EBK GENERAL CHEMISTRY
11th Edition
ISBN: 8220103631259
Author: Bissonnette
Publisher: YUZU
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Chapter 11, Problem 100SAE
Construct a concept map that embodies the ideas of
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Chapter 11 Solutions
EBK GENERAL CHEMISTRY
Ch. 11 - Prob. 1ECh. 11 - Explain why it is necessary to hybridize atomic...Ch. 11 - Describe the molecular geometry of H2O suggested...Ch. 11 - Describe the molecular geometry of NH2 suggested...Ch. 11 - In which of the following, CO32-,SO2,CCl4,CO,NO3-...Ch. 11 - In the manner of Example 11-1, describe the...Ch. 11 - For each of the following species, identify the...Ch. 11 - Propose a plausible Lewis structure, geometric...Ch. 11 - Describe a hybridization scheme for the central Cl...Ch. 11 - Describe a hybridization scheme for the central S...
Ch. 11 - Match each of the following species with one of...Ch. 11 - Propose a hybridization scheme to account for...Ch. 11 - Indicate which of the following molecules and ions...Ch. 11 - In the manner of Figure 11-18, indicate the...Ch. 11 - Write Lewis structures for the following...Ch. 11 - Represent bonding in the carbon dioxide molecule,...Ch. 11 - Use the method of Figure 11-19 to represent...Ch. 11 - Use the method of Figure 11-19 to represent...Ch. 11 - The molecular model below represents citric acid,...Ch. 11 - Malic is e common organic acid found in unripe...Ch. 11 - Shown below are ball-and-stick models. Describe...Ch. 11 - Shown below are ban-and-stick models. Describe...Ch. 11 - Prob. 23ECh. 11 - The structure of the molecule allene, CH2CCH2 , is...Ch. 11 - Angelic acid, shown below, occurs in symbol root,...Ch. 11 - Dimethylolpropionic acid, shown below, is used in...Ch. 11 - Explain the essential difference in how the...Ch. 11 - Describe the bond order of diatomic carbon, C2 ,...Ch. 11 - Prob. 29ECh. 11 - The paramagnetism of gaseous B2 has been...Ch. 11 - Prob. 31ECh. 11 - Is it correct to say that when a diatomic molecule...Ch. 11 - For the following pairs of molecular orbitals,...Ch. 11 - For each of the species C2+,O2,F2+ , and NO+ ; a....Ch. 11 - Write plausible molecular orbital occupancy...Ch. 11 - We have used the term “isoelectronic” to refer to...Ch. 11 - Consider the molecules NO+ and N2+ and use...Ch. 11 - Consider the molecules CO+ and CN- and use...Ch. 11 - Construct the molecular orbital diagram for CF....Ch. 11 - Construct the molecular orbital diagram for SrCl....Ch. 11 - Explain why the concept of delocalized molecular...Ch. 11 - Explain how it is possible to avoid the concept of...Ch. 11 - In which of the following molecules would you...Ch. 11 - In which of the following ions would you expect to...Ch. 11 - The Lewis structure of N2 indicates that the...Ch. 11 - Show that both the valence bond method and...Ch. 11 - A group of spectroscopists believe that they have...Ch. 11 - Lewis theory is satisfactory to explain bonding in...Ch. 11 - The compound potassium sesquoxide has the...Ch. 11 - Draw a Lewis structure for the urea molecule, CO(...Ch. 11 - Methyl nitrate, CH2NO2 , is used as a rocket...Ch. 11 - Fluorine nitrate, FONO2 , is an oxidizing agent...Ch. 11 - Draw a Lewis structure(s) for the nitrite ion, NO2...Ch. 11 - Think of the reaction shown here as involving the...Ch. 11 - Prob. 55IAECh. 11 - Prob. 56IAECh. 11 - The molecule formamide, HCONH2 , has the...Ch. 11 - Pyridine, C2H2N , is used in the synthesis of...Ch. 11 - Prob. 59IAECh. 11 - The ion F2Cl is linear, but the ion F2Cl+ is bent....Ch. 11 - Prob. 61IAECh. 11 - Prob. 62IAECh. 11 - Prob. 63IAECh. 11 - Prob. 64IAECh. 11 - Histidine, an essential amino acid, serves as a...Ch. 11 - The anion I42 is linear, and the anion I5 is...Ch. 11 - Prob. 67IAECh. 11 - A conjugated hydrocarbon has an alternation of...Ch. 11 - An elusive intermediate of atmospheric reactions...Ch. 11 - Resonance energy is the difference in energy...Ch. 11 - Furan, C4H4O , is a substance derivable from oat...Ch. 11 - As discussed in Are You Wondering 11-1, the sp...Ch. 11 - In Chapter 10, we saw that electronegativity...Ch. 11 - Borazine, B2N2H2 is often referred to as inorganic...Ch. 11 - Which of the following combinations of orbitals...Ch. 11 - Prob. 76FPCh. 11 - Prob. 77SAECh. 11 - Prob. 78SAECh. 11 - Explain the important distinctions between the...Ch. 11 - A molecule in which sp2 hybrid orbitals are used...Ch. 11 - Prob. 81SAECh. 11 - The hybridization scheme for the central atom...Ch. 11 - Of the following, the species with a bond order of...Ch. 11 - The hybridization scheme for Xe in XeF2 is (a) sp;...Ch. 11 - Delocalized molecular orbitals are found in (a)...Ch. 11 - Prob. 86SAECh. 11 - Why does the hybridization sp2d not account for...Ch. 11 - What is the total number of (a) bonds and (b) p...Ch. 11 - Which of the following species are paramagnetic?...Ch. 11 - Use the valence molecular orbital configuration to...Ch. 11 - Use the valence molecular orbital configuration to...Ch. 11 - Which of these diatomic molecules do you think has...Ch. 11 - For each of the following ions or molecules,...Ch. 11 - Draw Lewis structures for the NO2 and NO2+ ions,...Ch. 11 - In which of the following is the central atom sp...Ch. 11 - Prob. 96SAECh. 11 - According to molecular orbital theory, the O22 ion...Ch. 11 - What is the angle between the hybrid orbitals...Ch. 11 - Consider the molecule with the Lewis structure...Ch. 11 - Construct a concept map that embodies the ideas of...Ch. 11 - Prob. 101SAECh. 11 - Construct a concept map that describes the...
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- Which of the following molecular formulas are correctly represented by line-bond structures that are consistent with valence rules?arrow_forwardA student who missed this class needs to know how to predict the bond angles and shape of a molecule from looking at its line representation. Write a concise but complete explanation for this student.arrow_forwardWhat are some limitations of the Valence Bond Theory?arrow_forward
- 11) Molecular Geometry/ Electron-Group Geometry Total Valence Formula Rough Lewis Structure Electrons Molecular Geometry: SbCl6 Electron-Group Geo.: (Include formal charges other than 0.) More soluble in Bond Polarity (AEN) Molecule Polarity hexane or water? 12) Molecular Geometry/ Electron-Group Geometry Total Valence Formula Rough Lewis Structure Electrons Molecular Geometry: TeF4 Electron-Group Geo.: (Include formal charges other than 0.) More soluble in Bond Polarity (AEN) Molecule Polarity hexane or water? 10arrow_forwardWrite drawbacks of Valence Bond Theory .arrow_forwardThese molecules are called constitutional (or structural) isomers because they share the same chemical formula but have different patterns of atomic connectivity. Draw as many constitutional isomers as you can for C5H8 in bond-line notation. It may be helpful to draw a Lewis Structure for one of the isomers first.arrow_forward
- The most stable forms of the nonmetals in groups 4A, 5A, and 6A of the second period are molecules with multiple bonds. Beginning with the third period, the most stable forms of the nonmetals of these groups are molecules without multiple bonds. Propose an explanation for this observation based on valence bond theoryarrow_forwardExplain what is a covalent bond in valence bond theory.arrow_forwardIn VSEPR theory, which uses the Lewis model to determine molecular geometry, the trend of decreasing bond angle in CH4, NH3, and H2O is accounted for by the greater repulsion of lone pair electrons compared to bonding pair electrons. How is this trend accounted for in valence bond theory?arrow_forward
- What is the difference between valence bond theory and lewis theory?arrow_forwardWhy is the concept of hybridization important in understanding bond angle and polarity? Explain thoroughly.arrow_forwardThe molecular structure of hinokitiol is represented below (See attached image) Draw a complete Lewis structure of the molecule and answer the following questions. Complete the structure by adding ONLY hydrogen atoms to carbon atoms where needed. You must not create any other bonds. Atoms such as oxygen or nitrogen may have lone pairs to complete their octets. Each of the non-hydrogen atoms of this skeletal structure has been randomly numbered. Match the atom number with the orbital hybridization invoked for sigma bonding. Match these to the below (A)) (Options: sp3, sp2, sp, s, p, d2sp3, dsp3) A) 12, 9, 7, 2, 4 B) How many pairs of non-bonding electrons are there in the molecule? C) How many CH3 (methyl) groups are there in the molecule? D) How many CH2 (methylene) groups are there in the molecule? (i.e. # of C-atoms having exactly two bonded H-atoms) E) How many CH (methyne) groups are there in the molecule? (i.e. # of C-atoms having exactly one bonded H-atom) F) How many…arrow_forward
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