GENERAL,ORGANIC,+BIOCHEMISTRY
GENERAL,ORGANIC,+BIOCHEMISTRY
10th Edition
ISBN: 9781260148954
Author: Denniston
Publisher: RENT MCG
Question
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Chapter 14.3, Problem 14.9Q

(a)

Interpretation Introduction

Interpretation:

The IUPAC names of the acid chloride and carboxylate anion reactants and acid anhydride products have to be written.

Concept Introduction:

Naming of Acid Chloride:

Acid chlorides are derivatives of carboxylic acids with the formula,

GENERAL,ORGANIC,+BIOCHEMISTRY, Chapter 14.3, Problem 14.9Q , additional homework tip  1

Acid chlorides are named by replacing the –ic acid ending of the common name with –yl chloride and –oic acid ending of the IUPAC name of the carboxylic acid with –oyl chloride.

Naming of Acid Anhydrides:

Acid anhydrides are compounds with the formula,

GENERAL,ORGANIC,+BIOCHEMISTRY, Chapter 14.3, Problem 14.9Q , additional homework tip  2

Acid anhydride is divided into symmetrical and unsymmetrical anhydrides.

Symmetrical anhydrides: contain same acyl groups.  They are named by replacing acid ending of the carboxylic acid with the word anhydride.

Unsymmetrical anhydrides: contain different acyl groups.  They are named by arranging the names of two-parent carboxylic acid followed by the word anhydride.  The names of the carboxylic acid are arranged by size or in alphabetical order.

(b)

Interpretation Introduction

Interpretation:

The IUPAC names of the acid chloride and carboxylate anion reactants and acid anhydride products have to be written.

Concept Introduction:

Naming of Acid Chloride:

Acid chlorides are derivatives of carboxylic acids with the formula,

GENERAL,ORGANIC,+BIOCHEMISTRY, Chapter 14.3, Problem 14.9Q , additional homework tip  3

Acid chlorides are named by replacing the –ic acid ending of the common name with –yl chloride and –oic acid ending of the IUPAC name of the carboxylic acid with –oyl chloride.

Naming of Acid Anhydrides:

Acid anhydrides are compounds with the formula,

GENERAL,ORGANIC,+BIOCHEMISTRY, Chapter 14.3, Problem 14.9Q , additional homework tip  4

Acid anhydride is divided into symmetrical and unsymmetrical anhydrides.

Symmetrical anhydrides: contain same acyl groups.  They are named by replacing acid ending of the carboxylic acid with the word anhydride.

Unsymmetrical anhydrides: contain different acyl groups.  They are named by arranging the names of two-parent carboxylic acid followed by the word anhydride.  The names of the carboxylic acid are arranged by size or in alphabetical order.

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Chapter 14 Solutions

GENERAL,ORGANIC,+BIOCHEMISTRY

Ch. 14.1 - Prob. 14.5PPCh. 14.1 - Prob. 14.6PPCh. 14.2 - Prob. 14.7PPCh. 14.2 - Prob. 14.8PPCh. 14.2 - Prob. 14.9PPCh. 14.2 - Prob. 14.7QCh. 14.2 - Prob. 14.8QCh. 14.3 - Prob. 14.10PPCh. 14.3 - Write the common and IUPAC names for each of the...Ch. 14.3 - Prob. 14.9QCh. 14.3 - Prob. 14.10QCh. 14 - Prob. 14.11QPCh. 14 - Prob. 14.12QPCh. 14 - Prob. 14.13QPCh. 14 - Prob. 14.14QPCh. 14 - Prob. 14.15QPCh. 14 - Prob. 14.16QPCh. 14 - Prob. 14.17QPCh. 14 - Which member in each of the following pairs is...Ch. 14 - Prob. 14.19QPCh. 14 - Prob. 14.20QPCh. 14 - Prob. 14.21QPCh. 14 - Prob. 14.22QPCh. 14 - Prob. 14.23QPCh. 14 - Prob. 14.24QPCh. 14 - Prob. 14.25QPCh. 14 - Prob. 14.26QPCh. 14 - Prob. 14.27QPCh. 14 - Prob. 14.28QPCh. 14 - Prob. 14.29QPCh. 14 - Prob. 14.30QPCh. 14 - Prob. 14.31QPCh. 14 - Prob. 14.32QPCh. 14 - Prob. 14.33QPCh. 14 - Prob. 14.34QPCh. 14 - Prob. 14.35QPCh. 14 - Prob. 14.36QPCh. 14 - Prob. 14.37QPCh. 14 - Prob. 14.38QPCh. 14 - Prob. 14.39QPCh. 14 - Prob. 14.40QPCh. 14 - Prob. 14.41QPCh. 14 - Prob. 14.42QPCh. 14 - Prob. 14.43QPCh. 14 - Prob. 14.44QPCh. 14 - Prob. 14.45QPCh. 14 - Prob. 14.46QPCh. 14 - Prob. 14.47QPCh. 14 - Prob. 14.48QPCh. 14 - Write an equation representing the oxidation of...Ch. 14 - Prob. 14.50QPCh. 14 - Prob. 14.51QPCh. 14 - Prob. 14.52QPCh. 14 - Prob. 14.54QPCh. 14 - Write an equation representing the neutralization...Ch. 14 - Prob. 14.56QPCh. 14 - Prob. 14.57QPCh. 14 - Prob. 14.58QPCh. 14 - Prob. 14.59QPCh. 14 - Prob. 14.60QPCh. 14 - Prob. 14.61QPCh. 14 - Prob. 14.62QPCh. 14 - Prob. 14.63QPCh. 14 - Draw condensed formulas for each of the following...Ch. 14 - Prob. 14.65QPCh. 14 - Prob. 14.66QPCh. 14 - Prob. 14.67QPCh. 14 - Prob. 14.68QPCh. 14 - Prob. 14.69QPCh. 14 - Prob. 14.70QPCh. 14 - Prob. 14.71QPCh. 14 - Prob. 14.72QPCh. 14 - Prob. 14.73QPCh. 14 - Prob. 14.74QPCh. 14 - Prob. 14.75QPCh. 14 - Prob. 14.76QPCh. 14 - Prob. 14.77QPCh. 14 - Prob. 14.78QPCh. 14 - Prob. 14.79QPCh. 14 - Prob. 14.80QPCh. 14 - Prob. 14.81QPCh. 14 - Prob. 14.82QPCh. 14 - Prob. 14.83QPCh. 14 - Prob. 14.84QPCh. 14 - Prob. 14.85QPCh. 14 - Prob. 14.86QPCh. 14 - Prob. 14.87QPCh. 14 - Prob. 14.88QPCh. 14 - Prob. 14.89QPCh. 14 - Prob. 14.90QPCh. 14 - Prob. 14.91QPCh. 14 - Prob. 14.92QPCh. 14 - Prob. 14.93QPCh. 14 - Prob. 14.94QPCh. 14 - Prob. 14.95QPCh. 14 - Prob. 14.96QPCh. 14 - Prob. 14.97QPCh. 14 - What is meant by a phosphoanhydride bond? Ch. 14 - Prob. 14.99QPCh. 14 - Prob. 14.100QPCh. 14 - Prob. 14.101QPCh. 14 - Prob. 14.102QPCh. 14 - Prob. 14.103QPCh. 14 - Prob. 2MCPCh. 14 - Consider the Chapter Map, and explain the...Ch. 14 - Prob. 4MCPCh. 14 - Prob. 6MCPCh. 14 - Triglycerides are the major lipid storage form in...Ch. 14 - Prob. 10MCPCh. 14 - Acetyl coenzyme A (acetyl CoA) can serve as a...Ch. 14 - Prob. 12MCP
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