Physical Chemistry
2nd Edition
ISBN: 9781133958437
Author: Ball, David W. (david Warren), BAER, Tomas
Publisher: Wadsworth Cengage Learning,
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Textbook Question
Chapter 13, Problem 13.25E
Point groups are called such because all of the symmetry elements in the group intersect at one point in space. For point groups that have
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Physical Chemistry
Ch. 13 - In your own words, explain why an object that has...Ch. 13 - Identify the symmetry elements present in the...Ch. 13 - Identify the symmetry elements present in the...Ch. 13 - Prob. 13.4ECh. 13 - Prob. 13.5ECh. 13 - Prob. 13.6ECh. 13 - Prob. 13.7ECh. 13 - Prob. 13.8ECh. 13 - Any axis of symmetry Cn that rotates an object by...Ch. 13 - Prob. 13.10E
Ch. 13 - Prob. 13.11ECh. 13 - Prob. 13.12ECh. 13 - Prob. 13.13ECh. 13 - What are the number of classes and the order of...Ch. 13 - Prob. 13.15ECh. 13 - a Show that the C3v point group satisfies the...Ch. 13 - a In the Td point group, an S41 improper rotation...Ch. 13 - Determine which single symmetry operation of the...Ch. 13 - Prob. 13.19ECh. 13 - Prob. 13.20ECh. 13 - Prob. 13.21ECh. 13 - Figure 13.27 shows the structure of the molecule...Ch. 13 - Prob. 13.23ECh. 13 - Identify all the symmetry elements present in the...Ch. 13 - Point groups are called such because all of the...Ch. 13 - Determine the point groups of the following...Ch. 13 - Determine the point group of the following...Ch. 13 - Determine the point groups of the following...Ch. 13 - Determine the point groups of the following...Ch. 13 - Structural isomers can have very different point...Ch. 13 - Structural isomers can have very different point...Ch. 13 - Prob. 13.32ECh. 13 - Identify the point group of the wave functions of...Ch. 13 - Identify the point group of the wave functions of...Ch. 13 - Prob. 13.35ECh. 13 - Determine if the following species have permanent...Ch. 13 - Determine if the following species have permanent...Ch. 13 - Which of the following species will not have...Ch. 13 - Prob. 13.39ECh. 13 - Explain why a molecule with a center of inversion...Ch. 13 - a Unlike methane, bromochlorofluoromethane...Ch. 13 - Prob. 13.42ECh. 13 - Prob. 13.43ECh. 13 - Prob. 13.44ECh. 13 - Show that the irreducible representations of the...Ch. 13 - Show that any two of the irreducible...Ch. 13 - Show that any irreducible representation of these...Ch. 13 - Explain why this proposed irreducible...Ch. 13 - Prob. 13.49ECh. 13 - Prob. 13.50ECh. 13 - Why is it unnecessary to consider whether an...Ch. 13 - Prob. 13.52ECh. 13 - Prob. 13.53ECh. 13 - Prob. 13.54ECh. 13 - Prob. 13.55ECh. 13 - Prob. 13.56ECh. 13 - Prob. 13.57ECh. 13 - Prob. 13.58ECh. 13 - Reduce the following reducible representations...Ch. 13 - Determine the resulting representations for the...Ch. 13 - Prob. 13.61ECh. 13 - Without using the great orthogonality theorem,...Ch. 13 - Assume that you are evaluating the integral of...Ch. 13 - Prob. 13.64ECh. 13 - Assume that x- polarized light can be assigned an...Ch. 13 - Prob. 13.66ECh. 13 - Prob. 13.67ECh. 13 - Prob. 13.68ECh. 13 - Prob. 13.69ECh. 13 - Prob. 13.70ECh. 13 - Construct the symmetry-adapted linear combination...Ch. 13 - Prob. 13.72ECh. 13 - Prob. 13.73ECh. 13 - Prob. 13.74ECh. 13 - Prob. 13.75ECh. 13 - Prob. 13.76ECh. 13 - Prob. 13.77ECh. 13 - Suppose you use p0,p1 and p+1 along with s...Ch. 13 - Show that the individual sp orbitals, as written...Ch. 13 - Prob. 13.80ECh. 13 - What is the rough hybridization of the carbon...Ch. 13 - Determine the symmetry species of the D3h point...Ch. 13 - Determine the D3h symmetry species of the sp3d...Ch. 13 - Prob. 13.84ECh. 13 - In propene CH3CH=CH2, the first carbon has sp3...Ch. 13 - Prob. 13.87ECh. 13 - Prob. 13.88ECh. 13 - Prob. 13.89E
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- Construct the symmetry-adapted linear combination molecular orbitals for hydrogen sulfide, H2S.arrow_forwarda In the Td point group, an S41 improper rotation is equivalent to what other improper rotation? b In the D6h point group, the symmetry operation labeled C21 is equivalent to what other symmetry operation?arrow_forwardLinearly polarized light can be assigned a specific irreducible representation of a symmetry point group. If the electronic ground state of methane has A1g symmetry and x- polarized light has the label T2, what are the symmetry labels of allowed excited electronic states? Use the Td character table in Appendix 3.arrow_forward
- Assume that x- polarized light can be assigned an E symmetry species in a system that has C4v symmetry. Can a transition from E state to a B2 state occur? Why or why not?arrow_forwardDetermine the symmetry species of the D3h point group for the sp2 hybrid orbitals, assuming that the C3 axis is coincident with the z-axis and that one of the orbitals lies along the positive x-axis. See Example 13.16.arrow_forwardWhy is it unnecessary to consider whether an irreducible representation from C4h is orthogonal to an irreducible representation of D6h?arrow_forward
- In your own words, explain why an object that has more symmetry elements is said to have higher symmetry than an object with fewer symmetry elements.arrow_forwardShow that the irreducible representations of the D2d point group satisfy the closure requirement. You will have to use the great orthogonality theorem to reduce one combination.arrow_forwardThe Cu(H2O)62+ complex has octahedral symmetry. Is a transition from a T2g state to an Eg state allowed if the transition moment operator has a T1u symmetry label?arrow_forward
- a Unlike methane, bromochlorofluoromethane (CHBrClF) is chiral. Determine all symmetry elements that are present in CHBrClF and identify its point group. b If the fluorine in this molecule were substituted with a hydrogen atom, what is the point group for the new molecule? Is it chiral?arrow_forwardDetermine the point group of the following molecules. a cis1,2 Dichloroethylene b trans1,2 Dichloroethylene c Toluene, C6H5CH3 d 1,3-Cyclohexadiene.arrow_forwardFigure 13.27 shows the structure of the molecule porphine. Figure 13.27 The structure of porphine. Determine the symmetry elements present in the molecule, and its point group. Does the point group change if an Fe2+ ion is substituted for the two hydrogen atoms in the center of the porphine ring?arrow_forward
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