Introduction to Chemical Engineering Thermodynamics
Introduction to Chemical Engineering Thermodynamics
8th Edition
ISBN: 9781259696527
Author: J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Publisher: McGraw-Hill Education
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Chapter 11, Problem 11.15P

(a)

Interpretation Introduction

Interpretation:

The slope of the tangent at the particular point is to be proven equal to the partial excess enthalpy of the solvent in a solution with the composition being represented by n˜ .

Concept Introduction:

For mixing process, equation for enthalpy is:

   ΔH=HE .....(1)

For a binary system, equation which represents the partial excess property of a solvent in a solution is :

   H¯2E=HEx1dHEdx1 .....(2)

(b)

Interpretation Introduction

Interpretation:

The intercept I is to be proven equal to the partial excess enthalpy of the solute in a solution.

Concept Introduction:

The summability equation for excess enthalpy is:

   HE=x1H¯1E+x2H¯2E .....(5)

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