(a)
To determine: The synthesis of the given alcohol by reducing appropriate carbonyl compound.
Interpretation: The synthesis of the given alcohol by reducing appropriate carbonyl compound is to be shown.
Concept introduction: The synthesis of the primary or secondary alcohols is done by reaction carbonyl compound like carboxylic acid, ketone,
(b)
To determine: The synthesis of the given alcohol by reducing appropriate carbonyl compound.
Interpretation: The synthesis of the given alcohol by reducing appropriate carbonyl compound is to be shown.
Concept introduction: The synthesis of the primary or secondary alcohols is done by reaction carbonyl compound like carboxylic acid, ketone, aldehyde and ester by reducing agents like
(c)
To determine: The synthesis of the given alcohol by reducing appropriate carbonyl compound.
Interpretation: The synthesis of the given alcohol by reducing appropriate carbonyl compound is to be shown.
Concept introduction: The synthesis of the primary or secondary alcohols is done by reaction carbonyl compound like carboxylic acid, ketone, aldehyde and ester by reducing agents like
(d)
To determine: The synthesis of the given alcohol by reducing appropriate carbonyl compound.
Interpretation: The synthesis of the given alcohol by reducing appropriate carbonyl compound is to be shown.
Concept introduction: The synthesis of the primary or secondary alcohols is done by reaction carbonyl compound like carboxylic acid, ketone, aldehyde and ester by reducing agents like
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Organic Chemistry (9th Edition)
- The following series of reactions yields ___________. 1) Butanoic acid and SOCl2; set product aside for use in step 3 2) Bromoethane in excess plus Mg and ether 3) Add the product of step 1 to the reaction mix of step 2 4) When the reaction is complete, add dilute aqueous acid 3-ethylhexan-3-ol 3-ethylheptan-2-ol hexanoic acid hexanal 3-heptanonearrow_forwardDraw out the product structure when 1mol of Acetone is reacted with 2mols of benzaldehyde (in presence of sodium hydroxide). Please show workarrow_forwardDraw the structure of the two ketones which may be used to make the tertiary alcohol shown below by reaction with a Grignard reagent.arrow_forward
- In each case, show how you would synthesize the chloride, bromide, and iodide from the corresponding alcohol. (a) 1-halobutane (halo = chloro, bromo, iodo) (b) halocyclopentane (c) 1-halo-1-methylcyclohexane (d) 1-halo-2-methylcyclohexanearrow_forwardShow two different ways you would make 2-methyl-3-hexanol via a Grignard reagent, beginning each time with an alkyl halide and any other organic or inorganic reagents.arrow_forwardPropose a short synthesis f or ONE of the following molecules. You can start with acetylene, and alkyl halides from 1-4 carbons in length. You can also use an reagents you wish. a) Hexan-3-one (CH3CH2COCH2CH2CH3)arrow_forward
- How to get the molecule given below by getting out of bromobenzene and using the reagents you want? You synthesize? Show it.arrow_forwardUse as many reactions as it takes to turn this compound into a structure that has a tertiary alcohol, and has exactly 15 carbons. You may not use any other carbon-containing reagents except the one above. Assume you have an unlimted amount of this reagent.arrow_forwardCompounds A, B, and C which are all alcohols are subjected to the Lucas test. An oily layer was formed almost instantly after the addition of reagents to Compound C. For compound A, it took several minutes before an oily layer was formed. Meanwhile, it took at least one hour with compound B before an oily layer was observed. What could be compound B? Choices: Ethanol Isopropyl alcohol tert-butyl alcoholarrow_forward
- Which reagents would you use to perform reaction B?a) PBr3.b) p-toluenesulfonyl chloride.c) SOCl2.d) NaOCl, NaOHarrow_forwardThe reaction of ethanal with one equivalent of methanol and a trace of an acid will give: * a-Acetal b-Hemiacetal c-Ketal d-Hemiketalarrow_forwardThe alcohol below was synthesized via a Grignard reaction. There are TWO different combinations of the Grignard reagent and carbonyl that can be used to make the product. Think about TWO ways to make the product, listing the carbonyl and Grignard reagent in the designated boxes.arrow_forward
- Organic ChemistryChemistryISBN:9781305580350Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. FootePublisher:Cengage Learning