The chemical shift values can predict the groups that are present in the molecule.

The splitting of signals predicts the number of hydrogens or protons attached to the adjacent carbon in a carbon chain of a compound. The single signal is split into multiple peaks called the multiplicity of the signal. Splitting of signals is done according to the (N+1) rule. N is the number of adjacent non-equivalent protons.

According to the (N+1) rule, for a proton-coupled with N adjacent non-equivalent protons, the signal split into (N+1) peak. The splitting is mutual. With this information, the structure of the compound can be predicted.

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Answer 5

Chapter 10, Problem 69P

(a)

Interpretation Introduction

Interpretation:

Compounds from the 1H NMR data and the given molecular formula has to be identified.

Concept introduction:

The 1H NMR spectrum of a compound provides some vital information that is required to predict the structure of the compound. The chemical shift values can predict the groups that are present in the molecule.

The splitting of signals predicts the number of hydrogens or protons attached to the adjacent carbon in a carbon chain of a compound. The single signal is split into multiple peaks called the multiplicity of the signal. Splitting of signals is done according to the (N+1) rule. N is the number of adjacent non-equivalent protons.

According to the (N+1) rule, for a proton-coupled with N adjacent non-equivalent protons, the signal split into (N+1) peak. The splitting is mutual. With this information, the structure of the compound can be predicted.

(b)

Interpretation Introduction

Interpretation:

Compounds from the 1H NMR data and the given molecular formula has to be identified.

Concept introduction:

The 1H NMR spectrum of a compound provides some vital information that is required to predict the structure of the compound. The chemical shift values can predict the groups that are present in the molecule.

The splitting of signals predicts the number of hydrogens or protons attached to the adjacent carbon in a carbon chain of a compound. The single signal is split into multiple peaks called the multiplicity of the signal. Splitting of signals is done according to the (N+1) rule. N is the number of adjacent non-equivalent protons.

According to the (N+1) rule, for a proton-coupled with N adjacent non-equivalent protons, the signal split into (N+1) peak. The splitting is mutual. With this information, the structure of the compound can be predicted.

(c)

Interpretation Introduction

Interpretation:

Compounds from the 1H NMR data and the given molecular formula has to be identified.

Concept introduction:

The 1H NMR spectrum of a compound provides some vital information that is required to predict the structure of the compound. The chemical shift values can predict the groups that are present in the molecule.

The splitting of signals predicts the number of hydrogens or protons attached to the adjacent carbon in a carbon chain of a compound. The single signal is split into multiple peaks called the multiplicity of the signal. Splitting of signals is done according to the (N+1) rule. N is the number of adjacent non-equivalent protons.

According to the (N+1) rule, for a proton-coupled with N adjacent non-equivalent protons, the signal split into (N+1) peak. The splitting is mutual. With this information, the structure of the compound can be predicted.

Answer 6

Chapter 10, Problem 69P

(a)

Interpretation Introduction

Interpretation:

Compounds from the 1H NMR data and the given molecular formula has to be identified.

Concept introduction:

The 1H NMR spectrum of a compound provides some vital information that is required to predict the structure of the compound. The chemical shift values can predict the groups that are present in the molecule.

The splitting of signals predicts the number of hydrogens or protons attached to the adjacent carbon in a carbon chain of a compound. The single signal is split into multiple peaks called the multiplicity of the signal. Splitting of signals is done according to the (N+1) rule. N is the number of adjacent non-equivalent protons.

According to the (N+1) rule, for a proton-coupled with N adjacent non-equivalent protons, the signal split into (N+1) peak. The splitting is mutual. With this information, the structure of the compound can be predicted.

Answer 7

Chapter 10, Problem 69P

(a)

Interpretation Introduction

Interpretation:

Compounds from the 1H NMR data and the given molecular formula has to be identified.

Concept introduction:

The 1H NMR spectrum of a compound provides some vital information that is required to predict the structure of the compound. The chemical shift values can predict the groups that are present in the molecule.

The splitting of signals predicts the number of hydrogens or protons attached to the adjacent carbon in a carbon chain of a compound. The single signal is split into multiple peaks called the multiplicity of the signal. Splitting of signals is done according to the (N+1) rule. N is the number of adjacent non-equivalent protons.

According to the (N+1) rule, for a proton-coupled with N adjacent non-equivalent protons, the signal split into (N+1) peak. The splitting is mutual. With this information, the structure of the compound can be predicted.

Answer 8

(b)

Interpretation Introduction

Interpretation:

Compounds from the 1H NMR data and the given molecular formula has to be identified.

Concept introduction:

The 1H NMR spectrum of a compound provides some vital information that is required to predict the structure of the compound. The chemical shift values can predict the groups that are present in the molecule.

The splitting of signals predicts the number of hydrogens or protons attached to the adjacent carbon in a carbon chain of a compound. The single signal is split into multiple peaks called the multiplicity of the signal. Splitting of signals is done according to the (N+1) rule. N is the number of adjacent non-equivalent protons.

According to the (N+1) rule, for a proton-coupled with N adjacent non-equivalent protons, the signal split into (N+1) peak. The splitting is mutual. With this information, the structure of the compound can be predicted.

Answer 9

(b)

Interpretation Introduction

Interpretation:

Compounds from the 1H NMR data and the given molecular formula has to be identified.

Concept introduction:

The 1H NMR spectrum of a compound provides some vital information that is required to predict the structure of the compound. The chemical shift values can predict the groups that are present in the molecule.

The splitting of signals predicts the number of hydrogens or protons attached to the adjacent carbon in a carbon chain of a compound. The single signal is split into multiple peaks called the multiplicity of the signal. Splitting of signals is done according to the (N+1) rule. N is the number of adjacent non-equivalent protons.

According to the (N+1) rule, for a proton-coupled with N adjacent non-equivalent protons, the signal split into (N+1) peak. The splitting is mutual. With this information, the structure of the compound can be predicted.

Answer 10

(c)

Interpretation Introduction

Interpretation:

Compounds from the 1H NMR data and the given molecular formula has to be identified.

Concept introduction:

The 1H NMR spectrum of a compound provides some vital information that is required to predict the structure of the compound. The chemical shift values can predict the groups that are present in the molecule.

The splitting of signals predicts the number of hydrogens or protons attached to the adjacent carbon in a carbon chain of a compound. The single signal is split into multiple peaks called the multiplicity of the signal. Splitting of signals is done according to the (N+1) rule. N is the number of adjacent non-equivalent protons.

According to the (N+1) rule, for a proton-coupled with N adjacent non-equivalent protons, the signal split into (N+1) peak. The splitting is mutual. With this information, the structure of the compound can be predicted.

Answer 11

(c)

Interpretation Introduction

Interpretation:

Compounds from the 1H NMR data and the given molecular formula has to be identified.

Concept introduction:

The 1H NMR spectrum of a compound provides some vital information that is required to predict the structure of the compound. The chemical shift values can predict the groups that are present in the molecule.

The splitting of signals predicts the number of hydrogens or protons attached to the adjacent carbon in a carbon chain of a compound. The single signal is split into multiple peaks called the multiplicity of the signal. Splitting of signals is done according to the (N+1) rule. N is the number of adjacent non-equivalent protons.

According to the (N+1) rule, for a proton-coupled with N adjacent non-equivalent protons, the signal split into (N+1) peak. The splitting is mutual. With this information, the structure of the compound can be predicted.

Answer 12

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Answer 13

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Answer 14

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Answer 15

Ch. 10.1 - Prob. 1P Ch. 10.2 - What would distinguish the mass spectrum of...Ch. 10.2 - Prob. 3P Ch. 10.3 - Prob. 5P Ch. 10.3 - Suggest possible molecular formulas for a compound...Ch. 10.3 - Prob. 7P Ch. 10.4 - Prob. 8P Ch. 10.4 - Prob. 9P Ch. 10.5 - Prob. 10P Ch. 10.5 - Prob. 11P

Solution Summary: The author explains that the 1H NMR spectrum of a compound provides vital information that is required to predict the structure of the compound.

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