Organic Chemistry
Organic Chemistry
7th Edition
ISBN: 9780321826596
Author: Bruice, Paula Yurkanis/
Publisher: Pearson College Div
Question
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Chapter 16, Problem 77P

(a)

Interpretation Introduction

Interpretation:

To determine the products formed in the following reactions.

Concept introduction:

The carboxylic acid and its derivatives like esters, acyl chlorides and amides have groups such as Cl, OH, OR and NH2. These groups can be replaced in a chemical reaction when the compounds react with some reagents like water, alcohol, sodium hydroxide. The nucleophile from the reagents attacks the carbonyl carbon leading to the formation of tetrahedral intermediate followed by the collapse of the intermediate to form a product. The groups Cl, OH, OR and NH2 present in the compound are replaced by the nucleophile in a chemical reaction.

(b)

Interpretation Introduction

Interpretation:

To determine the products formed in the following reactions.

Concept introduction:

The carboxylic acid and its derivatives like esters, acyl chlorides and amides have groups such as Cl, OH, OR and NH2. These groups can be replaced in a chemical reaction when the compounds react with some reagents like water, alcohol, sodium hydroxide. The nucleophile from the reagents attacks the carbonyl carbon leading to the formation of tetrahedral intermediate followed by the collapse of the intermediate to form a product. The groups Cl, OH, OR and NH2 present in the compound are replaced by the nucleophile in a chemical reaction.

(c)

Interpretation Introduction

Interpretation:

To determine the products formed in the following reactions.

Concept introduction:

The carboxylic acid and its derivatives like esters, acyl chlorides and amides have groups such as Cl, OH, OR and NH2. These groups can be replaced in a chemical reaction when the compounds react with some reagents like water, alcohol, sodium hydroxide. The nucleophile from the reagents attacks the carbonyl carbon leading to the formation of tetrahedral intermediate followed by the collapse of the intermediate to form a product. The groups Cl, OH, OR and NH2 present in the compound are replaced by the nucleophile in a chemical reaction.

(d)

Interpretation Introduction

Interpretation:

To determine the products formed in the following reactions.

Concept introduction:

The carboxylic acid and its derivatives like esters, acyl chlorides and amides have groups such as Cl, OH, OR and NH2. These groups can be replaced in a chemical reaction when the compounds react with some reagents like water, alcohol, sodium hydroxide. The nucleophile from the reagents attacks the carbonyl carbon leading to the formation of tetrahedral intermediate followed by the collapse of the intermediate to form a product. The groups Cl, OH, OR and NH2 present in the compound are replaced by the nucleophile in a chemical reaction.

(e)

Interpretation Introduction

Interpretation:

To determine the products formed in the following reactions.

Concept introduction:

The carboxylic acid and its derivatives like esters, acyl chlorides and amides have groups such as Cl, OH, OR and NH2. These groups can be replaced in a chemical reaction when the compounds react with some reagents like water, alcohol, sodium hydroxide. The nucleophile from the reagents attacks the carbonyl carbon leading to the formation of tetrahedral intermediate followed by the collapse of the intermediate to form a product. The groups Cl, OH, OR and NH2 present in the compound are replaced by the nucleophile in a chemical reaction.

(f)

Interpretation Introduction

Interpretation:

To determine the products formed in the following reactions.

Concept introduction:

The carboxylic acid and its derivatives like esters, acyl chlorides and amides have groups such as Cl, OH, OR and NH2. These groups can be replaced in a chemical reaction when the compounds react with some reagents like water, alcohol, sodium hydroxide. The nucleophile from the reagents attacks the carbonyl carbon leading to the formation of tetrahedral intermediate followed by the collapse of the intermediate to form a product. The groups Cl, OH, OR and NH2 present in the compound are replaced by the nucleophile in a chemical reaction.

(g)

Interpretation Introduction

Interpretation:

To determine the products formed in the following reactions.

Concept introduction:

The carboxylic acid and its derivatives like esters, acyl chlorides and amides have groups such as Cl, OH, OR and NH2. These groups can be replaced in a chemical reaction when the compounds react with some reagents like water, alcohol, sodium hydroxide. The nucleophile from the reagents attacks the carbonyl carbon leading to the formation of tetrahedral intermediate followed by the collapse of the intermediate to form a product. The groups Cl, OH, OR and NH2 present in the compound are replaced by the nucleophile in a chemical reaction.

(h)

Interpretation Introduction

Interpretation:

To determine the products formed in the following reactions.

Concept introduction:

The carboxylic acid and its derivatives like esters, acyl chlorides and amides have groups such as Cl, OH, OR and NH2. These groups can be replaced in a chemical reaction when the compounds react with some reagents like water, alcohol, sodium hydroxide. The nucleophile from the reagents attacks the carbonyl carbon leading to the formation of tetrahedral intermediate followed by the collapse of the intermediate to form a product. The groups Cl, OH, OR and NH2 present in the compound are replaced by the nucleophile in a chemical reaction.

(i)

Interpretation Introduction

Interpretation:

To determine the products formed in the following reactions.

Concept introduction:

The carboxylic acid and its derivatives like esters, acyl chlorides and amides have groups such as Cl, OH, OR and NH2. These groups can be replaced in a chemical reaction when the compounds react with some reagents like water, alcohol, sodium hydroxide. The nucleophile from the reagents attacks the carbonyl carbon leading to the formation of tetrahedral intermediate followed by the collapse of the intermediate to form a product. The groups Cl, OH, OR and NH2 present in the compound are replaced by the nucleophile in a chemical reaction.

(j)

Interpretation Introduction

Interpretation:

To determine the products formed in the following reactions.

Concept introduction:

The carboxylic acid and its derivatives like esters, acyl chlorides and amides have groups such as Cl, OH, OR and NH2. These groups can be replaced in a chemical reaction when the compounds react with some reagents like water, alcohol, sodium hydroxide. The nucleophile from the reagents attacks the carbonyl carbon leading to the formation of tetrahedral intermediate followed by the collapse of the intermediate to form a product. The groups Cl, OH, OR and NH2 present in the compound are replaced by the nucleophile in a chemical reaction.

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Chapter 16 Solutions

Organic Chemistry

Ch. 16.5 - a. What is the product of the reaction of acetyl...Ch. 16.6 - a. Which compound has the stretching vibration for...Ch. 16.6 - Using the pKa values listed in Table 15.1, predict...Ch. 16.6 - Is the following statement true or false? If the...Ch. 16.7 - What is the product of an acyl substitution...Ch. 16.8 - PROBLEM 16 Starting with acetyl chloride, what...Ch. 16.8 - Prob. 18PCh. 16.9 - We saw that it is necessary to use excess amine in...Ch. 16.9 - Prob. 20PCh. 16.9 - a. state three factors that cause the uncatalyzed...Ch. 16.10 - Prob. 23PCh. 16.10 - Using the mechanism for the acid-catalyzed...Ch. 16.10 - Prob. 25PCh. 16.10 - Prob. 27PCh. 16.10 - Write the mechanism for the acid-catalyzed...Ch. 16.10 - Write the mechanism for the acid-catalyzed...Ch. 16.11 - Prob. 30PCh. 16.12 - Prob. 31PCh. 16.12 - Prob. 32PCh. 16.13 - Prob. 34PCh. 16.13 - Which has a higher melting point, glyceryl...Ch. 16.13 - Draw the structure of an optically inactive fat...Ch. 16.13 - Draw the structure of an optically active fat...Ch. 16.14 - Show how each of the following esters could he...Ch. 16.14 - Prob. 39PCh. 16.15 - Prob. 40PCh. 16.15 - Which of the following reactions leads to the...Ch. 16.16 - Prob. 42PCh. 16.16 - Prob. 43PCh. 16.18 - Prob. 44PCh. 16.18 - Prob. 45PCh. 16.19 - Prob. 46PCh. 16.19 - Which alkyl halides from the carboxylic acids...Ch. 16.20 - Prob. 49PCh. 16.20 - Prob. 50PCh. 16.20 - Prob. 51PCh. 16.21 - Prob. 52PCh. 16.21 - Prob. 53PCh. 16.22 - How could you synthesize the following compounds...Ch. 16 - Prob. 55PCh. 16 - Name the following:Ch. 16 - Prob. 57PCh. 16 - What compound are obtained from the fallowing...Ch. 16 - a. Rank the following esters in order of...Ch. 16 - Because bromocyclohexane is a secondary alkyl...Ch. 16 - a. Which compound would you expect to have a...Ch. 16 - How could you use 1H NMR spectroscopy to...Ch. 16 - Prob. 63PCh. 16 - a. When a carboxylic acid is dissolved in...Ch. 16 - Rank the following compounds in order of...Ch. 16 - Prob. 66PCh. 16 - Prob. 67PCh. 16 - Prob. 68PCh. 16 - A compound with molecular formula C5H10O2 gives...Ch. 16 - Prob. 70PCh. 16 - Prob. 71PCh. 16 - Prob. 72PCh. 16 - Two products, A and B, are obtained from the...Ch. 16 - Prob. 74PCh. 16 - Prob. 75PCh. 16 - Prob. 76PCh. 16 - Prob. 77PCh. 16 - When treated with an equivalent of methanol,...Ch. 16 - a. Identify the two products obtained from the...Ch. 16 - Prob. 80PCh. 16 - Identity the major and minor products of the...Ch. 16 - Prob. 82PCh. 16 - When a compound with molecular formula C11H14O2...Ch. 16 - Prob. 84PCh. 16 - Prob. 85PCh. 16 - The 1H NMR spectra for two esters with molecular...Ch. 16 - Show how the following compounds could be prepared...Ch. 16 - Prob. 88PCh. 16 - Prob. 89PCh. 16 - Prob. 90PCh. 16 - The intermediate shown here is formed during the...Ch. 16 - Prob. 92PCh. 16 - Propose a mechanism that accounts for the...Ch. 16 - Catalytic antibodies catalyze a reaction by...Ch. 16 - Prob. 95P
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