Concept explainers
(a)
Interpretation:
The Fischer projection of both the enantiomers of 2-pentanolneeds to be drawn.
Concept introduction:
For a molecule with the chiral center, the Fischer projection formula is written to describe the stereo arrangement of atoms in two dimensions. For large molecules with more than 1 stereocenters are also represent their stereochemistry using the Fischer Projection. The carbon chain of the molecule containing the chiral carbon center is represented as a vertical line with chiral carbon at the center. Two other groups are then horizontally arranged around the chiral carbon atom.
(b)
Interpretation:
The Fischer projection of both the enantiomers of 1,2-dichlorobutane needs to be drawn.
Concept introduction:
For a molecule with the chiral center, the Fischer projectionformula is written to describe the stereo arrangement of atoms in two dimensions. For large molecules with more than 1 stereocenters are also represent their stereochemistry using the Fischer Projection. The carbon chain of the molecule containing the chiral carbon center is represented as a vertical line with chiral carbon at the center. Two other groups are then horizontally arranged around the chiral carbon atom.
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Chapter 15 Solutions
CONNECT IA GENERAL ORGANIC&BIO CHEMISTRY
- If a mixture has an ee of 90%, what is the percentage of each enantiomer? Multiple Choice 80% : 20% 55% : 45% 95% : 5% 65% : 35%arrow_forwardFor those that have only one stereocenter draw Fischer projection(s) of the S-stereoisomer placing the 4 and 2 positions on the vertical line.arrow_forwardR/S configuration for each stereocenter in the following Fischer projection.arrow_forward
- C. Smelling Chirality. Carvone Olfactory receptors in our noses, used for the detection of odors, are chiral. Therefore, in some cases, we can tell the difference between enantiomers by their odor. Carvone is one such compound that we can distinguish between the R and S enantiomer by their odor. 1. Identify the chiral center in carvone and draw the R and S enantiomers in the indicated boxes. 2. Smell both of the enantiomers of carvone and provide a brief description of their odors in the same boxes. Carvone is perfectly safe to smell as both enantiomers are found in various foods. R-carvone S-carvonearrow_forward1. Locate the stereogenic centers in the following molecule corresponding to a drug used to treat hypertension and determine the possible stereoisomers that can be formed. NH₂ H3CO H3CO H₂N byggarrow_forwardDraw both enantiomers for each biologically active compound.arrow_forward
- Organic Chemistry: A Guided InquiryChemistryISBN:9780618974122Author:Andrei StraumanisPublisher:Cengage Learning
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