Organic Chemistry
11th Edition
ISBN: 9781118133576
Author: T. W. Graham Solomons, Craig Fryhle
Publisher: Wiley, John & Sons, Incorporated
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Chapter 10, Problem 6Q
Interpretation Introduction
Interpretation: The different monochloro products, including stereoisomers, obtained when 2-methylbutane react with chlorine is to be determined.
Concept introduction:
Stereoisomers are defined as the isomers that have thesame molecular formula but differ in arrangement of the atoms in three dimensional space.
Chlorination of
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How many tertiary alkyl halides have the formula C4H9Br?A.) 1B.) 2C.) 3D.) 4
Which of the following alkane will give the MOST number of monohalogenated products (not counting stereoisomers)?A.) hexaneB.) 3-methylpentaneC.) 2,3-dimethylbutaneD.) 2-methylheptane
A. Complete and balance the following combustion reactions. Assume
that each hydrocarbon is converted completely to carbon dioxide and
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1. Propane + O2 →
2. Cyclohexane + 02→
3.2-Methylpentane + O2 →
B. Following are structural formulas and heats of combustion of
acetaldehyde and ethylene oxide. Which of these compounds is the
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CH-CH
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Ethylene oxide
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An alkene forms 2-methylpropane when catalytically reduced and 1,2-dichloro-2-methylpropane
when treated with Cl₂. Draw the structural formula of the alkene.
• You do not have to consider stereochemistry.
• You do not have to explicitly draw H atoms.
• In cases where there is more than one answer, just draw one.
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ChemDoodle
Chapter 10 Solutions
Organic Chemistry
Ch. 10 - Prob. 1PPCh. 10 - Prob. 2PPCh. 10 - Practice Problem 10.3 How would the molecular ion...Ch. 10 - Prob. 4PPCh. 10 - Prob. 5PPCh. 10 - Prob. 6PPCh. 10 - Practice Problem 10.7 Chlorination reactions of...Ch. 10 - Prob. 8PPCh. 10 - Prob. 9PPCh. 10 - Prob. 10PP
Ch. 10 - Prob. 11PPCh. 10 - Practice Problem 10.12 Benzylic radicals, due to...Ch. 10 - Prob. 13PPCh. 10 - Practice Problem 10.14 Show how the following...Ch. 10 - Prob. 15PPCh. 10 - Prob. 16PPCh. 10 - Prob. 17PPCh. 10 - Prob. 18PCh. 10 - Explain the relative distribution of produces...Ch. 10 - 10.20 Which of the following compounds can be...Ch. 10 - Prob. 21PCh. 10 - Prob. 22PCh. 10 - Prob. 23PCh. 10 - Prob. 24PCh. 10 - 10.25 List in order of decreasing stability all of...Ch. 10 - Prob. 26PCh. 10 - Prob. 27PCh. 10 - Prob. 28PCh. 10 - Starting with the compound or compounds indicated...Ch. 10 - Prob. 30PCh. 10 - 10.31 Synthesize each of the following compounds...Ch. 10 - 10.32 Synthesize each of the following compounds...Ch. 10 - Prob. 33PCh. 10 - Prob. 34PCh. 10 - Prob. 35PCh. 10 - Write a mechanism for the following reaction.Ch. 10 - Prob. 37PCh. 10 - The halogen atom of an alkyl halide can be...Ch. 10 - Prob. 39PCh. 10 - Prob. 40PCh. 10 - If one were to try to draw the simplest Lewis...Ch. 10 - Prob. 1LGPCh. 10 - 2. (a) Propose a synthesis of 2-methoxypropene...Ch. 10 - Use the single-bond dissociation energies of Table...Ch. 10 - 10.2 In the radical chlorination of methane, one...Ch. 10 - Prob. 3QCh. 10 - Use the single-bond dissociation energies of Table...Ch. 10 - Prob. 5QCh. 10 - Prob. 6Q
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Similar questions
- Consider the following structures OH он A C HO NH2 F G H. The compound(s) that undergo electrophilic addition reaction is (are) Choose. + The compound that is the most reactive toward nucleophilic addition reaction is Choose... + The compound that have the highest boiling point is Choose.. + The compound(s) that undergo elimination reaction is(are) Choose.. +arrow_forwardDraw the product that would form when 2-methylpropene reacts with chlorine. • You do not have to consider stereochemistry. • You do not have to explicitly draw H atoms. • In cases where there is more than one answer, just draw one. ChemDoodlearrow_forwardChlorination of alkanes can produce a multitude of products. Determine the number of monochlorinated and dichlorinated products that can be obtained by chlorination of 3‑methylpentane. (Consider constitutional isomers only. Do not count stereoisomers.)arrow_forward
- How many monochlorinated products can be produced from the alkane methylcyclohexane (excluding stereoisomers)?arrow_forward4. Using acetylene as the starting material to synthesize 4-methyl-2-pentyne. Please feel free to use any inorganic molecule and organic molecules containing carbon not more two.arrow_forwardDistinguish between isomerism and resonance. Distinguish between structural and geometric isomerism. When writing the various structural isomers, the most difficult task is identifying which are different isomers and which are identical to a previously written structurethat is, which are compounds that differ only by the rotation of a carbon single bond. How do you distinguish between structural isomers and those that are identical? Alkenes and cycloalkanes are structural isomers of each other. Give an example of each using C4H8. Another common feature of alkenes and cycloalkanes is that both have restricted rotation about one or more bonds in the compound, so both can exhibit cis- trans isomerism. What is required for an alkene or cycloalkane to exhibit cis-trans isomerism? Explain the difference between cis and trans isomers. Alcohols and ethers are structural isomers of each other, as are aldehydes and ketones. Give an example of each to illustrate. Which functional group in Table 21-4 can be structural isomers of carboxylic acids? What is optical isomerism? What do you look for to determine whether an organic compound exhibits optical isomerism? 1-Bromo-1-chloroethane is optically active whereas 1-bromo-2-chloroethane is not optically active. Explain.arrow_forward
- Alcohols are very useful starting materials for the production of many different compounds. The following conversions, starting with 1-butanol, can be carried out in two or more steps. Show the steps (reactants/catalysts) you would follow to carry out the conversions, drawing the formula for the organic product in each step. For each step, a major product must be produced. (See Exercise 62.) (Hint: In the presence of H+, an alcohol is converted into an alkene and water. This is the exact reverse of the reaction of adding water to an alkene to form an alcohol.) a. 1-butanol butane b. 1-butanol 2-butanonearrow_forwardPyrethrins, such as jasmolin II (shown below), are a group of natural compounds that are synthesized by flowers of the genus Chrysanthemum (known as pyrethrum flowers) to act as insecticides. CH3 CH2=CH-CH. CH-C- -HCS 0-CH, CH,-C H2C- ČH, Which is not a functional group or structural feature in jasmolin II? cycloalkane carboxylic acid ester alkenearrow_forwardHow could 2,6-dimethylheptane be prepared from an alkyne and an alkyl halide? (The prime in R′ signifies that R and R′ can be different alkyl groups.)arrow_forward
- 2. Using structural diagrams to explain the synthesis of butyl ethanoate from an alkane and an alcohol. Make sure you have the names of the substances and the reaction conditions of the reactions of the steps that consists your synthesis HC-C H- styrene HH ethane-1,2-diol OH НО. JOL -0-H benzene-1.4-dicarboxylic acid.arrow_forwardHow many different monochlorinated products can be formed from the following compounds?arrow_forwardIs the reaction between an alkene and a halogen a substitution reaction(displacement reaction) or another reaction? Explain the reaction mechanism by giving an example.arrow_forward
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