ORGANIC CHEMISTRY E-BOOK W/SMARTWORK5
2nd Edition
ISBN: 9780393664034
Author: KARTY
Publisher: NORTON
expand_more
expand_more
format_list_bulleted
Question
Chapter 15, Problem 15.17P
Interpretation Introduction
Interpretation:
The frequencies of the stretching vibrations indicated in each of the given molecules are to be estimated by using Table 15-2.
Concept introduction:
The frequencies of the stretching vibrations are estimated from the type of bond and the frequency range given for that bond. Also frequency range for the given type of bond is identified by the compound class to which that bond resembles in the molecule.
Expert Solution & Answer
Want to see the full answer?
Check out a sample textbook solution
Students have asked these similar questions
Label below statement as True or False.
When a nucleus is strongly shielded, the effective field is smaller than the applied field and the absorption is shifted upfield .
Match the spectra below to the molecule that most likely produces that spectra. Then, identify key absorption on the spectra.
Identify all of the peaks in the spectrum. State the Experimental wavelength, Literature wavelength, peak characteristic, and assignment.
DOWN BELOW IS AN EXAMPLE...
Experimental Wavelength (cm-1)
Literature wavelength (cm-1)
Peak characteristic
assignment
3001cm-1,
3043cm-1
3010cm-1
sp2 C-H stretching
alkene
2924cm-1
2900 -2980cm-1
sp3 C-H stretching
Alkyl C-H
1614cm-1
1500 -1650cm-1
C=C stretch
alkene
1443cm-1
1350-1450cm-1
C-H bend
C-H
Chapter 15 Solutions
ORGANIC CHEMISTRY E-BOOK W/SMARTWORK5
Ch. 15 - Prob. 15.1PCh. 15 - Prob. 15.2PCh. 15 - Prob. 15.3PCh. 15 - Prob. 15.4PCh. 15 - Prob. 15.5PCh. 15 - Prob. 15.6PCh. 15 - Prob. 15.7PCh. 15 - Prob. 15.8PCh. 15 - Prob. 15.9PCh. 15 - Prob. 15.10P
Ch. 15 - Prob. 15.11PCh. 15 - Prob. 15.12PCh. 15 - Prob. 15.13PCh. 15 - Prob. 15.14PCh. 15 - Prob. 15.15PCh. 15 - Prob. 15.16PCh. 15 - Prob. 15.17PCh. 15 - Prob. 15.18PCh. 15 - Prob. 15.19PCh. 15 - Prob. 15.20PCh. 15 - Prob. 15.21PCh. 15 - Prob. 15.22PCh. 15 - Prob. 15.23PCh. 15 - Prob. 15.24PCh. 15 - Prob. 15.25PCh. 15 - Prob. 15.26PCh. 15 - Prob. 15.27PCh. 15 - Prob. 15.28PCh. 15 - Prob. 15.29PCh. 15 - Prob. 15.30PCh. 15 - Prob. 15.31PCh. 15 - Prob. 15.32PCh. 15 - Prob. 15.33PCh. 15 - Prob. 15.34PCh. 15 - Prob. 15.35PCh. 15 - Prob. 15.36PCh. 15 - Prob. 15.37PCh. 15 - Prob. 15.38PCh. 15 - Prob. 15.39PCh. 15 - Prob. 15.40PCh. 15 - Prob. 15.41PCh. 15 - Prob. 15.42PCh. 15 - Prob. 15.43PCh. 15 - Prob. 15.44PCh. 15 - Prob. 15.45PCh. 15 - Prob. 15.46PCh. 15 - Prob. 15.47PCh. 15 - Prob. 15.48PCh. 15 - Prob. 15.49PCh. 15 - Prob. 15.50PCh. 15 - Prob. 15.51PCh. 15 - Prob. 15.52PCh. 15 - Prob. 15.53PCh. 15 - Prob. 15.54PCh. 15 - Prob. 15.55PCh. 15 - Prob. 15.56PCh. 15 - Prob. 15.57PCh. 15 - Prob. 15.58PCh. 15 - Prob. 15.59PCh. 15 - Prob. 15.60PCh. 15 - Prob. 15.61PCh. 15 - Prob. 15.62PCh. 15 - Prob. 15.63PCh. 15 - Prob. 15.64PCh. 15 - Prob. 15.65PCh. 15 - Prob. 15.66PCh. 15 - Prob. 15.67PCh. 15 - Prob. 15.68PCh. 15 - Prob. 15.1YTCh. 15 - Prob. 15.2YTCh. 15 - Prob. 15.3YTCh. 15 - Prob. 15.4YTCh. 15 - Prob. 15.5YTCh. 15 - Prob. 15.6YTCh. 15 - Prob. 15.7YTCh. 15 - Prob. 15.8YTCh. 15 - Prob. 15.9YTCh. 15 - Prob. 15.10YTCh. 15 - Prob. 15.11YTCh. 15 - Prob. 15.12YTCh. 15 - Prob. 15.13YTCh. 15 - Prob. 15.14YTCh. 15 - Prob. 15.15YTCh. 15 - Prob. 15.16YTCh. 15 - Prob. 15.17YTCh. 15 - Prob. 15.18YTCh. 15 - Prob. 15.19YTCh. 15 - Prob. 15.20YTCh. 15 - Prob. 15.21YTCh. 15 - Prob. 15.22YTCh. 15 - Prob. 15.23YTCh. 15 - Prob. 15.24YTCh. 15 - Prob. 15.25YTCh. 15 - Prob. 15.26YTCh. 15 - Prob. 15.27YTCh. 15 - Prob. 15.28YTCh. 15 - Prob. 15.29YTCh. 15 - Prob. 15.30YT
Knowledge Booster
Similar questions
- please help me draw a HNMR spectra of the following moleculearrow_forwardIdentify the following spectra. Assign all pertinent peaks (~5-6 peaks). Place the structure of the compound in the box on the lower left-hand corner of the spectrum. circle spectrum on grapharrow_forwardInterprt as many of the main peaks in the following spectra as you can – do this by providing the chemical formula of the species responsible for the peak in each case – you don’t need to outline specific fragmentation pathwaysarrow_forward
- Unrounded Rounded ε∗,L/μmolε∗,L/μmol 0.0259825 0.0260 heres data: TZ # Concentration Absorbance at 430 nmnm 1 33.6480 0.931 2 25.2360 0.757 3 16.8420 0.210 4 8.41200 0.137 5 4.20600 0.122arrow_forwardBetween these 2 compounds, which one will be (R) and which one is (S) configuration? Please draw to explain your answer in detailed..arrow_forwardBased on the spectra you located, does your molecule have a carbonyl? If so, what functional group is it a part of (carboxylic acid, ketone, aldehyde, ester, amide) and what is the frequency (in wavenumbers) of the absorption peak? If not, what is the approximate frequency range for a carbonyl? Does your molecule have either an –O-H or –N-H bond? If so, what functional group is it a part of (carboxylic acid, alcohol, amine, amide) and what is the frequency (in wavenumbers) of the absorption peak? If not, what are the approximate frequency ranges for an –O-H and an –N-H bond? Does your molecule have either an alkyne or nitrile functional group? If so, which functional group is it and what is the frequency (in wavenumbers) of the absorption peak? If not, what is the approximate frequency range for a triple bond?arrow_forward
- Please answer in typewritten and essay form. Thank you. Brief explanation only (2-3 sentences each factors) How do the following factors affect absorption frequencies? A. O-H vs O-D. B. CH stretch, hybrid orbitals used by carbonarrow_forwardA 300-MHz spectrometer records a proton that absorbs at a frequency 2130 Hz downfield(deshielded) from TMS. ) Predict this proton’s chemical shift at 60 MHz. In a 60-MHz spectrometer, how fardownfield (in hertz) from TMS would this proton absorb?arrow_forwardWhy the extended Pi(π) conjugated are suitable for Fluorescence properties? Answer should be specific(3-4 lines).arrow_forward
- Pls help ASAP, thanks!"predict the multiplicity and integral of the signal corresponding to the proton(s) indicated below"arrow_forwardProvide structures that are consistent with the attached DEPT spectra (A-C). Each set of spectra includes a DEPT-90 (top), DEPT-135 (middle) and standard 13C decoupled spectrum (bottom). a) C5H11Brarrow_forwardProblem is 75 but only need the answer to 37 and not 41arrow_forward
arrow_back_ios
SEE MORE QUESTIONS
arrow_forward_ios
Recommended textbooks for you
Organic Chemistry: A Guided InquiryChemistryISBN:9780618974122Author:Andrei StraumanisPublisher:Cengage Learning
Organic Chemistry: A Guided Inquiry
Chemistry
ISBN:9780618974122
Author:Andrei Straumanis
Publisher:Cengage Learning