Concept explainers
(a)
Interpretation:
Whether the statement.
Ethanol and dimethyl ether are constitutional isomer is true or false should be explained.
Concept Introduction:
Constitutional isomers or structural isomers are those which differ in bonding pattern but has same moleuclar formula.
(b)
Interpretation:
Whether the statement.
The solubility of low molecular weight ethers is comparable to low molecular weight alcohol in water is true or false should be explained.
Concept Introduction:
Solubility of organic compound is more when it is capable of forming hydrogen bond.
(c)
Interpretation:
Whether the statement.
Ethers undergo many of the same reaction that alcohols do is true or false should be explained.
Concept Introduction:
Ethers are unreactive unlike alcohols.
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Chapter 14 Solutions
Introduction to General, Organic and Biochemistry
- 14-39 Name two important alcohols derived from ethylene and give two important uses of each.arrow_forward14-40 Name two important alcohols derived from propene and give two important uses of each.arrow_forward14-62 Draw structural formulas and write IUPAC names for the eight isomeric alcohols with the molecular formula C5H12O.arrow_forward
- 14-60 Write a balanced equation for the complete combustion of ethanol, the alcohol blended with gasoline to produce E85.arrow_forward14-17 Explain in terms of noncovalent interactions why the low-molecular-weight alcohols are soluble in water but the low-molecular-weight alkanes and alkynes are not.arrow_forward14-66 1,4-Butanediol, hexane, and 1-pentanol have similar molecular weights. Their boiling points, arranged from lowest to highest, are 69°C, 138°C, and 230°C. Which compound has which boiling point?arrow_forward
- 14-21 Show hydrogen bonding between the oxygen of di ethyl ether and a hydrogen of water.arrow_forward14-49 Answer true or false. Today, the major carbon sources for the synthesis of methanol are coal and methane (natural gas), both nonrenewable resources. Today the major carbon sources for the synthesis of ethanol are petroleum and natural gas, both nonrenewable resources. Intermolecular acid-catalyzed dehydration of ethanol gives diethyl ether. Conversion of ethylene to ethylene glycol involves oxidation to ethylene oxide, followed by acid-catalyzed hydration (addition of water, to ethylene oxide. Ethylene glycol is soluble in water in all proportions. A major use of ethylene glycol is as automobile antifreeze.arrow_forward14-55 (Chemical Connections 140 The legal definition of being under the influence of alcohol is based on blood alcohol content. What is the relationship between breath alcohol content and blood alcohol content?arrow_forward
- 14-9 What is the difference in structure between a primary, a secondary, and a tertiary alcohol?arrow_forward14-24 2-Propanol (isopropyl alcohol) is commonly used as rubbing alcohol to cool the skin. 2-Hexanol, also a liquid, is not suitable for this purpose. Why?arrow_forward14-10 Which of the following are secondary alcohols? (b) (CHqKCOHarrow_forward
- Introduction to General, Organic and BiochemistryChemistryISBN:9781285869759Author:Frederick A. Bettelheim, William H. Brown, Mary K. Campbell, Shawn O. Farrell, Omar TorresPublisher:Cengage LearningOrganic And Biological ChemistryChemistryISBN:9781305081079Author:STOKER, H. Stephen (howard Stephen)Publisher:Cengage Learning,General, Organic, and Biological ChemistryChemistryISBN:9781285853918Author:H. Stephen StokerPublisher:Cengage Learning