GENERAL,ORGANIC,+BIOCHEMISTRY
GENERAL,ORGANIC,+BIOCHEMISTRY
10th Edition
ISBN: 9781260148954
Author: Denniston
Publisher: RENT MCG
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Question
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Chapter 14.1, Problem 14.3PP

(a)

Interpretation Introduction

Interpretation:

The structure of the given compound has to be drawn.

Concept Introduction:

IUPAC naming of Aromatic Carboxylic acids

  1. 1) The simplest aromatic carboxylic acid is benzoic acid.
  2. 2) Aromatic carboxylic acids are generally derivatives of benzoic acid.
  3. 3) The suffix –oic acid is used in IUPAC system and the suffix –ic acid is used in common system and is attached to the appropriate prefix.
  4. 4) The phenyl group is treated as substituent and the name is obtained from the appropriate alkanoic acid parent chain.

(a)

Expert Solution
Check Mark

Answer to Problem 14.3PP

The structure of the given compound is,

GENERAL,ORGANIC,+BIOCHEMISTRY, Chapter 14.1, Problem 14.3PP , additional homework tip  1

Explanation of Solution

The given compound is o-toluicacid

o-toluicacid is derivative of benzoic acid.  The substituent CH3 is bonded to carbon -2 of the benzene ring.

The structure of the given compound is,

GENERAL,ORGANIC,+BIOCHEMISTRY, Chapter 14.1, Problem 14.3PP , additional homework tip  2

This compound is o-toluicacid or 2-methylbenzoicacid

(b)

Interpretation Introduction

Interpretation:

The structure of the given compound has to be drawn.

Concept Introduction:

IUPAC naming of Aromatic Carboxylic acids

  1. 1) The simplest aromatic carboxylic acid is benzoic acid.
  2. 2) Aromatic carboxylic acids are generally derivatives of benzoic acid.
  3. 3) The suffix –oic acid is used in IUPAC system and the suffix –ic acid is used in common system and is attached to the appropriate prefix.
  4. 4) The phenyl group is treated as substituent and the name is obtained from the appropriate alkanoic acid parent chain.

(b)

Expert Solution
Check Mark

Answer to Problem 14.3PP

The structure of the given compound is,

GENERAL,ORGANIC,+BIOCHEMISTRY, Chapter 14.1, Problem 14.3PP , additional homework tip  3

Explanation of Solution

The given compound is 2,4,6-tribromobenzoicacid

The substituent Br is bonded to carbon -2,4 and6 of the benzene ring.

The structure of the given compound is,

GENERAL,ORGANIC,+BIOCHEMISTRY, Chapter 14.1, Problem 14.3PP , additional homework tip  4

This compound is 2,4,6-tribromobenzoicacid.

(c)

Interpretation Introduction

Interpretation:

The structure of the given compound has to be drawn.

Concept Introduction:

IUPAC naming of Aromatic Carboxylic acids

  1. 1) The simplest aromatic carboxylic acid is benzoic acid.
  2. 2) Aromatic carboxylic acids are generally derivatives of benzoic acid.
  3. 3) The suffix –oic acid is used in IUPAC system and the suffix –ic acid is used in common system and is attached to the appropriate prefix.
  4. 4) The phenyl group is treated as substituent and the name is obtained from the appropriate alkanoic acid parent chain.

(c)

Expert Solution
Check Mark

Answer to Problem 14.3PP

The structure of the given compound is,

GENERAL,ORGANIC,+BIOCHEMISTRY, Chapter 14.1, Problem 14.3PP , additional homework tip  5

Explanation of Solution

The given compound is 2,2,2-triphenylethanoicacid

The substituent phenyl is bonded to carbon -2 of the parent chain.

The structure of the given compound is,

GENERAL,ORGANIC,+BIOCHEMISTRY, Chapter 14.1, Problem 14.3PP , additional homework tip  6

This compound is 2,2,2-triphenylethanoicacid or 2,2,2-triphenylaceticacid

(d)

Interpretation Introduction

Interpretation:

The structure of the given compound has to be drawn.

Concept Introduction:

IUPAC naming of Aromatic Carboxylic acids

  1. 1) The simplest aromatic carboxylic acid is benzoic acid.
  2. 2) Aromatic carboxylic acids are generally derivatives of benzoic acid.
  3. 3) The suffix –oic acid is used in IUPAC system and the suffix –ic acid is used in common system and is attached to the appropriate prefix.
  4. 4) The phenyl group is treated as substituent and the name is obtained from the appropriate alkanoic acid parent chain.

(d)

Expert Solution
Check Mark

Answer to Problem 14.3PP

The structure of the given compound is,

GENERAL,ORGANIC,+BIOCHEMISTRY, Chapter 14.1, Problem 14.3PP , additional homework tip  7

Explanation of Solution

The given compound is p-toluicacid.

p-toluicacid is derivative of benzoic acid.  The substituent CH3 is bonded to carbon -4 of the benzene ring.

The structure of the given compound is,

GENERAL,ORGANIC,+BIOCHEMISTRY, Chapter 14.1, Problem 14.3PP , additional homework tip  8

This compound is p-toluicacid or 4-methylbenzoicacid.

(e)

Interpretation Introduction

Interpretation:

The structure of the given compound has to be drawn.

Concept Introduction:

IUPAC naming of Aromatic Carboxylic acids

  1. 1) The simplest aromatic carboxylic acid is benzoic acid.
  2. 2) Aromatic carboxylic acids are generally derivatives of benzoic acid.
  3. 3) The suffix –oic acid is used in IUPAC system and the suffix –ic acid is used in common system and is attached to the appropriate prefix.
  4. 4) The phenyl group is treated as substituent and the name is obtained from the appropriate alkanoic acid parent chain.

(e)

Expert Solution
Check Mark

Answer to Problem 14.3PP

The structure of the given compound is,

GENERAL,ORGANIC,+BIOCHEMISTRY, Chapter 14.1, Problem 14.3PP , additional homework tip  9

Explanation of Solution

The given compound is 3-phenylhexanoic acid.

The substituent phenyl is bonded to carbon -3 of the parent chain of the carboxylic acid.

The structure of the given compound is,

GENERAL,ORGANIC,+BIOCHEMISTRY, Chapter 14.1, Problem 14.3PP , additional homework tip  10

(f)

Interpretation Introduction

Interpretation:

The structure of the given compound has to be drawn.

Concept Introduction:

IUPAC naming of Aromatic Carboxylic acids

  1. 1) The simplest aromatic carboxylic acid is benzoic acid.
  2. 2) Aromatic carboxylic acids are generally derivatives of benzoic acid.
  3. 3) The suffix –oic acid is used in IUPAC system and the suffix –ic acid is used in common system and is attached to the appropriate prefix.
  4. 4) The phenyl group is treated as substituent and the name is obtained from the appropriate alkanoic acid parent chain.

(f)

Expert Solution
Check Mark

Answer to Problem 14.3PP

The structure of the given compound is,

GENERAL,ORGANIC,+BIOCHEMISTRY, Chapter 14.1, Problem 14.3PP , additional homework tip  11

Explanation of Solution

The given compound is 3-phenycyclohexanecarboxylic acid.

The substituent phenyl is bonded to carbon -3 of the cycloalkane parent chain of the carboxylic acid.

The structure of the given compound is,

GENERAL,ORGANIC,+BIOCHEMISTRY, Chapter 14.1, Problem 14.3PP , additional homework tip  12

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Chapter 14 Solutions

GENERAL,ORGANIC,+BIOCHEMISTRY

Ch. 14.1 - Prob. 14.5PPCh. 14.1 - Prob. 14.6PPCh. 14.2 - Prob. 14.7PPCh. 14.2 - Prob. 14.8PPCh. 14.2 - Prob. 14.9PPCh. 14.2 - Prob. 14.7QCh. 14.2 - Prob. 14.8QCh. 14.3 - Prob. 14.10PPCh. 14.3 - Write the common and IUPAC names for each of the...Ch. 14.3 - Prob. 14.9QCh. 14.3 - Prob. 14.10QCh. 14 - Prob. 14.11QPCh. 14 - Prob. 14.12QPCh. 14 - Prob. 14.13QPCh. 14 - Prob. 14.14QPCh. 14 - Prob. 14.15QPCh. 14 - Prob. 14.16QPCh. 14 - Prob. 14.17QPCh. 14 - Which member in each of the following pairs is...Ch. 14 - Prob. 14.19QPCh. 14 - Prob. 14.20QPCh. 14 - Prob. 14.21QPCh. 14 - Prob. 14.22QPCh. 14 - Prob. 14.23QPCh. 14 - Prob. 14.24QPCh. 14 - Prob. 14.25QPCh. 14 - Prob. 14.26QPCh. 14 - Prob. 14.27QPCh. 14 - Prob. 14.28QPCh. 14 - Prob. 14.29QPCh. 14 - Prob. 14.30QPCh. 14 - Prob. 14.31QPCh. 14 - Prob. 14.32QPCh. 14 - Prob. 14.33QPCh. 14 - Prob. 14.34QPCh. 14 - Prob. 14.35QPCh. 14 - Prob. 14.36QPCh. 14 - Prob. 14.37QPCh. 14 - Prob. 14.38QPCh. 14 - Prob. 14.39QPCh. 14 - Prob. 14.40QPCh. 14 - Prob. 14.41QPCh. 14 - Prob. 14.42QPCh. 14 - Prob. 14.43QPCh. 14 - Prob. 14.44QPCh. 14 - Prob. 14.45QPCh. 14 - Prob. 14.46QPCh. 14 - Prob. 14.47QPCh. 14 - Prob. 14.48QPCh. 14 - Write an equation representing the oxidation of...Ch. 14 - Prob. 14.50QPCh. 14 - Prob. 14.51QPCh. 14 - Prob. 14.52QPCh. 14 - Prob. 14.54QPCh. 14 - Write an equation representing the neutralization...Ch. 14 - Prob. 14.56QPCh. 14 - Prob. 14.57QPCh. 14 - Prob. 14.58QPCh. 14 - Prob. 14.59QPCh. 14 - Prob. 14.60QPCh. 14 - Prob. 14.61QPCh. 14 - Prob. 14.62QPCh. 14 - Prob. 14.63QPCh. 14 - Draw condensed formulas for each of the following...Ch. 14 - Prob. 14.65QPCh. 14 - Prob. 14.66QPCh. 14 - Prob. 14.67QPCh. 14 - Prob. 14.68QPCh. 14 - Prob. 14.69QPCh. 14 - Prob. 14.70QPCh. 14 - Prob. 14.71QPCh. 14 - Prob. 14.72QPCh. 14 - Prob. 14.73QPCh. 14 - Prob. 14.74QPCh. 14 - Prob. 14.75QPCh. 14 - Prob. 14.76QPCh. 14 - Prob. 14.77QPCh. 14 - Prob. 14.78QPCh. 14 - Prob. 14.79QPCh. 14 - Prob. 14.80QPCh. 14 - Prob. 14.81QPCh. 14 - Prob. 14.82QPCh. 14 - Prob. 14.83QPCh. 14 - Prob. 14.84QPCh. 14 - Prob. 14.85QPCh. 14 - Prob. 14.86QPCh. 14 - Prob. 14.87QPCh. 14 - Prob. 14.88QPCh. 14 - Prob. 14.89QPCh. 14 - Prob. 14.90QPCh. 14 - Prob. 14.91QPCh. 14 - Prob. 14.92QPCh. 14 - Prob. 14.93QPCh. 14 - Prob. 14.94QPCh. 14 - Prob. 14.95QPCh. 14 - Prob. 14.96QPCh. 14 - Prob. 14.97QPCh. 14 - What is meant by a phosphoanhydride bond? Ch. 14 - Prob. 14.99QPCh. 14 - Prob. 14.100QPCh. 14 - Prob. 14.101QPCh. 14 - Prob. 14.102QPCh. 14 - Prob. 14.103QPCh. 14 - Prob. 2MCPCh. 14 - Consider the Chapter Map, and explain the...Ch. 14 - Prob. 4MCPCh. 14 - Prob. 6MCPCh. 14 - Triglycerides are the major lipid storage form in...Ch. 14 - Prob. 10MCPCh. 14 - Acetyl coenzyme A (acetyl CoA) can serve as a...Ch. 14 - Prob. 12MCP
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