Prescott's Microbiology
Prescott's Microbiology
11th Edition
ISBN: 9781260211887
Author: WILLEY, Sandman, Wood
Publisher: McGraw Hill
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Chapter 10.4, Problem 4CC

In general terms, how is ΔG°′ related to ΔE0? What is the ΔE0 when electrons flow from the NAD+/NADH redox pair to the Fe3+/Fe2+ redox pair? How does this compare to the ΔE0 when electrons flow from the Fe3+/Fe2+ conjugate redox pair to the 1 2 O 2 / H 2 O pair? Which will yield the largest amount of free energy to the cell?

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In the complete b-oxidation of stearic acid (18:0) How many moles of FADH2 are produced? How many moles of ATP are produced after all NADH are reoxidized in the respiratory chain? How many moles of ATP are produced after all FADH2 are reoxidized in the respiratorychain? How many moles of ATP are produced from the complete oxidation of stearic acid?
When electrons flow from the NAD+ /NADH conjugate redox pair to the 1/2 O2/H2O redox pair, does the reaction begin with NAD1 or with NADH? What is produced—O2 or H2O?
Compare the delta ΔG0' values for the oxidation of succinate by NAD+ and by FAD. Use the data given in Table 18.1 to find the E0' of the NAD+-NADH and fumarate-succinate couples, and assume that E0' for the FAD – FADH2 redox couple is nearly 0.05 V. Why is FAD rather than  NAD+ the electron acceptor in the reaction catalyzed by succinate dehydrogenase?

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