Physical Chemistry
2nd Edition
ISBN: 9781133958437
Author: Ball, David W. (david Warren), BAER, Tomas
Publisher: Wadsworth Cengage Learning,
expand_more
expand_more
format_list_bulleted
Videos
Question
Chapter 13, Problem 13.73E
Interpretation Introduction
Interpretation:
The justification of the given statement in light of the idea that molecular orbitals are orbitals of the molecule as a whole, and not orbitals of the atoms is to be stated.
Concept introduction:
Molecular orbital diagrams are used for determining the bonding in molecules using linear combination of atomic orbitals. The number of molecular orbitals formed is equal to the number of atomic orbitals that combine with each other.
Expert Solution & Answer
Want to see the full answer?
Check out a sample textbook solution
Students have asked these similar questions
How many molecular orbitals can be constructed from a diatomic molecule in which s. p, d. and f orbitals are all important for bonding?
List and discuss the approximations built into valence bond theory and molecular orbital theory.
The languages of valence-bond theory and molecular orbital theory are commonly combined when discussing unsaturated organic compounds. Construct the molecular orbital energy level diagrams of ethene on the basis that the molecule is formed from the appropriately hybridized CH2 or CH fragments.
Chapter 13 Solutions
Physical Chemistry
Ch. 13 - In your own words, explain why an object that has...Ch. 13 - Identify the symmetry elements present in the...Ch. 13 - Identify the symmetry elements present in the...Ch. 13 - Prob. 13.4ECh. 13 - Prob. 13.5ECh. 13 - Prob. 13.6ECh. 13 - Prob. 13.7ECh. 13 - Prob. 13.8ECh. 13 - Any axis of symmetry Cn that rotates an object by...Ch. 13 - Prob. 13.10E
Ch. 13 - Prob. 13.11ECh. 13 - Prob. 13.12ECh. 13 - Prob. 13.13ECh. 13 - What are the number of classes and the order of...Ch. 13 - Prob. 13.15ECh. 13 - a Show that the C3v point group satisfies the...Ch. 13 - a In the Td point group, an S41 improper rotation...Ch. 13 - Determine which single symmetry operation of the...Ch. 13 - Prob. 13.19ECh. 13 - Prob. 13.20ECh. 13 - Prob. 13.21ECh. 13 - Figure 13.27 shows the structure of the molecule...Ch. 13 - Prob. 13.23ECh. 13 - Identify all the symmetry elements present in the...Ch. 13 - Point groups are called such because all of the...Ch. 13 - Determine the point groups of the following...Ch. 13 - Determine the point group of the following...Ch. 13 - Determine the point groups of the following...Ch. 13 - Determine the point groups of the following...Ch. 13 - Structural isomers can have very different point...Ch. 13 - Structural isomers can have very different point...Ch. 13 - Prob. 13.32ECh. 13 - Identify the point group of the wave functions of...Ch. 13 - Identify the point group of the wave functions of...Ch. 13 - Prob. 13.35ECh. 13 - Determine if the following species have permanent...Ch. 13 - Determine if the following species have permanent...Ch. 13 - Which of the following species will not have...Ch. 13 - Prob. 13.39ECh. 13 - Explain why a molecule with a center of inversion...Ch. 13 - a Unlike methane, bromochlorofluoromethane...Ch. 13 - Prob. 13.42ECh. 13 - Prob. 13.43ECh. 13 - Prob. 13.44ECh. 13 - Show that the irreducible representations of the...Ch. 13 - Show that any two of the irreducible...Ch. 13 - Show that any irreducible representation of these...Ch. 13 - Explain why this proposed irreducible...Ch. 13 - Prob. 13.49ECh. 13 - Prob. 13.50ECh. 13 - Why is it unnecessary to consider whether an...Ch. 13 - Prob. 13.52ECh. 13 - Prob. 13.53ECh. 13 - Prob. 13.54ECh. 13 - Prob. 13.55ECh. 13 - Prob. 13.56ECh. 13 - Prob. 13.57ECh. 13 - Prob. 13.58ECh. 13 - Reduce the following reducible representations...Ch. 13 - Determine the resulting representations for the...Ch. 13 - Prob. 13.61ECh. 13 - Without using the great orthogonality theorem,...Ch. 13 - Assume that you are evaluating the integral of...Ch. 13 - Prob. 13.64ECh. 13 - Assume that x- polarized light can be assigned an...Ch. 13 - Prob. 13.66ECh. 13 - Prob. 13.67ECh. 13 - Prob. 13.68ECh. 13 - Prob. 13.69ECh. 13 - Prob. 13.70ECh. 13 - Construct the symmetry-adapted linear combination...Ch. 13 - Prob. 13.72ECh. 13 - Prob. 13.73ECh. 13 - Prob. 13.74ECh. 13 - Prob. 13.75ECh. 13 - Prob. 13.76ECh. 13 - Prob. 13.77ECh. 13 - Suppose you use p0,p1 and p+1 along with s...Ch. 13 - Show that the individual sp orbitals, as written...Ch. 13 - Prob. 13.80ECh. 13 - What is the rough hybridization of the carbon...Ch. 13 - Determine the symmetry species of the D3h point...Ch. 13 - Determine the D3h symmetry species of the sp3d...Ch. 13 - Prob. 13.84ECh. 13 - In propene CH3CH=CH2, the first carbon has sp3...Ch. 13 - Prob. 13.87ECh. 13 - Prob. 13.88ECh. 13 - Prob. 13.89E
Knowledge Booster
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.Similar questions
- Determine if the following species have permanent dipole moments. a Dichloromethane, CH2Cl2 b Chlorobenzene, C6H5Cl c Ammonia, NH3 d Carbon dioxide, CO2.arrow_forwardMolecular Orbital Theory (See Examples 9.49.6.) The hydrogen molecular ion, H2+, can be detected spectroscopically. Write the electron configuration of the ion in molecular orbital terms. What is the bond order of the ion? Is the hydrogenhydrogen bond stronger or weaker in H2+ than in H2s?arrow_forwardAspirin, or acetylsalicylic acid, has the formula C9H8O4 and the skeleton structure (a) Complete the Lewis structure and give the number of bonds and bonds in aspirin. (b) What is the hybridization about the CO2H carbon atom (colored blue)? (c) What is the hybridization about the carbon atom in the benzene-like ring that is bonded to an oxygen atom (colored red)? Also, what is the hybridization of the oxygen atom bonded to this carbon atom?arrow_forward
- There are two compounds with the molecular formula HN3. One is called hydrogen azide; the other is cyclotriazene. (a) Write the Lewis structure for each compound. (b) Designate the hybridization of each nitrogen in hydrogen azide. (c) What is the hybridization of each nitrogen in cyclotriazene? (d) How many sigma bonds are in hydrogen azide? In cyclotriazene? (e) How many pi bonds are in hydrogen azide? In cyclotriazene? (f) Give approximate values for the N-to-N-to-N bond angles in each molecule.arrow_forwardIn propene CH3CH=CH2, the first carbon has sp3 hybrid orbitals and the second carbon has sp2 hybrid orbitals. These orbitals interact to make a bond. Why are these hybrid orbitals not orthogonal?arrow_forwardIn the molecular orbital mode l, compare and contrast bonds with bonds. What orbitals form the bonds and what orbitals form the bonds? Assume the z-axis is the internuclear axis.arrow_forward
- Define the term sigma 1S2 molecular orbitals?arrow_forwardWrite the molecular orbitals for the diatomic molecule. The atomic number is 1 (1, = consider hydrogen molecule.)arrow_forward(c) In the construction of molecular orbital diagram involving a hypervalence system of hexafluoro sulphur, only 12 valence electrons are distributed across the molecular orbitals. Explain why this is so?arrow_forward
arrow_back_ios
arrow_forward_ios
Recommended textbooks for you
Physical ChemistryChemistryISBN:9781133958437Author:Ball, David W. (david Warren), BAER, TomasPublisher:Wadsworth Cengage Learning,
Chemistry & Chemical ReactivityChemistryISBN:9781337399074Author:John C. Kotz, Paul M. Treichel, John Townsend, David TreichelPublisher:Cengage Learning
Chemistry & Chemical ReactivityChemistryISBN:9781133949640Author:John C. Kotz, Paul M. Treichel, John Townsend, David TreichelPublisher:Cengage Learning
Chemistry: Principles and PracticeChemistryISBN:9780534420123Author:Daniel L. Reger, Scott R. Goode, David W. Ball, Edward MercerPublisher:Cengage Learning
Chemistry by OpenStax (2015-05-04)ChemistryISBN:9781938168390Author:Klaus Theopold, Richard H Langley, Paul Flowers, William R. Robinson, Mark BlaserPublisher:OpenStax
ChemistryChemistryISBN:9781305957404Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCostePublisher:Cengage Learning
Physical Chemistry
Chemistry
ISBN:9781133958437
Author:Ball, David W. (david Warren), BAER, Tomas
Publisher:Wadsworth Cengage Learning,
Chemistry & Chemical Reactivity
Chemistry
ISBN:9781337399074
Author:John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Publisher:Cengage Learning
Chemistry & Chemical Reactivity
Chemistry
ISBN:9781133949640
Author:John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Publisher:Cengage Learning
Chemistry: Principles and Practice
Chemistry
ISBN:9780534420123
Author:Daniel L. Reger, Scott R. Goode, David W. Ball, Edward Mercer
Publisher:Cengage Learning
Chemistry by OpenStax (2015-05-04)
Chemistry
ISBN:9781938168390
Author:Klaus Theopold, Richard H Langley, Paul Flowers, William R. Robinson, Mark Blaser
Publisher:OpenStax
Chemistry
Chemistry
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Cengage Learning
Linear Combination of Atomic Orbitals LCAO; Author: Edmerls;https://www.youtube.com/watch?v=nq1zwrAIr4c;License: Standard YouTube License, CC-BY
Quantum Molecular Orbital Theory (PChem Lecture: LCAO and gerade ungerade orbitals); Author: Prof Melko;https://www.youtube.com/watch?v=l59CGEstSGU;License: Standard YouTube License, CC-BY