Interpretation:
The values of the five transitions for
Concept introduction:
Spectroscopy method is used to identify the structure of the molecule. It is based on the interactions between matter and
Answer to Problem 14.66E
The values of the five transitions for
Explanation of Solution
The energy of a Morse oscillator is calculated by the formula shown below.
Where,
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•
•
•
The value of
The value of
Convert
Convert
Substitute
Substitute
Subtract equation (2) from equation (3).
Substitute the value of Planck’s constant,
The frequency of a transition in
Substitute the value of
Substitute
Subtract equation (2) from equation (6).
Substitute the value of Planck’s constant,
The frequency of a transition in
Substitute the value of
Substitute
Subtract equation (2) from equation (9).
Substitute the value of Planck’s constant,
The frequency of a transition in
Substitute the value of
Substitute
Subtract equation (2) from equation (12).
Substitute the value of Planck’s constant,
The frequency of a transition in
Substitute the value of
Substitute
Subtract equation (2) from equation (15).
Substitute the value of Planck’s constant,
The frequency of a transition in
Substitute the value of
The values of the five transitions for
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Chapter 14 Solutions
Bundle: Physical Chemistry, 2nd + Student Solutions Manual
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- what is the lewis dot structure of an excited state oxygen?arrow_forwardIf the spacings between adjacent vibrational features in a photoelectron spectroscopy experiment decrease, changing by a factor of 1/2, when you deuterate the molecule being ionized, is it more likely that the orbital from which you are ejecting an electron is from a nonbonding orbital, a p orbital localized on a C-C or C-O bond, or a s orbital localized on a C-H bond? Explain.arrow_forwardWhat is the order of decreasing vibrational frequency for C — Cl, C — Br, C — C, C — O and C — H ?arrow_forward
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