It should be identified for the unprepared compounds by using the Heck reaction. Concept introduction: Suzuki reaction: A reaction that couples an aryl halide or vinyl halide with an Organoboron reagent . Heck reaction: A reaction that breaks the double bond of an alkene and then joins the fragments .

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Answer 1

Question

Chapter 12, Problem 36P

(a)

Interpretation Introduction

Interpretation:

It should be identified for the unprepared compounds by using the Heck reaction.

Concept introduction:

Suzuki reaction:

A reaction that couples an aryl halide or vinyl halide with an Organoboron reagent.

Heck reaction:

A reaction that breaks the double bond of an alkene and then joins the fragments.

(b)

Interpretation Introduction

Interpretation:

The starting material and the suitable compound should be identified which can be prepared from Heck reaction.

Concept introduction:

Suzuki reaction:

A reaction that couples an aryl halide or vinyl halide with an Organoboron reagent.

Heck reaction:

A reaction that breaks the double bond of an alkene and then joins the fragments.

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5. Devise concise syntheses for the following transformations. Clearly show the reagent and product for each step. All syntheses can be accomplished in two steps. a. b. Br Br

a. Which of the following compounds cannot be prepared by a Heck reaction?b. For those compounds that can be prepared by a Heck reaction, what starting materials are required?

Which of the following compounds cannot be prepared by a Heck reaction? a. For those compounds that can be prepared by a Heck reaction, what starting materials are required?

Answer 2

Question

Chapter 12, Problem 36P

(a)

Interpretation Introduction

Interpretation:

It should be identified for the unprepared compounds by using the Heck reaction.

Concept introduction:

Suzuki reaction:

A reaction that couples an aryl halide or vinyl halide with an Organoboron reagent.

Heck reaction:

A reaction that breaks the double bond of an alkene and then joins the fragments.

(b)

Interpretation Introduction

Interpretation:

The starting material and the suitable compound should be identified which can be prepared from Heck reaction.

Concept introduction:

Suzuki reaction:

A reaction that couples an aryl halide or vinyl halide with an Organoboron reagent.

Heck reaction:

A reaction that breaks the double bond of an alkene and then joins the fragments.

Expert Solution & Answer

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Answer 3

Question

Chapter 12, Problem 36P

(a)

Interpretation Introduction

Interpretation:

It should be identified for the unprepared compounds by using the Heck reaction.

Concept introduction:

Suzuki reaction:

A reaction that couples an aryl halide or vinyl halide with an Organoboron reagent.

Heck reaction:

A reaction that breaks the double bond of an alkene and then joins the fragments.

(b)

Interpretation Introduction

Interpretation:

The starting material and the suitable compound should be identified which can be prepared from Heck reaction.

Concept introduction:

Suzuki reaction:

A reaction that couples an aryl halide or vinyl halide with an Organoboron reagent.

Heck reaction:

A reaction that breaks the double bond of an alkene and then joins the fragments.

Expert Solution & Answer

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Answer 4

Question

Chapter 12, Problem 36P

(a)

Interpretation Introduction

Interpretation:

It should be identified for the unprepared compounds by using the Heck reaction.

Concept introduction:

Suzuki reaction:

A reaction that couples an aryl halide or vinyl halide with an Organoboron reagent.

Heck reaction:

A reaction that breaks the double bond of an alkene and then joins the fragments.

(b)

Interpretation Introduction

Interpretation:

The starting material and the suitable compound should be identified which can be prepared from Heck reaction.

Concept introduction:

Suzuki reaction:

A reaction that couples an aryl halide or vinyl halide with an Organoboron reagent.

Heck reaction:

A reaction that breaks the double bond of an alkene and then joins the fragments.

Expert Solution & Answer

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Answer 5

Chapter 12, Problem 36P

(a)

Interpretation Introduction

Interpretation:

It should be identified for the unprepared compounds by using the Heck reaction.

Concept introduction:

Suzuki reaction:

A reaction that couples an aryl halide or vinyl halide with an Organoboron reagent.

Heck reaction:

A reaction that breaks the double bond of an alkene and then joins the fragments.

(b)

Interpretation Introduction

Interpretation:

The starting material and the suitable compound should be identified which can be prepared from Heck reaction.

Concept introduction:

Suzuki reaction:

A reaction that couples an aryl halide or vinyl halide with an Organoboron reagent.

Heck reaction:

A reaction that breaks the double bond of an alkene and then joins the fragments.

Answer 6

Chapter 12, Problem 36P

(a)

Interpretation Introduction

Interpretation:

It should be identified for the unprepared compounds by using the Heck reaction.

Concept introduction:

Suzuki reaction:

A reaction that couples an aryl halide or vinyl halide with an Organoboron reagent.

Heck reaction:

A reaction that breaks the double bond of an alkene and then joins the fragments.

Answer 7

Chapter 12, Problem 36P

(a)

Interpretation Introduction

Interpretation:

It should be identified for the unprepared compounds by using the Heck reaction.

Concept introduction:

Suzuki reaction:

A reaction that couples an aryl halide or vinyl halide with an Organoboron reagent.

Heck reaction:

A reaction that breaks the double bond of an alkene and then joins the fragments.

Answer 8

(b)

Interpretation Introduction

Interpretation:

The starting material and the suitable compound should be identified which can be prepared from Heck reaction.

Concept introduction:

Suzuki reaction:

A reaction that couples an aryl halide or vinyl halide with an Organoboron reagent.

Heck reaction:

A reaction that breaks the double bond of an alkene and then joins the fragments.

Answer 9

(b)

Interpretation Introduction

Interpretation:

The starting material and the suitable compound should be identified which can be prepared from Heck reaction.

Concept introduction:

Suzuki reaction:

A reaction that couples an aryl halide or vinyl halide with an Organoboron reagent.

Heck reaction:

A reaction that breaks the double bond of an alkene and then joins the fragments.

Answer 10

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Answer 11

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Answer 12

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Answer 13

Ch. 12.1 - Prob. 1P Ch. 12.2 - Which is more reactive an organolithium compound...Ch. 12.2 - Prob. 3P Ch. 12.3 - PROBLEM 6♦ Explain why tertiary alkyl halides...Ch. 12.3 - Muscalure is the sex attractant of the common...Ch. 12.3 - Prob. 8P Ch. 12.3 - Prob. 9P Ch. 12.3 - Prob. 10P Ch. 12.4 - Prob. 13P Ch. 12.4 - Prob. 14P

Solution Summary: The author explains that Suzuki reaction couples an aryl halide with an Organoboron reagent. Heck reaction breaks the double bond of an alkene and joins the fragments.

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Chapter 12 Solutions