Elements Of Physical Chemistry
Elements Of Physical Chemistry
7th Edition
ISBN: 9780198796701
Author: ATKINS, P. W. (peter William), De Paula, Julio
Publisher: Oxford University Press
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Chapter 15, Problem 15A.1E
Interpretation Introduction

Interpretation:

Volume of the unit cell and density of the solid has to be determined.

Concept Introduction:

Unit cells are the fundamental building block of atoms which repeats itself to form an entire crystal lattice.

Volume=massdensity

If the edge length of unit cell is known then the volume of a unit cell can be calculated by using the equation a×b×c where a, b and c are the edge length in X, Y and Z axis respectively.

Volume of the tetragonal unit cell:

  Volume=a2c

The density is expressed by the formula,

  d=Z×Ma3×Na

Where d is the density, Na is the Avogadro number, M is the mass and a is the edge length.

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