(a) Interpretation: The major organic product of the given reaction is to be predicted. Concept introduction: Although CO 2 is a non-polar compound, each C=O bond is highly polar, and the central carbon atom in the CO 2 molecule is quite electron-poor. Thus, it is inclined to nucleophilic attack. Grignard reagents can add to CO 2 in the reaction known as carboxylation reaction. The immediate product of carboxylation is a carboxylate ion, which is subsequently protonated through an acid workup to yield a carboxylic acid. Note that the carboxylic acid that is produced contains one extra carbon atom as compared to the original compound.

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Answer 1

Question

Chapter 17, Problem 17.16P

Interpretation Introduction

(a)

Interpretation:

The major organic product of the given reaction is to be predicted.

Concept introduction:

Although CO2 is a non-polar compound, each C=O bond is highly polar, and the central carbon atom in the CO2 molecule is quite electron-poor. Thus, it is inclined to nucleophilic attack. Grignard reagents can add to CO2 in the reaction known as carboxylation reaction. The immediate product of carboxylation is a carboxylate ion, which is subsequently protonated through an acid workup to yield a carboxylic acid. Note that the carboxylic acid that is produced contains one extra carbon atom as compared to the original compound.

Interpretation Introduction

(b)

Interpretation:

The major organic product of the given reaction is to be predicted.

Concept introduction:

Although CO2 is a non-polar compound, each C=O bond is highly polar, and the central carbon atom in the CO2 molecule is quite electron-poor. Thus, it is inclined to nucleophilic attack. Grignard reagents can add to CO2 in the reaction known as carboxylation reaction. The immediate product of carboxylation is a carboxylate ion, which is subsequently protonated through an acid workup to yield a carboxylic acid. Note that the carboxylic acid that is produced contains one extra carbon atom as compared to the original compound.

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Answer 2

Question

Chapter 17, Problem 17.16P

Interpretation Introduction

(a)

Interpretation:

The major organic product of the given reaction is to be predicted.

Concept introduction:

Although CO2 is a non-polar compound, each C=O bond is highly polar, and the central carbon atom in the CO2 molecule is quite electron-poor. Thus, it is inclined to nucleophilic attack. Grignard reagents can add to CO2 in the reaction known as carboxylation reaction. The immediate product of carboxylation is a carboxylate ion, which is subsequently protonated through an acid workup to yield a carboxylic acid. Note that the carboxylic acid that is produced contains one extra carbon atom as compared to the original compound.

Interpretation Introduction

(b)

Interpretation:

The major organic product of the given reaction is to be predicted.

Concept introduction:

Although CO2 is a non-polar compound, each C=O bond is highly polar, and the central carbon atom in the CO2 molecule is quite electron-poor. Thus, it is inclined to nucleophilic attack. Grignard reagents can add to CO2 in the reaction known as carboxylation reaction. The immediate product of carboxylation is a carboxylate ion, which is subsequently protonated through an acid workup to yield a carboxylic acid. Note that the carboxylic acid that is produced contains one extra carbon atom as compared to the original compound.

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Answer 3

Question

Chapter 17, Problem 17.16P

Interpretation Introduction

(a)

Interpretation:

The major organic product of the given reaction is to be predicted.

Concept introduction:

Although CO2 is a non-polar compound, each C=O bond is highly polar, and the central carbon atom in the CO2 molecule is quite electron-poor. Thus, it is inclined to nucleophilic attack. Grignard reagents can add to CO2 in the reaction known as carboxylation reaction. The immediate product of carboxylation is a carboxylate ion, which is subsequently protonated through an acid workup to yield a carboxylic acid. Note that the carboxylic acid that is produced contains one extra carbon atom as compared to the original compound.

Interpretation Introduction

(b)

Interpretation:

The major organic product of the given reaction is to be predicted.

Concept introduction:

Although CO2 is a non-polar compound, each C=O bond is highly polar, and the central carbon atom in the CO2 molecule is quite electron-poor. Thus, it is inclined to nucleophilic attack. Grignard reagents can add to CO2 in the reaction known as carboxylation reaction. The immediate product of carboxylation is a carboxylate ion, which is subsequently protonated through an acid workup to yield a carboxylic acid. Note that the carboxylic acid that is produced contains one extra carbon atom as compared to the original compound.

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Answer 4

Question

Chapter 17, Problem 17.16P

Interpretation Introduction

(a)

Interpretation:

The major organic product of the given reaction is to be predicted.

Concept introduction:

Although CO2 is a non-polar compound, each C=O bond is highly polar, and the central carbon atom in the CO2 molecule is quite electron-poor. Thus, it is inclined to nucleophilic attack. Grignard reagents can add to CO2 in the reaction known as carboxylation reaction. The immediate product of carboxylation is a carboxylate ion, which is subsequently protonated through an acid workup to yield a carboxylic acid. Note that the carboxylic acid that is produced contains one extra carbon atom as compared to the original compound.

Interpretation Introduction

(b)

Interpretation:

The major organic product of the given reaction is to be predicted.

Concept introduction:

Although CO2 is a non-polar compound, each C=O bond is highly polar, and the central carbon atom in the CO2 molecule is quite electron-poor. Thus, it is inclined to nucleophilic attack. Grignard reagents can add to CO2 in the reaction known as carboxylation reaction. The immediate product of carboxylation is a carboxylate ion, which is subsequently protonated through an acid workup to yield a carboxylic acid. Note that the carboxylic acid that is produced contains one extra carbon atom as compared to the original compound.

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Answer 5

Chapter 17, Problem 17.16P

Interpretation Introduction

(a)

Interpretation:

The major organic product of the given reaction is to be predicted.

Concept introduction:

Although CO2 is a non-polar compound, each C=O bond is highly polar, and the central carbon atom in the CO2 molecule is quite electron-poor. Thus, it is inclined to nucleophilic attack. Grignard reagents can add to CO2 in the reaction known as carboxylation reaction. The immediate product of carboxylation is a carboxylate ion, which is subsequently protonated through an acid workup to yield a carboxylic acid. Note that the carboxylic acid that is produced contains one extra carbon atom as compared to the original compound.

Interpretation Introduction

(b)

Interpretation:

The major organic product of the given reaction is to be predicted.

Concept introduction:

Although CO2 is a non-polar compound, each C=O bond is highly polar, and the central carbon atom in the CO2 molecule is quite electron-poor. Thus, it is inclined to nucleophilic attack. Grignard reagents can add to CO2 in the reaction known as carboxylation reaction. The immediate product of carboxylation is a carboxylate ion, which is subsequently protonated through an acid workup to yield a carboxylic acid. Note that the carboxylic acid that is produced contains one extra carbon atom as compared to the original compound.

Answer 6

Chapter 17, Problem 17.16P

Interpretation Introduction

(a)

Interpretation:

The major organic product of the given reaction is to be predicted.

Concept introduction:

Although CO2 is a non-polar compound, each C=O bond is highly polar, and the central carbon atom in the CO2 molecule is quite electron-poor. Thus, it is inclined to nucleophilic attack. Grignard reagents can add to CO2 in the reaction known as carboxylation reaction. The immediate product of carboxylation is a carboxylate ion, which is subsequently protonated through an acid workup to yield a carboxylic acid. Note that the carboxylic acid that is produced contains one extra carbon atom as compared to the original compound.

Answer 7

Chapter 17, Problem 17.16P

Interpretation Introduction

(a)

Interpretation:

The major organic product of the given reaction is to be predicted.

Concept introduction:

Although CO2 is a non-polar compound, each C=O bond is highly polar, and the central carbon atom in the CO2 molecule is quite electron-poor. Thus, it is inclined to nucleophilic attack. Grignard reagents can add to CO2 in the reaction known as carboxylation reaction. The immediate product of carboxylation is a carboxylate ion, which is subsequently protonated through an acid workup to yield a carboxylic acid. Note that the carboxylic acid that is produced contains one extra carbon atom as compared to the original compound.

Answer 8

Interpretation Introduction

(b)

Interpretation:

The major organic product of the given reaction is to be predicted.

Concept introduction:

Although CO2 is a non-polar compound, each C=O bond is highly polar, and the central carbon atom in the CO2 molecule is quite electron-poor. Thus, it is inclined to nucleophilic attack. Grignard reagents can add to CO2 in the reaction known as carboxylation reaction. The immediate product of carboxylation is a carboxylate ion, which is subsequently protonated through an acid workup to yield a carboxylic acid. Note that the carboxylic acid that is produced contains one extra carbon atom as compared to the original compound.

Answer 9

Interpretation Introduction

(b)

Interpretation:

The major organic product of the given reaction is to be predicted.

Concept introduction:

Although CO2 is a non-polar compound, each C=O bond is highly polar, and the central carbon atom in the CO2 molecule is quite electron-poor. Thus, it is inclined to nucleophilic attack. Grignard reagents can add to CO2 in the reaction known as carboxylation reaction. The immediate product of carboxylation is a carboxylate ion, which is subsequently protonated through an acid workup to yield a carboxylic acid. Note that the carboxylic acid that is produced contains one extra carbon atom as compared to the original compound.

Answer 10

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Answer 11

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Answer 12

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Answer 13

Ch. 17 - Prob. 17.1P Ch. 17 - Prob. 17.2P Ch. 17 - Prob. 17.3P Ch. 17 - Prob. 17.4P Ch. 17 - Prob. 17.5P Ch. 17 - Prob. 17.6P Ch. 17 - Prob. 17.7P Ch. 17 - Prob. 17.8P Ch. 17 - Prob. 17.9P Ch. 17 - Prob. 17.10P

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Chapter 17 Solutions