Chemistry (7th Edition)
Chemistry (7th Edition)
7th Edition
ISBN: 9780321943170
Author: John E. McMurry, Robert C. Fay, Jill Kirsten Robinson
Publisher: PEARSON
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Chapter 14, Problem 14.143CP
Interpretation Introduction

Interpretation:

In the following reaction of formation of fumarate.

Laspartate fumarate + ammonium ion.

An initial concentration of L-aspartate is 8.32×103M at 37 0C. Calculate the equilibrium concentration of L-aspartate, fumarate and ammonium ion.

Concept introduction:

Equilibrium is the process in which temperature, pressure, concentration of reactant and product do not show any change with respect to time.
There are two types of equilibrium.

  1. Physical equilibrium: In this physical state of reactant and product does not change when dynamic equilibrium occurred.
  2. Chemical equilibrium: In this chemical composition of reactant and product does not change when dynamic equilibrium occurred. There are two types of reaction occurred in this.
  3. (a) Reversible reactions: In this reaction two ways reaction can occurs that is reactant can convert to product as well as product can convert back to reactant.
    (b) Irreversible reaction: In this reaction two ways reaction cannot occurs that is reactant can convert to product but product cannot convert back to reactant.


Equilibrium constant Kc is defined as the ratio of the concentrations of the products raised to the power of their stoichiometric coefficients and reactants raised to the power of their stoichiometric coefficients.
Reaction quotient Q is defined as the ratio at any point of the reaction of the concentration of the product raised to the power of their stoichiometric coefficients and reactant raised to the power of their stoichiometric coefficients.

aA+bBcC+dDKc= [C]c [D]d [A]a [B]b,equilibriumQ= [C]c [D]d [A]a [B]b

To calculate:

The equilibrium concentration of L-aspartate, fumarate and ammonium ion.

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Chapter 14 Solutions

Chemistry (7th Edition)

Ch. 14 - Prob. 14.11PCh. 14 - APPLY 14.12 Magnesium hydroxide is the active...Ch. 14 - Prob. 14.13PCh. 14 - Prob. 14.14ACh. 14 - Prob. 14.15PCh. 14 - Conceptual APPLY 14.16 The reaction A2 + B2 2...Ch. 14 - PRACTICE 14.17 The H2/CO ratio in mixtures of...Ch. 14 - APPLY 14.18 Calculate the equilibrium...Ch. 14 - PRACTICE 14.19 Calculate the equilibrium...Ch. 14 - APPLY 14.20 Calculate the equilibrium...Ch. 14 - Prob. 14.21PCh. 14 - Prob. 14.22ACh. 14 - Prob. 14.23PCh. 14 - Prob. 14.24ACh. 14 - Prob. 14.25PCh. 14 - Prob. 14.26ACh. 14 - Prob. 14.27PCh. 14 - Prob. 14.28ACh. 14 - Prob. 14.29PCh. 14 - Prob. 14.30ACh. 14 - Prob. 14.31PCh. 14 - Prob. 14.32ACh. 14 - Prob. 14.33PCh. 14 - Prob. 14.34PCh. 14 - Prob. 14.35PCh. 14 - Prob. 14.36PCh. 14 - PROBLEM 14.37 The affinity of hemoglobin (Hb) for...Ch. 14 - Prob. 14.38PCh. 14 - Prob. 14.39CPCh. 14 - The following pictures represent the equilibrium...Ch. 14 - The reaction A2+BA+AB has an equilibrium constant...Ch. 14 - Prob. 14.42CPCh. 14 - Prob. 14.43CPCh. 14 - Prob. 14.44CPCh. 14 - The following pictures represent equilibrium...Ch. 14 - Prob. 14.46CPCh. 14 - Prob. 14.47CPCh. 14 - Prob. 14.48CPCh. 14 - Prob. 14.49CPCh. 14 - Prob. 14.50SPCh. 14 - Identify the true statement about the...Ch. 14 - Prob. 14.52SPCh. 14 - Prob. 14.53SPCh. 14 - For each of the following equilibria, write the...Ch. 14 - Prob. 14.55SPCh. 14 - Prob. 14.56SPCh. 14 - Prob. 14.57SPCh. 14 - For each of the following equilibria, write the...Ch. 14 - Prob. 14.59SPCh. 14 - 14.60 If Kc = 7.5 × 10-9 at 1000 K for the...Ch. 14 - Prob. 14.61SPCh. 14 - Prob. 14.62SPCh. 14 - Prob. 14.63SPCh. 14 - Prob. 14.64SPCh. 14 - Prob. 14.65SPCh. 14 - Prob. 14.66SPCh. 14 - Prob. 14.67SPCh. 14 - Prob. 14.68SPCh. 14 - Prob. 14.69SPCh. 14 - Prob. 14.70SPCh. 14 - Prob. 14.71SPCh. 14 - Prob. 14.72SPCh. 14 - Prob. 14.73SPCh. 14 - Prob. 14.74SPCh. 14 - Prob. 14.75SPCh. 14 - Prob. 14.76SPCh. 14 - Prob. 14.77SPCh. 14 - Prob. 14.78SPCh. 14 - Prob. 14.79SPCh. 14 - Prob. 14.80SPCh. 14 - Prob. 14.81SPCh. 14 - Prob. 14.82SPCh. 14 - Prob. 14.83SPCh. 14 - Prob. 14.84SPCh. 14 - Prob. 14.85SPCh. 14 - Prob. 14.86SPCh. 14 - Prob. 14.87SPCh. 14 - Prob. 14.88SPCh. 14 - Prob. 14.89SPCh. 14 - Prob. 14.90SPCh. 14 - Prob. 14.91SPCh. 14 - Prob. 14.92SPCh. 14 - Prob. 14.93SPCh. 14 - Prob. 14.94SPCh. 14 - Prob. 14.95SPCh. 14 - Prob. 14.96SPCh. 14 - Prob. 14.97SPCh. 14 - Prob. 14.98SPCh. 14 - Prob. 14.99SPCh. 14 - Prob. 14.100SPCh. 14 - Prob. 14.101SPCh. 14 - Prob. 14.102SPCh. 14 - Prob. 14.103SPCh. 14 - Prob. 14.104SPCh. 14 - Consider the endothermic reaction...Ch. 14 - Prob. 14.106SPCh. 14 - Prob. 14.107SPCh. 14 - Prob. 14.108SPCh. 14 - Prob. 14.109SPCh. 14 - Prob. 14.110SPCh. 14 - Prob. 14.111SPCh. 14 - Prob. 14.112SPCh. 14 - Prob. 14.113SPCh. 14 - Prob. 14.114SPCh. 14 - Prob. 14.115SPCh. 14 - Prob. 14.116SPCh. 14 - Prob. 14.117SPCh. 14 - Prob. 14.118SPCh. 14 - Forward and reverse rate constants for the...Ch. 14 - Prob. 14.120CPCh. 14 - Prob. 14.121CPCh. 14 - Prob. 14.122CPCh. 14 - Prob. 14.123CPCh. 14 - Prob. 14.124CPCh. 14 - Prob. 14.125CPCh. 14 - Prob. 14.126CPCh. 14 - Prob. 14.127CPCh. 14 - Prob. 14.128CPCh. 14 - Prob. 14.129CPCh. 14 - Prob. 14.130CPCh. 14 - At 1000 K, Kp, = 2.1 106 and H=107.7kJ for the...Ch. 14 - Prob. 14.132CPCh. 14 - Prob. 14.133CPCh. 14 - Prob. 14.134CPCh. 14 - Prob. 14.135CPCh. 14 - Prob. 14.136CPCh. 14 - Prob. 14.137CPCh. 14 - Prob. 14.138CPCh. 14 - Prob. 14.139CPCh. 14 - Prob. 14.140CPCh. 14 - Prob. 14.141CPCh. 14 - Prob. 14.142CPCh. 14 - Prob. 14.143CPCh. 14 - Prob. 14.144CPCh. 14 - Prob. 14.145CPCh. 14 - Prob. 14.146CPCh. 14 - Prob. 14.147MPCh. 14 - Prob. 14.148MPCh. 14 - Prob. 14.149MPCh. 14 - Prob. 14.150MPCh. 14 - Prob. 14.151MPCh. 14 - Prob. 14.152MPCh. 14 - Prob. 14.153MPCh. 14 - Prob. 14.154MPCh. 14 - Prob. 14.155MPCh. 14 - Prob. 14.156MPCh. 14 - Prob. 14.157MPCh. 14 - Prob. 14.158MPCh. 14 - Prob. 14.159MP
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