Essential Organic Chemistry (3rd Edition)
Essential Organic Chemistry (3rd Edition)
3rd Edition
ISBN: 9780321937711
Author: Paula Yurkanis Bruice
Publisher: PEARSON
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Chapter 11, Problem 41P

Using an alcohol for one method and an alkyl halide for the other, show two ways to make each of the following esters:

  1. a. propyl acetate (odor of pears)
  2. b. isopentyl acetate (odor of bananas)
  3. c. ethyl butyrate (odor of pineapple)
  4. d. methyl phenylethanoate (odor of honey)
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What is the final product with you mix 3-nitrobenzaldehyde with each of these: a) 4-bromophenylthydrazine hydrochloride  b) 4-cyanophenylhydrazine hydrochloride  c) aminoguanidine bicarbonate  d) 4-chlorophenylhydrazine hydrochloride
1. What are the possible interferences or complications in detecting and differentiating aldehydesand ketones using the following tests:a. 2,4-dinitrophenyl hydrazine test b. benedicts test c. tollens test d. jones test e. iodoform test 2. Describe the positive results for the following qualitative tests:a. 2,4-dinitrophenyl hydrazine test
Show how you would use anhydrides to synthesize the following compounds. In eachcase, explain why an anhydride might be preferable to an acid chloride.(a) n-octyl formate (b) n-octyl acetate(c) phthalic acid monoamide (d) succinic acid monomethyl ester

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Essential Organic Chemistry (3rd Edition)

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