General Chemistry: Principles and Modern Applications - With Solutions Manual and Modified MasteringChemistry Code
11th Edition
ISBN: 9780134641003
Author: Petrucci
Publisher: PEARSON
expand_more
expand_more
format_list_bulleted
Concept explainers
Videos
Question
Chapter 14, Problem 99IAE
Interpretation Introduction
Interpretation:
In the given cooling curve, the reason for absence of a horizontal straight line portion which can be seen in the cooling curve for pure water, should be discussed.
Concept introduction:
Cooling curve is a graphical representation of the changes in temperature with time for a substance as it cools down. When a phase change occurs, the temperature remains constant. So, it will show a horizontal line near the freezing temperature.
Expert Solution & Answer
Want to see the full answer?
Check out a sample textbook solution
Students have asked these similar questions
Please provide complete solution.
Kf (°C/m) of water
1.86
Freezing Point of Water, °C
0.00
SOLVENT
100.0 g water
SHOW COMPLETE SOLUTION AND WRITE LEGIBLY
Pressure was exerted with a piston on molten naphthalene at 95 °C. The vapor pressure of naphthalene when the applied pressure is 1.0 bar is 2.0 kPa. What is the vapor pressure when the pressure on the liquid is 15 MPa? The mass density of naphthalene at this temperature is 1.16 g cm-1
Data was collected to determine the molar mass of a nonvolatile solid solute when dissolved in cyclohexane. Complete the table for the analysis. Record calculated values with the correct number of significant figures.
B. Freezing point of Cyclohexane plus unknown solute
Mass of cyclohexane (g) 10.14
Mass of added solute (g). 0.255
C. Calculations
1. Kf for cyclohexane (degrees C x kg/mol) 20.0
2. Freezing point change 3.04
3. Mass of cyclohexane in solution (kg)?
4. Moles of sulute, total (mol)? (Show calculation)
5. Mass of solute in solution, total (g)?
6. Molar mass of solute? (g/mol) (Show calculation)
Chapter 14 Solutions
General Chemistry: Principles and Modern Applications - With Solutions Manual and Modified MasteringChemistry Code
Ch. 14 - Which of the following do you expect to be most...Ch. 14 - Which of the following is moderately soluble both...Ch. 14 - Substances that dissolve in water generally do not...Ch. 14 - Prob. 4ECh. 14 - Two of the substances listed here highly soluble...Ch. 14 - Benzoic acid, C8H8COOH, is much more soluble in...Ch. 14 - Prob. 7ECh. 14 - Explain the observation that all metal nitrates...Ch. 14 - A saturated aqueous solution of NaBr at 20C...Ch. 14 - Prob. 10E
Ch. 14 - Prob. 11ECh. 14 - You are asked to prepare 125.0 mL of 0.0321 M...Ch. 14 - Prob. 13ECh. 14 - Prob. 14ECh. 14 - Prob. 15ECh. 14 - Prob. 16ECh. 14 - The sulfate ion level in a municipal water supply...Ch. 14 - A water sample is found to have 9.4 ppb of...Ch. 14 - Prob. 19ECh. 14 - Prob. 20ECh. 14 - How many milliliters at the ethanol-water solution...Ch. 14 - Prob. 22ECh. 14 - What is the molarity of CO2 in liter ocean water...Ch. 14 - Prob. 24ECh. 14 - Prob. 25ECh. 14 - Prob. 26ECh. 14 - How many grams of iodine, l2 , must be dissolved...Ch. 14 - How many grams of water would you add to 1.00 kg...Ch. 14 - Prob. 29ECh. 14 - A 10.00%-by-man solution of ethanol, CH2CH2OH , in...Ch. 14 - Prob. 31ECh. 14 - Prob. 32ECh. 14 - Prob. 33ECh. 14 - Prob. 34ECh. 14 - What volume of glycerol,...Ch. 14 - Prob. 36ECh. 14 - Prob. 37ECh. 14 - The amount of CO2 in the ocean is approximately...Ch. 14 - Prob. 39ECh. 14 - Prob. 40ECh. 14 - Prob. 41ECh. 14 - Prob. 42ECh. 14 - Under an O2(g) pressure of 1.00 atm, 28.31mL of...Ch. 14 - Prob. 44ECh. 14 - Natural gas consists about 90% methane, CM. Assume...Ch. 14 - At 1.00 atm, the solubility of O2 in water is...Ch. 14 - The aqueous solubility at 20C of Ar at 1.00 atm...Ch. 14 - Prob. 48ECh. 14 - Prob. 49ECh. 14 - Prob. 50ECh. 14 - What are the partial and total vapor pressures of...Ch. 14 - Prob. 52ECh. 14 - Calculate the vapor pressure at 25C of a solution...Ch. 14 - Calculate the vapor pressure at 20C of a saturated...Ch. 14 - Styrene, used in the manufacture of polystyrene...Ch. 14 - Prob. 56ECh. 14 - A benzene-toluene solution with banz=0.300 has a...Ch. 14 - Prob. 58ECh. 14 - Prob. 59ECh. 14 - Prob. 60ECh. 14 - Prob. 61ECh. 14 - Prob. 62ECh. 14 - Prob. 63ECh. 14 - Prob. 64ECh. 14 - Prob. 65ECh. 14 - Use the concentration of an istonic solution,...Ch. 14 - Prob. 67ECh. 14 - The two solutions pictured here are separated by a...Ch. 14 - of an unknown compound reduces e freezing point of...Ch. 14 - Prob. 70ECh. 14 - Prob. 71ECh. 14 - Prob. 72ECh. 14 - A compound is 42.9% C, 2.4% H, 16.7%N, and 38.1%...Ch. 14 - Nicotinamide is a water-soluble vitamin important...Ch. 14 - Prob. 75ECh. 14 - Coniferin is glycoside (a derivative of a sugar)...Ch. 14 - Cooks often add some salt to water before boding...Ch. 14 - An important test for the purity of an organic...Ch. 14 - Prob. 79ECh. 14 - If ocean water consisted of 3.5% salt, what would...Ch. 14 - Predict the approximate freezing points of 0.10m...Ch. 14 - Calculate the van’t Hoff factors of the following...Ch. 14 - NH2(aq) conducts electric current only weakly. The...Ch. 14 - Prob. 84ECh. 14 - Prob. 85ECh. 14 - Prob. 86ECh. 14 - Prob. 87IAECh. 14 - Prob. 88IAECh. 14 - Prob. 89IAECh. 14 - Prob. 90IAECh. 14 - A solid mixture consists of 85.0% KNO2 and 15.0%...Ch. 14 - Suppose you have available 2.50 L of a solution (d...Ch. 14 - Prob. 93IAECh. 14 - Prob. 94IAECh. 14 - Prob. 95IAECh. 14 - Nitrobenzene, C6H2NO2 , and benzene, C6H8 , are...Ch. 14 - Prob. 97IAECh. 14 - Prob. 98IAECh. 14 - Prob. 99IAECh. 14 - Suppose that I 00mg of gold obtained in a...Ch. 14 - At 20C , liquid benzene has a density of...Ch. 14 - The two compounds whose structures are depicted...Ch. 14 - Prob. 103IAECh. 14 - Prob. 104IAECh. 14 - Prob. 105IAECh. 14 - We noted m Figure 14-17 that the liquid and vapor...Ch. 14 - A saturated solution prepared at 70C contains...Ch. 14 - Prob. 108IAECh. 14 - Prob. 109IAECh. 14 - Prob. 110IAECh. 14 - Prob. 111IAECh. 14 - Prob. 112IAECh. 14 - Prob. 113FPCh. 14 - The phase diagram shown is for mixtures of HCI and...Ch. 14 - The laboratory device pictured on the following...Ch. 14 - Prob. 116FPCh. 14 - Prob. 117SAECh. 14 - Briefly describe each of the following ides or...Ch. 14 - Explain the important distinctions between each...Ch. 14 - Prob. 120SAECh. 14 - Prob. 121SAECh. 14 - Prob. 122SAECh. 14 - Prob. 123SAECh. 14 - An ideal liquid solution has two volatile...Ch. 14 - Prob. 125SAECh. 14 - Prob. 126SAECh. 14 - A solution (d=1.159g/mL) is 62.0% glycerol,...Ch. 14 - Prob. 128SAECh. 14 - Prob. 129SAECh. 14 - Prob. 130SAECh. 14 - Prob. 131SAECh. 14 - Prob. 132SAECh. 14 - Prob. 133SAECh. 14 - What is the mole fractions of a monvolatile solute...Ch. 14 - What is the osmotic pressure, in bar, of 15.2L of...Ch. 14 - What is the weight percent of 23.4 g of CaF2 if...Ch. 14 - Prob. 137SAECh. 14 - Prob. 138SAE
Knowledge Booster
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.Similar questions
- From the data presented in Figure 12.11, determine which has the more positive enthalpy of solution: NaCl or NH4Cl. Explain.arrow_forwardIn terms of Raoults law, distinguish between an ideal liquid-liquid solution and a nonideal liquid-liquid solution. lf a solution is ideal, what is true about Hsoln, T for the solution formation, and the interactive forces within the pure solute and pure solvent as compared to the interactive forces within the solution? Give an example of an ideal solution. Answer the previous two questions for solutions that exhibit either negative or positive deviations from Raoults law.arrow_forwardA water solution of sodium hypochlorite (NaOCl) is used as laundry bleach. The concentration of sodium hypochlorite is 0.75 m. Express this concentration as a mole fraction.arrow_forward
- If a volatile solute is added to a volatile solvent, both substances contribute to the vapor pressure over the solution. Assuming an ideal solution, the vapor pressure of each is given by Raoults law, and the total vapor pressure is the sum of the vapor pressures for each component. A solution, assumed to be ideal, is made from 1.0 mol of toluene (C6H5CH3) and 2.0 mol of benzene (C6H6). The vapor pressures of the pure solvents are 22 mm Hg and 75 mm Hg, respectively, at 20 C. What is the total vapor pressure of the mixture? What is the mole fraction of each component in the liquid and in the vapor?arrow_forwardBoiling Point Elevation/Freezing Point DepressionT = m KWhere: T = T(solution) - T(pure solvent) * m = (# moles solute / Kg solvent) Kb = boiling point elevation constant. Kf = freezing point depression constant. Kb and Kf depend only on the SOLVENT. Below are some common values. Use these values for the calculations that follow. Solvent Formula Kb (°C / m) Kf (°C / m) Water H2O 0.512 -1.86 Ethanol CH3CH2OH 1.22 -1.99 Chloroform CHCl3 3.67 Benzene C6H6 2.53 -5.12 Diethyl ether CH3CH2OCH2CH3 2.02 note that ΔT as defined above will be a negative number for freezing point depression. Therefore, Kf must also be given as a negative number.arrow_forwardPart II. Determination of molecular weight for ethyl alcohol Freezing point, °C DTf Mass of solute, g mass of solvent, kg Calculated molecular weight, g/mol -2.30 0C ΔTf = T0f – Tf 0.0 °C -(-2.30 °C) = 2.30 0C 6.202 g 0.1kg Click or tap here to enter text.arrow_forward
arrow_back_ios
arrow_forward_ios
Recommended textbooks for you
Physical ChemistryChemistryISBN:9781133958437Author:Ball, David W. (david Warren), BAER, TomasPublisher:Wadsworth Cengage Learning,
ChemistryChemistryISBN:9781305957404Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCostePublisher:Cengage Learning
Chemistry: An Atoms First ApproachChemistryISBN:9781305079243Author:Steven S. Zumdahl, Susan A. ZumdahlPublisher:Cengage Learning
Chemistry: Matter and ChangeChemistryISBN:9780078746376Author:Dinah Zike, Laurel Dingrando, Nicholas Hainen, Cheryl WistromPublisher:Glencoe/McGraw-Hill School Pub Co
Macroscale and Microscale Organic ExperimentsChemistryISBN:9781305577190Author:Kenneth L. Williamson, Katherine M. MastersPublisher:Brooks Cole
Physical Chemistry
Chemistry
ISBN:9781133958437
Author:Ball, David W. (david Warren), BAER, Tomas
Publisher:Wadsworth Cengage Learning,
Chemistry
Chemistry
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Cengage Learning
Chemistry: An Atoms First Approach
Chemistry
ISBN:9781305079243
Author:Steven S. Zumdahl, Susan A. Zumdahl
Publisher:Cengage Learning
Chemistry: Matter and Change
Chemistry
ISBN:9780078746376
Author:Dinah Zike, Laurel Dingrando, Nicholas Hainen, Cheryl Wistrom
Publisher:Glencoe/McGraw-Hill School Pub Co
Macroscale and Microscale Organic Experiments
Chemistry
ISBN:9781305577190
Author:Kenneth L. Williamson, Katherine M. Masters
Publisher:Brooks Cole
Solutions: Crash Course Chemistry #27; Author: Crash Course;https://www.youtube.com/watch?v=9h2f1Bjr0p4;License: Standard YouTube License, CC-BY