The mechanism for the preparation of ketone from nitrile using Grignard reagent has to be given. Concept introduction: Grignard reagent: It is an organometallic compound that contains carbon magnesium bond. The electronegativity difference between carbon and magnesium makes the bond more polar. Grignard reagent useful in the synthesis of a desired organic compound that is not easily synthesis by other methods. The grignardreagent can be synthesis by the reaction between magnesium turning with an organic halide with the desired group. The Grignard reagent can act as a nucleophile and undergoes nucleophilic reactions. Grignard reagent on reacting with nitriles gives a ketone. This reaction can be shown as:

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Answer 1

Question

Chapter 16.8, Problem 27P

Interpretation Introduction

Interpretation:

The mechanism for the preparation of ketone from nitrile using Grignard reagent has to be given.

Concept introduction:

Grignard reagent: It is an organometallic compound that contains carbon magnesium bond. The electronegativity difference between carbon and magnesium makes the bond more polar. Grignard reagent useful in the synthesis of a desired organic compound that is not easily synthesis by other methods. The grignardreagent can be synthesis by the reaction between magnesium turning with an organic halide with the desired group. The Grignard reagent can act as a nucleophile and undergoes nucleophilic reactions. Grignard reagent on reacting with nitriles gives a ketone.

This reaction can be shown as:

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Answer 2

Question

Chapter 16.8, Problem 27P

Interpretation Introduction

Interpretation:

The mechanism for the preparation of ketone from nitrile using Grignard reagent has to be given.

Concept introduction:

Grignard reagent: It is an organometallic compound that contains carbon magnesium bond. The electronegativity difference between carbon and magnesium makes the bond more polar. Grignard reagent useful in the synthesis of a desired organic compound that is not easily synthesis by other methods. The grignardreagent can be synthesis by the reaction between magnesium turning with an organic halide with the desired group. The Grignard reagent can act as a nucleophile and undergoes nucleophilic reactions. Grignard reagent on reacting with nitriles gives a ketone.

This reaction can be shown as:

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Answer 3

Question

Chapter 16.8, Problem 27P

Interpretation Introduction

Interpretation:

The mechanism for the preparation of ketone from nitrile using Grignard reagent has to be given.

Concept introduction:

Grignard reagent: It is an organometallic compound that contains carbon magnesium bond. The electronegativity difference between carbon and magnesium makes the bond more polar. Grignard reagent useful in the synthesis of a desired organic compound that is not easily synthesis by other methods. The grignardreagent can be synthesis by the reaction between magnesium turning with an organic halide with the desired group. The Grignard reagent can act as a nucleophile and undergoes nucleophilic reactions. Grignard reagent on reacting with nitriles gives a ketone.

This reaction can be shown as:

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Answer 4

Question

Chapter 16.8, Problem 27P

Interpretation Introduction

Interpretation:

The mechanism for the preparation of ketone from nitrile using Grignard reagent has to be given.

Concept introduction:

Grignard reagent: It is an organometallic compound that contains carbon magnesium bond. The electronegativity difference between carbon and magnesium makes the bond more polar. Grignard reagent useful in the synthesis of a desired organic compound that is not easily synthesis by other methods. The grignardreagent can be synthesis by the reaction between magnesium turning with an organic halide with the desired group. The Grignard reagent can act as a nucleophile and undergoes nucleophilic reactions. Grignard reagent on reacting with nitriles gives a ketone.

This reaction can be shown as:

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Answer 5

Chapter 16.8, Problem 27P

Interpretation Introduction

Interpretation:

The mechanism for the preparation of ketone from nitrile using Grignard reagent has to be given.

Concept introduction:

Grignard reagent: It is an organometallic compound that contains carbon magnesium bond. The electronegativity difference between carbon and magnesium makes the bond more polar. Grignard reagent useful in the synthesis of a desired organic compound that is not easily synthesis by other methods. The grignardreagent can be synthesis by the reaction between magnesium turning with an organic halide with the desired group. The Grignard reagent can act as a nucleophile and undergoes nucleophilic reactions. Grignard reagent on reacting with nitriles gives a ketone.

This reaction can be shown as:

Answer 6

Chapter 16.8, Problem 27P

Interpretation Introduction

Interpretation:

The mechanism for the preparation of ketone from nitrile using Grignard reagent has to be given.

Concept introduction:

Grignard reagent: It is an organometallic compound that contains carbon magnesium bond. The electronegativity difference between carbon and magnesium makes the bond more polar. Grignard reagent useful in the synthesis of a desired organic compound that is not easily synthesis by other methods. The grignardreagent can be synthesis by the reaction between magnesium turning with an organic halide with the desired group. The Grignard reagent can act as a nucleophile and undergoes nucleophilic reactions. Grignard reagent on reacting with nitriles gives a ketone.

This reaction can be shown as:

Answer 7

Chapter 16.8, Problem 27P

Interpretation Introduction

Interpretation:

The mechanism for the preparation of ketone from nitrile using Grignard reagent has to be given.

Concept introduction:

Grignard reagent: It is an organometallic compound that contains carbon magnesium bond. The electronegativity difference between carbon and magnesium makes the bond more polar. Grignard reagent useful in the synthesis of a desired organic compound that is not easily synthesis by other methods. The grignardreagent can be synthesis by the reaction between magnesium turning with an organic halide with the desired group. The Grignard reagent can act as a nucleophile and undergoes nucleophilic reactions. Grignard reagent on reacting with nitriles gives a ketone.

This reaction can be shown as:

Answer 8

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Answer 9

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Answer 10

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Answer 11

Ch. 16.1 - Give two names for each of the following:Ch. 16.1 - Prob. 2P Ch. 16.1 - Name the following:Ch. 16.2 - Prob. 4P Ch. 16.4 - What products are formed when the following...Ch. 16.4 - We saw on the previous page that...Ch. 16.4 - a. How many stereoisomers are obtained from the...Ch. 16.4 - Prob. 9P Ch. 16.4 - Write the mechanism for the reaction of acetyl...Ch. 16.4 - Prob. 11P

Solution Summary: The author explains the mechanism for the preparation of ketone from nitrile using Grignard reagent.

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Chapter 16 Solutions