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Chapter 14, Problem 14.1E
Interpretation Introduction

Interpretation:

The principal structural difference between an aldehyde and a ketone is to be stated.

Concept introduction:

A carbonyl group has a carbon atom that is bonded to an oxygen atom through a double bond and single bonded to two other carbon atoms respectively.

Aldehydes and ketones contain carbonyl LMS Integrated OWLv2, 4 terms (24 months) Printed Access Card for Seager/Slabaugh/Hansen’s Chemistry for Today: General, Organic, and Biochemistry, 9th, Chapter 14, Problem 14.1E , additional homework tip  1 functional group in their parent chain and are named by adding suffix –al and –one to the name of the parent alkane.

Expert Solution & Answer
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Answer to Problem 14.1E

The structural formula of an aldehyde is RCOH.

The structural formula of a ketone is RCOR.

Explanation of Solution

An aldehyde consists of a carbonyl group that is single bonded to minimum one hydrogen atom, whereas a ketone consists of a carbonyl group that is single bonded to two carbon atoms. The structure difference between an aldehyde and a ketone is shown below.

LMS Integrated OWLv2, 4 terms (24 months) Printed Access Card for Seager/Slabaugh/Hansen’s Chemistry for Today: General, Organic, and Biochemistry, 9th, Chapter 14, Problem 14.1E , additional homework tip  2

Figure 1

Conclusion

The structure difference between an aldehyde and a ketone is shown in Figure 1.

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Chapter 14 Solutions

LMS Integrated OWLv2, 4 terms (24 months) Printed Access Card for Seager/Slabaugh/Hansen’s Chemistry for Today: General, Organic, and Biochemistry, 9th

Ch. 14 - Each of the following names is wrong. Give the...Ch. 14 - Each of the following names is wrong. Give the...Ch. 14 - Prob. 14.13ECh. 14 - Prob. 14.14ECh. 14 - Prob. 14.15ECh. 14 - Explain why propane boils at 42C, whereas ethanal,...Ch. 14 - Use a dotted line to show hydrogen bonding between...Ch. 14 - Use a dotted line to show hydrogen bonding between...Ch. 14 - Prob. 14.19ECh. 14 - Prob. 14.20ECh. 14 - Prob. 14.21ECh. 14 - Prob. 14.22ECh. 14 - Prob. 14.23ECh. 14 - Prob. 14.24ECh. 14 - Label each of the following as acetals, ketals, or...Ch. 14 - Label each of the following as acetals, ketals, or...Ch. 14 - Label each of the following structures as a cyclic...Ch. 14 - Label each of the following structures as a...Ch. 14 - What two functional groups react to form the...Ch. 14 - Hemiacetals are sometimes referred to as potential...Ch. 14 - Complete the following statements: a. Oxidation of...Ch. 14 - Prob. 14.32ECh. 14 - Prob. 14.33ECh. 14 - Prob. 14.34ECh. 14 - Prob. 14.35ECh. 14 - Not all aldehyde give a positve Bendicts test....Ch. 14 - A stockroom assistant prepares three bottles, each...Ch. 14 - Glucose, the sugar present within the blood, gives...Ch. 14 - Fructose, present with glucose in honey, reacts...Ch. 14 - Prob. 14.40ECh. 14 - Prob. 14.41ECh. 14 - Complete the following equations. If no reaction...Ch. 14 - Complete the following equations. If no reaction...Ch. 14 - Describe the products that result when hydrogen...Ch. 14 - Prob. 14.45ECh. 14 - Draw structural formulas for the products of the...Ch. 14 - The following compounds are cyclic acetals or...Ch. 14 - The following compounds are cyclic acetals or...Ch. 14 - Write equations to show how the following...Ch. 14 - Prob. 14.50ECh. 14 - Identify the most important aldehyde and ketone...Ch. 14 - Using Table 14.3, name an aldehyde or ketone used...Ch. 14 - Prob. 14.53ECh. 14 - CH3COH(O)CH3COOHacetaldehydeaceticacid You need to...Ch. 14 - The addition of water to aldehydes and ketones...Ch. 14 - Prob. 14.56ECh. 14 - Formaldehyde levels above 0.10mg/1000L of ambient...Ch. 14 - In the IUPAC name for the following ketone, it is...Ch. 14 - Why can formaldehyde (CH2O) be prepared in the...Ch. 14 - Other addition reactions of aldehydes occur....Ch. 14 - Prob. 14.61ECh. 14 - Prob. 14.62ECh. 14 - Vanilla flavoring is either extracted from a...Ch. 14 - Prob. 14.64ECh. 14 - The use of acetone in laboratory experiments must...Ch. 14 - Prob. 14.66ECh. 14 - Prob. 14.67ECh. 14 - Which of the following would be classified as a...
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