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Predict the approximate freezing points of 0.10m solutions of the following solutes dissolved in water: (a)
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- 6-111 As noted in Section 6-8C, the amount of external pressure that must be applied to a more concentrated solution to stop the passage of solvent molecules across a semipermeable membrane is known as the osmotic pressure The osmotic pressure obeys a law similar in form to the ideal gas law (discussed in Section 5-4), where Substituting for pressure and solving for osmotic pressures gives the following equation: RT MRT, where M is the concentration or molarity of the solution. (a) Determine the osmotic pressure at 25°C of a 0.0020 M sucrose (C12H22O11) solution. (b) Seawater contains 3.4 g of salts for every liter of solution. Assuming the solute consists entirely of NaCl (and complete dissociation of the NaCI salt), calculate the osmotic pressure of seawater at 25°C. (c) The average osmotic pressure of blood is 7.7 atm at 25°C. What concentration of glucose (C6H12O6) will be isotonic with blood? (d) Lysozyme is an enzyme that breaks bacterial cell walls. A solution containing 0.150 g of this enzyme in 210. mL of solution has an osmotic pressure of 0.953 torr at 25°C. What is the molar mass of lysozyme? (e) The osmotic pressure of an aqueous solution of a certain protein was measured in order to determine the protein's molar mass. The solution contained 3.50 mg of protein dissolved in sufficient water to form 5.00 mL of solution. The osmotic pressure of the solution at 25°C was found to be 1.54 torr. Calculate the molar mass of the protein.arrow_forward6-67 Calculate the freezing points of solutions made by dissolving 1.00 mole of each of the following ionic solutes in 1000. g of H2O. (a) NaCI (b) MgCI2 (c) (NH4)2CO3 (d) AI(HCO3)3arrow_forwardWhat is the freezing point and normal boiling point of a solution made by adding 39 mL of acetone, C3H6O, to 225 mL of water? The densities of acetone and water are 0.790 g/cm3 and 1.00 g/cm3, respectively.arrow_forward
- The dispersed phase of a certain colloidal dispersion consists of spheres of diameter 1.0 102 nm. (a) What are the volume (V=43r2) and surface area (A = r2) of each sphere? (b) How many spheres are required to give a total volume of 1.0 cm3? What is the total surface area of these spheres in square meters?arrow_forwardCalcium chloride, CaCl2, has been used to melt ice from roadways. Given that the saturated solution is 32% CaCl2 by mass, estimate the freezing point.arrow_forwardAn aqueous solution of sodium bromide freezes at 1.61 C. What is the total molality of solute particles? How many grams of sodium bromide are present in 1 kg of water? (Assume an ideal value for the vant Hoff factor.)arrow_forward
- A solution is made by dissolving 34.0 g of NaCl in 100 g of H2O at 0C. Based on the data in Table 8-1, should this solution be characterized as a. saturated or unsaturated b. dilute or concentratedarrow_forwardA 1.00 mol/kg aqueous sulfuric acid solution, H2SO4,freezes at 4.04 C. Calculate i, the vant Hoff factor,for sulfuric acid in this solution.arrow_forwardWhat is the freezing point of a solution of dibromobenzene, C6H4Br2, in 0.250 kg of benzene, if the solution boils at 83.5 C?arrow_forward
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