STRUCTURES AND PROPERTIES
2nd Edition
ISBN: 9780136607854
Author: Tro
Publisher: PEARSON C
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Chapter 12, Problem 101E
Interpretation Introduction
To determine:
The main features of crystalline solids e.g. molecular solid, ionic solid, non-bonded solid, metallic solid and network covalent solid.
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Using group members to play the role of atoms or molecules, demonstrate the main structural features of the following categories of crystalline solids: molecular solid, ionic solid, nonbonded solid, metallic solid, network covalent solid. Clearly identify what you represent and how you are representing various interactions between particles (e.g., covalent bond, ionic bond, etc.).
Please answer the following with complete solution/explanation:
1. Copper crystallizes in a face-centered cubic structure. What is the mass of one unit?
2. What is the edge length of a simple cubic unit cell made up of atoms having a radius of 158 pm?
3. State the number of atoms on a plane having the miller indices of 110 in a BCC unit cell.
Beryllium has an HCP unit cell for which the ratio of the lattice parameters c/a is 1.568. If the radius of the Be atom is 0.1143 nm, (a) determine the unit cell volume, (b) calculate the theoretical density of Be and compare it with the literature value of 1.848g/cm.
Chapter 12 Solutions
STRUCTURES AND PROPERTIES
Ch. 12 - What is graphene? Why is graphene unique?Ch. 12 - Prob. 2ECh. 12 - What is a crystalline lattice? How is the lattice...Ch. 12 - Prob. 4ECh. 12 - Prob. 5ECh. 12 - What is the difference between hexagonal closest...Ch. 12 - What are the three basic types of solids and the...Ch. 12 - Prob. 8ECh. 12 - What kinds of forces hold each of the three basic...Ch. 12 - Prob. 10E
Ch. 12 - In an ionic compound, how are the relative sizes...Ch. 12 - Prob. 12ECh. 12 - Show how the fluorite structure accommodates a...Ch. 12 - Prob. 14ECh. 12 - Prob. 15ECh. 12 - Prob. 16ECh. 12 - Prob. 17ECh. 12 - Prob. 18ECh. 12 - Prob. 19ECh. 12 - Describe the difference between vitreous silica...Ch. 12 - Prob. 21ECh. 12 - Prob. 22ECh. 12 - Prob. 23ECh. 12 - Prob. 24ECh. 12 - What is a polymer? What is the difference between...Ch. 12 - Prob. 26ECh. 12 - Prob. 27ECh. 12 - An X-ray beam of unknown wavelength is diffracted...Ch. 12 - Prob. 29ECh. 12 - Determine the coordination number for each...Ch. 12 - Calculate the packing efficiency of the...Ch. 12 - Prob. 32ECh. 12 - Prob. 33ECh. 12 - Molybdenum crystallizes with the body-centred unit...Ch. 12 - Rhodium has a density of 12.41 g / cm3 and...Ch. 12 - Barium has a density of 3.59 g/cm3 and...Ch. 12 - Prob. 37ECh. 12 - Palladium crystallizes with a face-centered cubic...Ch. 12 - Prob. 39ECh. 12 - Identify each solid as molecular, ionic, or...Ch. 12 - Which solid has the highest melting point? Why?...Ch. 12 - Which solid has the highest melting point? Why?...Ch. 12 - Which solid in each pair has the higher melting...Ch. 12 - Which solid in each pair has the higher melting...Ch. 12 - Prob. 45ECh. 12 - Prob. 46ECh. 12 - The unit cells for cesium chloride and barium(ll)...Ch. 12 - Prob. 48ECh. 12 - Prob. 49ECh. 12 - Prob. 50ECh. 12 - Prob. 51ECh. 12 - Consider the zinc blende structure in Figure 12.14...Ch. 12 - Prob. 53ECh. 12 - Prob. 54ECh. 12 - Prob. 55ECh. 12 - What are the name and formula of the compound...Ch. 12 - Prob. 57ECh. 12 - Prob. 58ECh. 12 - Prob. 59ECh. 12 - Prob. 60ECh. 12 - Prob. 61ECh. 12 - How many molecular orbitals are present in the...Ch. 12 - Prob. 63ECh. 12 - Prob. 64ECh. 12 - Prob. 65ECh. 12 - Prob. 66ECh. 12 - Prob. 67ECh. 12 - Prob. 68ECh. 12 - Prob. 69ECh. 12 - Saran, the polymer used to make saran wrap, is an...Ch. 12 - One kind of polyester is a condensation copolymer...Ch. 12 - Nomex, a condensation copolymer used by...Ch. 12 - Prob. 73ECh. 12 - Polyacrylonitrile (PAN) is an addition polymer...Ch. 12 - Prob. 75ECh. 12 - Prob. 76ECh. 12 - Prob. 77ECh. 12 - Prob. 78ECh. 12 - Prob. 79ECh. 12 - Prob. 80ECh. 12 - Prob. 81ECh. 12 - The density of an unknown metal is 12.3 g/cm3 and...Ch. 12 - An unknown metal is found to have a density of...Ch. 12 - Prob. 84ECh. 12 - Prob. 85ECh. 12 - Prob. 86ECh. 12 - Prob. 87ECh. 12 - Prob. 88ECh. 12 - Prob. 89ECh. 12 - Prob. 90ECh. 12 - Prob. 91ECh. 12 - Perovskite is a compound with a cubic unit cell...Ch. 12 - Prob. 93ECh. 12 - Despite Dalton's laws, it is now known that many...Ch. 12 - During the glass manufacturing process, the liquid...Ch. 12 - Why are X-rays used for crystallography? Why not...Ch. 12 - Compare the crystal structure of diamond (C) and...Ch. 12 - Prob. 98ECh. 12 - Prob. 99ECh. 12 - Have each group member select one of the cubic...Ch. 12 - Prob. 101ECh. 12 - Prob. 102ECh. 12 - Prob. 103ECh. 12 - Prob. 104ECh. 12 - Prob. 105ECh. 12 - Prob. 1SAQCh. 12 - A crystalline solid has a body-centered cubic...Ch. 12 - Prob. 3SAQCh. 12 - Prob. 4SAQCh. 12 - Prob. 5SAQCh. 12 - Prob. 6SAQCh. 12 - Prob. 7SAQCh. 12 - Prob. 8SAQCh. 12 - Prob. 9SAQCh. 12 - Prob. 10SAQCh. 12 - Prob. 11SAQCh. 12 - Prob. 12SAQCh. 12 - Prob. 13SAQCh. 12 - Prob. 14SAQCh. 12 - Prob. 15SAQ
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Similar questions
- Which solid phase that is, which allotrope of carbon is more stable, graphite or diamond? You should consult some of the tables in the thermodynamics section of this text.. Both solid phases exist under normal conditions of pressure and temperature. Explain why this is so, given that one solid phase is more thermodynamically stable than the other. Do their unit cells provide any suggestion for their relative stabilities?arrow_forwardExplain in words how Avogadros number could be obtained from the unit-cell edge length of a cubic crystal. What other data are required?arrow_forwardNanotechnology, or technology utilizing 1100 nm sized particles, has rapidly expanded in the past few decades, with potential applications ranging across far-reaching fields such as electronics, medicine, biomaterials, and consumer products, to name a few. One of the primary advantages of nanoparticles is the presence of large surface/mass ratios, resulting in enhanced surface activities compared to bulk materials. a Use the density of silver (10.49 g/cm3) to determine the number of Ag atoms in a spherical 20.-nm silver particle. b In the crystalline metallic environment, the measured radii of silver atoms has been measured to be 144 pm. Use this to calculate the atomic packing fraction of a 20.-nm silver particle. In other words, calculate the ratio of the volume taken up by Ag atoms to the volume of the entire nanoparticle. c Based on the result of part (b), silver conforms to which type of cubic crystal lattice? A simple cubic B body-centered cubic C face-centered cubic d A cubic Ag ingot having a mass of 5.0-g is processed to form a batch of 20.-nm Ag nanoparticles. Calculate the ratio of the surface area provided by the batch of nanoparticles to the surface area of the initial cube of Ag.arrow_forward
- Outline a two-dimensional unit cell for the pattern shown here. If the black squares are labeled A and the white squares are B, what is the simplest formula for a compound based on this pattern?arrow_forwardGiven the HCP crystal diagram, what is the index (vector/plane) as indicated inside the unit cell given?arrow_forwardA powdered diffraction photograph from tungsten shows lines that indexes as (110), (200), (211), (211), (220), (310), (222), (321), (400), ...Identify the (Bravais) lattice type of the unit cell.arrow_forward
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