ORGANIC CHEMISTRY,SOLN.MAN.+...-ACCESS
4th Edition
ISBN: 9781119659471
Author: Klein
Publisher: WILEY
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Chapter 11, Problem 26ASP
Interpretation Introduction
Interpretation: To determine the correct reagents for the given transformation taking place.
Concept introduction: Carbon atoms are added during the alkylation process. The final product has six carbon atoms, compared to the beginning material's four. As a result, two carbons must be inserted to obtain the product. Butyl bromide is used as the first reagent.
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What is the major product of the following reaction?
CH3
Br₂
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H₂O
L
CH3
IV.
CH3
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Br
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CH3
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OI
O III
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Each of the following syntheses requires three steps. Match the reagents for each step in order for
each product.
HO
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Br
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Reagents
1. H₂SO₂, H₂O
2. BH, THF/NaOH, H₂O₂
3. Br₂
4.1 equivalent Brg, hv
5.2 equivalents Br₂, hv
6. HBr
7.0₂. Zn/H₂O
8. HCOH
9. NaOCH CH HOCH₂CH₂
10. HBr, peroxides
11. KOC(CH3)s. HỌC(CH3)
12.
13.
--
What are the best reagents to accomplish this transformation?
?
Br
NaCE CH, followed by H2 and Pt
NaCE CH, followed by H2 and Lindlar's catalyst
NaOH, followed by t-BuOK
t-BuOK
Chapter 11 Solutions
ORGANIC CHEMISTRY,SOLN.MAN.+...-ACCESS
Ch. 11.1 - Prob. 1CCCh. 11.1 - Prob. 2CCCh. 11.2 - Prob. 1LTSCh. 11.2 - Prob. 3PTSCh. 11.3 - Prob. 2LTSCh. 11.3 - Prob. 6ATSCh. 11.4 - Prob. 3LTSCh. 11.4 - Prob. 7PTSCh. 11.4 - Prob. 8ATSCh. 11.5 - Prob. 4LTS
Ch. 11.5 - Propose an efficient synthesis for each of the...Ch. 11.5 - Prob. 10ATSCh. 11 - Prob. 11PPCh. 11 - Prob. 12PPCh. 11 - Prob. 13PPCh. 11 - Prob. 14PPCh. 11 - Prob. 15PPCh. 11 - Prob. 16PPCh. 11 - Prob. 17PPCh. 11 - Prob. 18PPCh. 11 - Prob. 19PPCh. 11 - Prob. 20PPCh. 11 - Prob. 21PPCh. 11 - Prob. 22PPCh. 11 - Prob. 23PPCh. 11 - Prob. 24PPCh. 11 - Prob. 25PPCh. 11 - Prob. 26ASPCh. 11 - Prob. 27ASPCh. 11 - Prob. 28ASPCh. 11 - Prob. 29ASPCh. 11 - Prob. 30ASPCh. 11 - Prob. 31ASPCh. 11 - Prob. 32ASPCh. 11 - Prob. 33IPCh. 11 - Prob. 34IPCh. 11 - Prob. 35IPCh. 11 - Prob. 36IPCh. 11 - Prob. 37IPCh. 11 - Prob. 38IPCh. 11 - Prob. 39IPCh. 11 - Prob. 42CPCh. 11 - The compound Z-3-hexenyl acetate is one of several...Ch. 11 - When a consumer purchases a tomato, smell is one...Ch. 11 - Prob. 45CPCh. 11 - Prob. 46CP
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