The ΔH value for the given reaction should be calculated. Concept introduction: Radical or free radical: unpaired valence electron of an atom, molecule, or ion is called as radical. Bond strength is depends on the formation of the radical, if the radical is involving in resonance which is weakest bond strength. The ΔH can be calculated by using following formula, ΔH o = bond broken- bonds formed

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Answer 1

Question

Chapter 12, Problem 47P

(a)

Interpretation Introduction

Interpretation:

The ΔH value for the given reaction should be calculated.

Concept introduction:

Radical or free radical: unpaired valence electron of an atom, molecule, or ion is called as radical.

Bond strength is depends on the formation of the radical, if the radical is involving in resonance which is weakest bond strength.

The ΔH can be calculated by using following formula,

ΔHo = bond broken- bonds formed

(b)

Interpretation Introduction

Interpretation:

The sum of the ΔH value for the given reaction should be calculated.

Concept introduction:

Radical or free radical: unpaired valence electron of an atom, molecule, or ion is called as radical.

Bond strength is depends on the formation of the radical, if the radical is involving in resonance which is weakest bond strength.

Propagation: In this stage, two steps are involving hydrogen abstraction and halogen abstraction (no change in the number of free radicals)

(c)

Interpretation Introduction

Interpretation:

The reason why both the above reactions from subpart (a) and (b) have same ΔH value.has to be explained.

Concept introduction:

Radical or free radical: unpaired valence electron of an atom, molecule, or ion is called as radical.

Bond strength is depends on the formation of the radical, if the radical is involving in resonance which is weakest bond strength.

Propagation: In this stage, two steps are involving hydrogen abstraction and halogen abstraction (no change in the number of free radicals)

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SiH4 (g) + 2 O2 (g) -> SiO2 (s) + 2 H20 (l) at 25ºC; where ΔН°rxn = -1 516 kJ and ΔSºrxn = -432.8 J K-1. Above what temperature would the reaction become nonspontaneous?

At 381 K, the following reaction takes place: Hg2Cl4(g) + Al2Cl6(g) --> 2 (HgAlCl5)(g) ΔH = +10 kJ (a) Offer an explanation for the very small ΔH for this reaction for the known structures of the compounds. (img 1) (b) Explain why the small ΔH in this reaction is evidence against (img 2) as the structure of Hg2Cl4(g).

10. The conversion of reactant I to product G is preferred at _____ temperature and is under ______ control. a. low, kinetic b. low, thermodynamic c. high, kinetic d. high, thermodynamic 11. The conversion of reactant I to product H is preferred at _____ temperature and is under ______ control. a. low, kinetic b. low, thermodynamic c. high, kinetic d. high, thermodynamic

Answer 2

Question

Chapter 12, Problem 47P

(a)

Interpretation Introduction

Interpretation:

The ΔH value for the given reaction should be calculated.

Concept introduction:

Radical or free radical: unpaired valence electron of an atom, molecule, or ion is called as radical.

Bond strength is depends on the formation of the radical, if the radical is involving in resonance which is weakest bond strength.

The ΔH can be calculated by using following formula,

ΔHo = bond broken- bonds formed

(b)

Interpretation Introduction

Interpretation:

The sum of the ΔH value for the given reaction should be calculated.

Concept introduction:

Radical or free radical: unpaired valence electron of an atom, molecule, or ion is called as radical.

Bond strength is depends on the formation of the radical, if the radical is involving in resonance which is weakest bond strength.

Propagation: In this stage, two steps are involving hydrogen abstraction and halogen abstraction (no change in the number of free radicals)

(c)

Interpretation Introduction

Interpretation:

The reason why both the above reactions from subpart (a) and (b) have same ΔH value.has to be explained.

Concept introduction:

Radical or free radical: unpaired valence electron of an atom, molecule, or ion is called as radical.

Bond strength is depends on the formation of the radical, if the radical is involving in resonance which is weakest bond strength.

Propagation: In this stage, two steps are involving hydrogen abstraction and halogen abstraction (no change in the number of free radicals)

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Answer 3

Question

Chapter 12, Problem 47P

(a)

Interpretation Introduction

Interpretation:

The ΔH value for the given reaction should be calculated.

Concept introduction:

Radical or free radical: unpaired valence electron of an atom, molecule, or ion is called as radical.

Bond strength is depends on the formation of the radical, if the radical is involving in resonance which is weakest bond strength.

The ΔH can be calculated by using following formula,

ΔHo = bond broken- bonds formed

(b)

Interpretation Introduction

Interpretation:

The sum of the ΔH value for the given reaction should be calculated.

Concept introduction:

Radical or free radical: unpaired valence electron of an atom, molecule, or ion is called as radical.

Bond strength is depends on the formation of the radical, if the radical is involving in resonance which is weakest bond strength.

Propagation: In this stage, two steps are involving hydrogen abstraction and halogen abstraction (no change in the number of free radicals)

(c)

Interpretation Introduction

Interpretation:

The reason why both the above reactions from subpart (a) and (b) have same ΔH value.has to be explained.

Concept introduction:

Radical or free radical: unpaired valence electron of an atom, molecule, or ion is called as radical.

Bond strength is depends on the formation of the radical, if the radical is involving in resonance which is weakest bond strength.

Propagation: In this stage, two steps are involving hydrogen abstraction and halogen abstraction (no change in the number of free radicals)

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Answer 4

Question

Chapter 12, Problem 47P

(a)

Interpretation Introduction

Interpretation:

The ΔH value for the given reaction should be calculated.

Concept introduction:

Radical or free radical: unpaired valence electron of an atom, molecule, or ion is called as radical.

Bond strength is depends on the formation of the radical, if the radical is involving in resonance which is weakest bond strength.

The ΔH can be calculated by using following formula,

ΔHo = bond broken- bonds formed

(b)

Interpretation Introduction

Interpretation:

The sum of the ΔH value for the given reaction should be calculated.

Concept introduction:

Radical or free radical: unpaired valence electron of an atom, molecule, or ion is called as radical.

Bond strength is depends on the formation of the radical, if the radical is involving in resonance which is weakest bond strength.

Propagation: In this stage, two steps are involving hydrogen abstraction and halogen abstraction (no change in the number of free radicals)

(c)

Interpretation Introduction

Interpretation:

The reason why both the above reactions from subpart (a) and (b) have same ΔH value.has to be explained.

Concept introduction:

Radical or free radical: unpaired valence electron of an atom, molecule, or ion is called as radical.

Bond strength is depends on the formation of the radical, if the radical is involving in resonance which is weakest bond strength.

Propagation: In this stage, two steps are involving hydrogen abstraction and halogen abstraction (no change in the number of free radicals)

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Answer 5

Chapter 12, Problem 47P

(a)

Interpretation Introduction

Interpretation:

The ΔH value for the given reaction should be calculated.

Concept introduction:

Radical or free radical: unpaired valence electron of an atom, molecule, or ion is called as radical.

Bond strength is depends on the formation of the radical, if the radical is involving in resonance which is weakest bond strength.

The ΔH can be calculated by using following formula,

ΔHo = bond broken- bonds formed

(b)

Interpretation Introduction

Interpretation:

The sum of the ΔH value for the given reaction should be calculated.

Concept introduction:

Radical or free radical: unpaired valence electron of an atom, molecule, or ion is called as radical.

Bond strength is depends on the formation of the radical, if the radical is involving in resonance which is weakest bond strength.

Propagation: In this stage, two steps are involving hydrogen abstraction and halogen abstraction (no change in the number of free radicals)

(c)

Interpretation Introduction

Interpretation:

The reason why both the above reactions from subpart (a) and (b) have same ΔH value.has to be explained.

Concept introduction:

Radical or free radical: unpaired valence electron of an atom, molecule, or ion is called as radical.

Bond strength is depends on the formation of the radical, if the radical is involving in resonance which is weakest bond strength.

Propagation: In this stage, two steps are involving hydrogen abstraction and halogen abstraction (no change in the number of free radicals)

Answer 6

Chapter 12, Problem 47P

(a)

Interpretation Introduction

Interpretation:

The ΔH value for the given reaction should be calculated.

Concept introduction:

Radical or free radical: unpaired valence electron of an atom, molecule, or ion is called as radical.

Bond strength is depends on the formation of the radical, if the radical is involving in resonance which is weakest bond strength.

The ΔH can be calculated by using following formula,

ΔHo = bond broken- bonds formed

Answer 7

Chapter 12, Problem 47P

(a)

Interpretation Introduction

Interpretation:

The ΔH value for the given reaction should be calculated.

Concept introduction:

Radical or free radical: unpaired valence electron of an atom, molecule, or ion is called as radical.

Bond strength is depends on the formation of the radical, if the radical is involving in resonance which is weakest bond strength.

The ΔH can be calculated by using following formula,

ΔHo = bond broken- bonds formed

Answer 8

(b)

Interpretation Introduction

Interpretation:

The sum of the ΔH value for the given reaction should be calculated.

Concept introduction:

Radical or free radical: unpaired valence electron of an atom, molecule, or ion is called as radical.

Bond strength is depends on the formation of the radical, if the radical is involving in resonance which is weakest bond strength.

Propagation: In this stage, two steps are involving hydrogen abstraction and halogen abstraction (no change in the number of free radicals)

Answer 9

(b)

Interpretation Introduction

Interpretation:

The sum of the ΔH value for the given reaction should be calculated.

Concept introduction:

Radical or free radical: unpaired valence electron of an atom, molecule, or ion is called as radical.

Bond strength is depends on the formation of the radical, if the radical is involving in resonance which is weakest bond strength.

Propagation: In this stage, two steps are involving hydrogen abstraction and halogen abstraction (no change in the number of free radicals)

Answer 10

(c)

Interpretation Introduction

Interpretation:

The reason why both the above reactions from subpart (a) and (b) have same ΔH value.has to be explained.

Concept introduction:

Radical or free radical: unpaired valence electron of an atom, molecule, or ion is called as radical.

Bond strength is depends on the formation of the radical, if the radical is involving in resonance which is weakest bond strength.

Propagation: In this stage, two steps are involving hydrogen abstraction and halogen abstraction (no change in the number of free radicals)

Answer 11

(c)

Interpretation Introduction

Interpretation:

The reason why both the above reactions from subpart (a) and (b) have same ΔH value.has to be explained.

Concept introduction:

Radical or free radical: unpaired valence electron of an atom, molecule, or ion is called as radical.

Bond strength is depends on the formation of the radical, if the radical is involving in resonance which is weakest bond strength.

Propagation: In this stage, two steps are involving hydrogen abstraction and halogen abstraction (no change in the number of free radicals)

Answer 12

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Answer 13

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Answer 14

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Answer 15

Ch. 12.2 - Prob. 1P Ch. 12.2 - Write the steps for formation of...Ch. 12.3 - Prob. 3P Ch. 12.4 - How many alkyl chlorides are obtained from...Ch. 12.4 - Prob. 6P Ch. 12.5 - Prob. 8P Ch. 12.5 - a. Would chlorination or bromination produce a...Ch. 12.5 - Show how the following compounds could be prepared...Ch. 12.6 - Prob. 12P Ch. 12.7 - Prob. 13P

Solution Summary: The author explains that the sum of the H value for the given reaction should be calculated.

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